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Excess Electrons at Oxide Surfaces

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Defects at Oxide Surfaces

Part of the book series: Springer Series in Surface Sciences ((SSSUR,volume 58))

Abstract

Excess electrons profoundly affect the properties of oxide surfaces. The present review deals with excess charges on rutile and anatase. These much studied titania polymorphs open with strong prospects regarding (photo)catalysis and dye-sensitized solar cells. In the complex landscape of the mechanisms of electron trapping and electron transfer toward adsorbates, excess electrons open with flexible model systems which are the focus of an extensive research effort.

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Acknowledgments

Authors greatly thank Alberto Verdini, Peter Krueger, Patrick Le Fèvre, Luca Floreano, Alberto Morgante, Jacek Goniakowski and Claudine Noguera for stimulating discussion about defective structures in titania. Financial supports from the EU COST Action CM1104 and the European Seventh Framework Programme Collaborative project SETNanoMetro are acknowledged.

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Authors and Affiliations

  1. ICB, UMR 6303 CNRS-Université de Bourgogne, BP 47870, 21078, Dijon, France

    Sylvie Bourgeois & Bruno Domenichini

  2. Sorbonne Universités, UPMC Univ Paris 06, UMR 7588, Institut des NanoSciences de Paris, 75005, Paris, France

    Jacques Jupille

  3. CNRS, UMR 7588, Institut des NanoSciences de Paris, 75005, Paris, France

    Jacques Jupille

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  1. Sylvie Bourgeois
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Correspondence to Jacques Jupille .

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Editors and Affiliations

  1. Paris Institute of Nanoscience, University Pierre and Marie Curie, Paris, France

    Jacques Jupille

  2. Department of Chemistry, University College London, London, United Kingdom

    Geoff Thornton

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Bourgeois, S., Domenichini, B., Jupille, J. (2015). Excess Electrons at Oxide Surfaces. In: Jupille, J., Thornton, G. (eds) Defects at Oxide Surfaces. Springer Series in Surface Sciences, vol 58. Springer, Cham. https://doi.org/10.1007/978-3-319-14367-5_4

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