Abstract
Hydrogen can be generated in several ways utilizing either renewable or non-renewable sources. However, the lack of a clean hydrogen generation methods at a large scale is considered to be one of the obstacles to implement hydrogen economy. The role of sodium hydroxide is increasing as a valuable ingredient to produce hydrogen. However, the vast use of sodium hydroxide is limited due to its (i) corrosive nature and (ii) high-energy-intensive production method. Various current technologies include sodium hydroxide to lower the operating temperature, accelerate hydrogen generation rate as well as sequester carbon dioxide during hydrogen production. Sodium hydroxide finds applications in all the major hydrogen production methods such as steam methane reforming (SMR), coal gasification, biomass gasification, electrolysis, photochemical and thermochemical. Sodium hydroxide, being alkaline, acts as a catalyst, promoter or even a precursor.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Gupta RB (2009) Hydrogen fuel: production, transport, and storage, Chapter 2. CRC Press, Boca Raton
Audus H, Kaarstad O, Kowal M (1996) Decarbonization of fossil fuels: hydrogen as an energy vector. In: Proceedings of 11th world hydrogen energy conference. Stuttgart, Germany
Reichman B, Mays W, Strebe J, Fetcenko M (2010) Ovonic renewable hydrogen (ORH)—low temperature hydrogen from renewable fuels. Int J Hydrogen Energy 35:4918–4924. doi:10.1016/j.ijhydene.2009.08.097
Onwudili JA, Williams PT (2009) Role of sodium hydroxide in the production of hydrogen gas from the hydrothermal gasification of biomass. Int J Hydrogen Energy 34:5645–5656. doi:10.1016/j.ijhydene.2009.05.082
Kamo T, Takaoka K, Otomo J, Takahashi H (2006) Effect of steam and sodium hydroxide for the production of hydrogen on gasification of dehydrochlorinated poly(vinyl) chloride. Fuel 85:1052–1059. doi:10.1016/j.fuel.2005.10.002
Kumar S, Saxena SK (2013) Role of sodium hydroxide for hydrogen gas production and storage. In: Mendez-Vilas A (ed) Materials and processes for energy: communicating current research and technological developments. Formatex Research Center, Spain
Probstein RF, Hicks RE (2000) Synthetic fuels, Chap 2. Dover, New York
Muradov N (2009) Production of hydrogen from hydrocarbons. In: Gupta R (ed) Hydrogen fuel, production, transport and storage. Boca Raton, FL
Armor J (1999) The multiple roles for catalysis in the production of H2. Appl Catal A General 176:159–176. doi:10.1016/S0926-860X(98)00244-0
Gupta H, Mahesh I, Bartev S, Fan LS (2004) Enhanced hydrogen production integrated with CO2 separation in a single-stage reactor; DOE contract no: DE FC26-03NT41853. Columbus
Ziock H-J, Lackner KS, Harrison DP (2001) Zero emission coal power, a new concept. In: Proceedings of 1st national conference on carbon sequestration. Washington
Stowinski G (2006) Some technical issues of zero-emission coal technology. Int J Hydrogen Energy 31:1091–1102. doi:10.1016/j.ijhydene.2005.08.012
Cormos CC, Starr F, Tzimas E, Peteves S (2008) Innovative concept for hydrogen production processes based on coal gasification with CO2 capture. Int J Hydrogen Energy 33:1286–1294. doi:10.1016/j.ijhydene.2007.12.048
Chiesa P, Consonni S, Kreutz T, Williams R (2005) Co-production of hydrogen, electricity and CO2 from coal with commercially ready technology. Part A: performance and emissions. Int J Hydrogen Energy 30:747–767. doi:10.1016/j.ijhydene.2004.08.002
Wang Z, Zhou J, Wang Q, Fan J, Cen K (2006) Thermodynamic equilibrium analysis of hydrogen production by coal based on Coal/CaO/H2O gasification system. Int J Hydrogen Energy 31:945–952. doi:10.1016/j.ijhydene.2005.07.010
Boswell MC, Dickson JV (1918) The fusion of sodium hydroxide with some inorganic salts. J Am Chem Soc 40:1779–1786. doi:10.1021/ja02245a003
Saxena S, Kumar S, Drozd V (2011) A modified steam-methane-reformation reaction for hydrogen production. Int J Hydrogen Energy 36:4366–4369. doi:10.1016/j.ijhydene.2010.12.133
Saxena S, Drozd V, Durygin A (2008) A fossil-fuel based recipe for clean energy. Int J Hyd Energy 33:3625–3631. doi:10.1016/j.ijhydene.2008.04.050
Ishida M, Takenaka S, Yamanaka I, Otsuka K (2006) Production of COx-free hydrogen from biomass and NaOH mixture: effect of catalysts. Energy Fuels 20:748–753. doi:10.1021/ef050282u
Minowa T, Fang Z, Ogi T, Varhegyi G (1998) Decomposition of cellulose and glucose in hot-compressed water under catalyst-free conditions. J Chem Eng Jpn 31:131–134. doi:10.1252/jcej.31.131
Muangrat R, Onwudili JA, Williams PT (2010) Alkali-promoted hydrothermal gasification of biomass food processing waste: a parametric study. Int J Hydrogen Energy 35:7405–7415. doi:10.1016/j.ijhydene.2010.04.179
Minowa T, Fang Z (1998) Hydrogen production from cellulose in hot compressed water using reduced nickel catalyst: product distribution at different reaction temperatures. J Chem Eng Jpn 31:488–491. doi:10.1016/S0920-5861(98)00277-6
Wang J, Zhang M, Chen M, Min F, Zhang S, Ren Z, Yan Y (2006) Catalytic effects of six inorganic compounds on pyrolysis of three kinds of biomass. Thermochim Acta 444:110–114. doi:10.1016/j.tca.2006.02.007
Su S, Li W, Bai Z, Xiang H, Bai J (2010) Production of hydrogen by steam gasification from lignin with Al2O3·Na2O·xH2O/NaOH/Al(OH)3 catalyst. J Fuel Chem Technol 238:270–274. doi:10.1016/S1872-5813(10)60032-1
Su S, Li W, Bai Z, Xiang H (2008) A preliminary study of a novel catalyst Al2O3·Na2O·xH2O/NaOH/Al(OH)3 for production of hydrogen and hydrogen-rich gas by steam gasification from cellulose. Int J Hydrogen Energy 33:6947–6952. doi:10.1016/j.ijhydene.2008.09.003
Williams DD, Grand JA, Miller RR (1956) The reactions of molten sodium hydroxide with various metals. J Am Chem Soc 78:5150–5155. doi:10.1021/ja01601a004
Annual Report National Advisory Committee for aeronautics (1934) Washington
Wang HZ, Leung DYC, Leung MKH, Ni M (2009) A review on hydrogen production using aluminum and aluminum alloys. Renew Sustain Energy Rev 13:845–853. doi:10.1016/j.rser.2008.02.009
Belitskus D (1970) Reaction of aluminum with sodium hydroxide solution as a source of hydrogen. J Electrochem Soc 117:1097–1099. doi:10.1149/1.2407730
Jung CR, Kundu A, Ku B, Gil JH, Lee HR, Jang JH (2008) Hydrogen from aluminum in a flow reactor for fuel cell applications. J Power Sources 175:490–494. doi:10.1016/j.jpowsour.2007.09.064
Deng ZY, Tang YB, Zhu LL, Sakka Y, Ye J (2010) Effect of different modification agents on hydrogen-generation by the reaction of Al with water. Int J Hydrogen Energy 35:9561–9568. doi:10.1016/j.ijhydene.2010.07.027
Dupiano P, Stamatis D, Dreizin EL (2011) Hydrogen production by reacting water with mechanically milled composite aluminum metal oxide powders. Int J Hydrogen Energy 36:4781–4791. doi:10.1016/j.ijhydene.2011.01.062
Skrovan J, Alfantazi A, Troczynski T (2009) Enhancing aluminum corrosion in water. J Appl Electrochem 39:1695–1702. doi:10.1007/s10800-009-9862-x
Soler L, Macana´s J, Mun˜oz M, Casado J (2005) Hydrogen generation from aluminum in a non-consumable potassium hydroxide solution. In: Proceedings of international hydrogen energy congress and exhibition IHEC. Istanbul, Turkey
Wang W, Chen DM, Yang K (2010) Investigation on microstructure and hydrogen generation performance of Al-rich alloys. Int J Hydrogen Energy 35:12011–12019. doi:10.1016/j.ijhydene.2010.08.089
Ziebarth JT, Woodall JM, Kramer RA, Choi G (2011) Liquid phase enabled reaction of Al–Ga and Al–Ga–In–Sn alloys with water. Int J Hydrogen Energy 36:5271–5279. doi:10.1016/j.ijhydene.2011.01.127
Fan MQ, Xu F, Sun LX (2007) Hydrogen generation by hydrolysis reaction of ball-milled Al–Bi alloys. Energy Fuels 21:2294–2298. doi:10.1021/ef0700127
Ilyukhina AV, Kravchenko OV, Bulychev BM, Shkolnikov EI (2010) Mechanochemical activation of aluminum with galliams for hydrogen evolution from water. Int J Hydrogen Energy 35:1905–1910. doi:10.1016/j.ijhydene.2009.12.118
Aleksandrov YA, Tsyganova EI, Pisarev AL (2003) Reaction of aluminum with dilute aqueous NaOH solutions. Russ J General Chem 73:689–694. doi:10.1023/A:1026114331597
Zhuk AZ, Sheindlin AE, Kleymenov BV (2006) Use of low-cost aluminum in electric energy production. J Power Sour 157:921–926. doi:10.1016/j.jpowsour.2005.11.097
Stockburger D, Stannard JH, Rao BML, Kobasz W, Tuck CD (1992) On-line hydrogen generation from aluminum in an alkaline solution. In: Proc Symp Hydrogen Storage Mater, Batteries Electrochem 92:431–444
Soler L, Macana´s J, Mun˜oz M, Casado J (2007) Aluminum and aluminum alloys as sources of hydrogen for fuel cell applications. J Power Sour 169:144–149. doi:10.1016/j.jpowsour.2007.01.080
Martı´nez SS, Benı´tesa WL, Gallegosa A, Sebastia´n PJ (2005) Recycling of aluminum to produce green energy. Solar Energy Mater Solar Cells 88:237–243. doi:10.1016/j.jsolmat.2004.09.022
Yalcin S (1989) A review of nuclear hydrogen production. Int J Hydrogen Energy 14:551–561. doi:10.1016/0360-3199(89)90113-4
Abanades S, Charvin P, Flamant G, Neveu P (2006) Screening of water-splitting thermochemical cycles potentially attractive for hydrogen production by concentrated solar energy. Energy 31:2805–2822. doi:10.1016/j.energy.2005.11.002
Holladay JD, Hu J, King DL, Wang Y (2009) An overview of hydrogen production technologies. Catal Today 139:244–260. doi:10.1016/j.cattod.2008.08.039
Nakamura T (1977) Hydrogen production from water utilizing solar heat at high temperatures. Sol Energy 19:467–475. doi:10.1016/0038-092X(77)90102-5
Sibieude F, Ducarroir M, Tofighi A, Ambriz J (1982) High temperature experiments with a solar furnace: the decomposition of Fe3O4, Mn3O4 CdO. Int J Hydrogen Energy 7:79–88. doi:10.1016/0360-3199(82)90209-9
Ambriz JJ, Ducarroir M, Sibieude F (1982) Preparation of cadmium by thermal dissociation of cadmium oxide using solar energy Int J Hydrogen Energy 7:143–153. doi:10.1016/0360-3199(82)90141-0
Weidenkaff A, Steinfeld A, Wokaun A, Auer PO, Eichler B, Reller A (1999) Direct solar thermal dissociation of zinc oxide: condensation and crystallisation of zinc in the presence of oxygen. Sol Energy 65:59–69. doi:10.1016/S0038-092X(98)00088-7
Lundberg M (1993) Model calculations on some feasible two-step water splitting processes. Int J Hydrogen Energy 18:369–376. doi:10.1016/0360-3199(93)90214-U
O’Keefe D, Allen C, Besenbruch G, Brown L, Norman J, Sharp R (1982) Preliminary results from bench-scale testing of a sulfur-iodine thermochemical water-splitting cycle. Int J Hydrogen Energy 7:381–392. doi :10.1016/0360-3199(82)90048-9
Sakurai M, Nakajima H, Amir R, Onuki K, Shimizu S (2000) Experimental study on side-reaction occurrence condition in the iodine-sulfur thermochemical hydrogen production process. Int J Hydrogen Energy 25:613–619. doi:10.1016/S0360-3199(99)00074-9
Kubo S, Nakajima H, Kasahara S, Higashi S, Masaki T, Abe H (2004) A demonstration study on a closed-cycle hydrogen production by the thermochemical water-splitting iodine sulfur process. Nucl Eng Des 233:347–354. doi:10.1016/j.nucengdes.2004.08.025
Kameyama H, Yoshida K (1981) Reactor design for the UT-3 thermochemical hydrogen production process. Int J Hydrogen Energy 6:567–575. doi:10.1016/0360-3199(81)90022-7
Kameyama H, Tomino Y, Sato T, Amir R, Orihara A, Aihara M (1989) Process simulation of “Mascot” plant using the UT-3 thermochemical cycle for hydrogen production. Int J Hydrogen Energy 14:323–330. doi:10.1016/0360-3199(89)90133-X
Sakurai M, Bilgen E, Tsutsumi A, Yoshida K (1996) Adiabatic UT-3 thermochemical process for hydrogen production. Int J Hydrogen Energy 21:865–870. doi:10.1016/0360-3199(96)00024-9
Miyoka H, Ichikawa T, Nakamura N, Kojima Y (2012) Low temperature water splitting by sodium redox reaction. Int J Hydrogen Energy 37:17709–17714. doi:10.1016/j.ijhydene.2012.09.085
Weimer A (2008) H2A analysis for Manganese oxide based solar thermal water splitting cycle. University of Colorado STCH, Denver
Tamura Y, Steinfeld A, Kuhn P, Ehrensberger K (1995) Production of solar hydrogen by a novel, 2-step, water-splitting thermochemical cycle. Energy 20:325–330. doi:10.1016/0360-5442(94)00090-O
Sturzenegger M, Ganz J, Nüesch P, Schelling T (1999) Solar hydrogen from a manganese oxide based thermochemical cycle. J de Phys Arch 09:Pr3–331–Pr3–335. doi:10.1051/jp4:1999351
Xu B, Bhawe Y, Davis ME (2012) Low-temperature, manganese oxide-based, thermochemical water splitting cycle. Proc Natl Acad Sci 109:9260–9264. doi:10.1073/pnas.1206407109
Leitner W, Dinjus E, Gaßner F (1994) Activation of carbon dioxide: IV. Rhodium-catalysed hydrogenation of carbon dioxide to formic acid. J Organomet Chem 475:257–266. doi:10.1016/0022-328X(94)84030-X
Coffey RS (1967) The decomposition of formic acid catalysed by soluble metal complexes. Chem Commun 18:923b–924. doi:10.1039/C1967000923B
Yoshida T, Ueda Y, Otsuka S (1978) Activation of water molecule. 1. Intermediates bearing on the water gas shift reaction catalyzed by platinum (0) complexes. J Am Chem Soc 100:3941–3942. doi:10.1021/ja00480a054
Paonessa RS, Trogler WC (1982) Solvent-dependent reactions of carbon dioxide with a platinum (II) Dihydride reversible formation of a platinum(II) formatohydride and a cationic platinum(II) dimer, [Pt2H3(PEt3)4][HCO2]. J Am Chem Soc 104:3529–3530. doi:10.1021/ja00376a058
Joszai I, Joo F (2004) Hydrogenation of aqueous mixtures of calcium carbonate and carbon dioxide using a water-soluble rhodium(I)–tertiary phosphine complex catalyst. J Mol Catal A: Chem 224:87–91. doi:10.1016/j.molcata.2004.08.045
Gao Y, Kuncheria JK, Yap GPA, Puddephatt RJ (1998) An efficient binuclear catalyst for decomposition of formic acid. Chem Commun 21:2365–2366. doi:10.1039/A805789C
Shin JH, Churchill DG, Parkin G (2002) Carbonyl abstraction reactions of Cp*Mo(PMe3)3H with CO2, (CH2O) n , HCO2H, and MeOH: the synthesis of Cp*Mo(PMe3)2(CO)H and the catalytic decarboxylation of formic acid. J Organomet Chem 642:9–15. doi:10.1016/S0022-328X(01)01218-9
Loges B, Boddien A, Gartner F, Junge H, Beller M (2010) Catalytic generation of hydrogen from formic acid and its derivatives: useful hydrogen storage materials. Top Catal 53:902–914. doi:10.1007/s11244-010-9522-8
Fukuzumi S, Suenobu T, Ogo S. Catalysts for the decomposition of formic acid, method for decomposing formic acid, process for producing hydrogen, apparatus for producing and decomposing formic acid, and method for storing and producing hydrogen, US Patent application no. US2010/ 0034733 A1
Guo WL, Li L, Li LL, Tian S, Liu SL, Wu YP (2011) Hydrogen production via electrolysis of aqueous formic acid solutions. Int J Hydrogen Energy 36:9415–9419. doi:10.1016/j.ijhydene.2011.04.127
Majewski A, Morris DJ, Kendall K, Wills M (2010) A continuous-flow method for the generation of hydrogen from formic acid. ChemSusChem 3:431–434. doi:10.1002/cssc.201000017
Loew O (1887) Ueber einige katalytische Wirkungen. Berichte der deutschen chemischen Gesellscha 20:144–145
Kapoor S, Naumov S (2004) On the origin of hydrogen in the formaldehyde reaction in alkaline solution. Chem Phys Lett 387:322–326. doi:10.1016/j.cplett.2004.01.127
Ansell MF, Coffey S, Rodd EH (1965) Rodd’s chemistry of carbon compounds Elsevier. Page, Amsterdam 11
Ashby EC, Doctorovich F, Liotta CL, Neumann HM, Barefield EK, Konda A, Zhang K, Hurley J, Siemer DD (1993) Concerning the formation of hydrogen in nuclear waste. Quantitative generation of hydrogen via a Cannizzaro intermediate. J Am Chem Soc 115:1171–1173. doi:10.1021/ja00056a065
Harden A (1899) Formaldehyde, action of hydrogen peroxide on. J Soc Chem Indus 15:158–159
Satterfield CN, Wilson RE, Le Clair RM, Reid RC (1954) Analysis of aqueous mixtures of hydrogen peroxide and aldehydes. Anal Chem 26:1792–1797. doi:10.1021/ac60095a030
Gorse RA, Volman DH (1971) Analysis of mixtures of hydrogen peroxide and formaldehyde. Anal Chem 43:284–284. doi:10.1021/ac60297a031
Kurt C, Bittner J (2006) Sodium hydroxide: Ullman’s encyclopedia of industrial chemistry.doi:10.1002/14356007.a24_345.pub2
Kumar S (2013) Clean hydrogen production and carbon dioxide capture methods. FIU electronic theses and dissertations paper 1039. http://digitalcommons.fiu.edu/etd/1039
Kreider PB, Funke HH, Cuche K, Schmidt M, Steinfeld A, Weimer AW (2011) Manganese oxide based thermochemical hydrogen production cycle. Int J Hydrogen Energy 36:7028–7037. doi:10.1016/j.ijhydene.2011.03.003
Charvin P, Abanades S, Beche E, Lemont F, Flamant G (2009) Hydrogen production from mixed cerium oxides via three-step water-splitting cycles. Solid State Ionics 180:1003–1010. doi:10.1016/j.ssi.2009.03.015
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2015 The Author(s)
About this chapter
Cite this chapter
Kumar, S. (2015). Sodium Hydroxide for Clean Hydrogen Production. In: Clean Hydrogen Production Methods. SpringerBriefs in Energy. Springer, Cham. https://doi.org/10.1007/978-3-319-14087-2_2
Download citation
DOI: https://doi.org/10.1007/978-3-319-14087-2_2
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-14086-5
Online ISBN: 978-3-319-14087-2
eBook Packages: EnergyEnergy (R0)