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Ultrafast Phenomena XIX pp 180–183Cite as

The Ultrafast Wolff Rearrangement in the Gas Phase

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Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 162))

Abstract

The Wolff rearrangement of gas-phase 5-diazo Meldrum’s acid is disclosed with femtosecond ion spectroscopy. Distinct differences are found for \( 267 \) nm and \( 200 \) nm excitation, the latter leading to even two ultrafast rearrangement reactions.

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References

  1. Bogdanova, A. and Popik, V. V.: Experimental and theoretical investigation of reversible interconversion, thermal reactions, and wavelength-dependent photochemistry of diazo Meldrum’s acid and its diazirine isomer, 6,6-dimethyl-5,7-dioxa-1,2-diaza-spiro[2,5]oct-1-ene-4,8-dione. J. Am. Chem. Soc. 125, 14153–14162 (2013)

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  2. Kammula, S. L., Tracer, H. L., Shevlin, P. B., and Jones, M.: Intramolecular decomposition of isopropylidene diazomalonate (diazo Meldrum’s acid). J. Org. Chem. 42, 2931–2932 (1977)

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  3. Rudolf, P., Buback, J., Aulbach, J., Nuernberger, P., and Brixner, T.: Ultrafast multisequential photochemistry of 5-diazo Meldrum’s acid. J. Am. Chem. Soc. 132, 15213–15222 (2010)

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  4. Steinbacher, A., Roeding, S., Brixner, T., and Nuernberger, P.: Ultrafast photofragment ion spectroscopy of the Wolff rearrangement in 5-diazo Meldrum’s acid. Phys. Chem. Chem. Phys. 16, 7290–7298 (2014)

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Author information

Authors and Affiliations

  1. Universität Würzburg, Am Hubland, 97074, Würzburg, Germany

    Andreas Steinbacher, Sebastian Roeding & Tobias Brixner

  2. Ruhr-Universität Bochum, 44780, Bochum, Germany

    Patrick Nuernberger

Authors
  1. Andreas Steinbacher
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  2. Sebastian Roeding
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  3. Tobias Brixner
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  4. Patrick Nuernberger
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Corresponding author

Correspondence to Patrick Nuernberger .

Editor information

Editors and Affiliations

  1. Department of Chemistry, The University of Tokyo, Tokyo, Japan

    Kaoru Yamanouchi

  2. JILA, University of Colorado, Boulder, Colorado, USA

    Steven Cundiff

  3. Department of Chemistry, Ludwig-Maximilians-University, München, Germany

    Regina de Vivie-Riedle

  4. Department of Physics, The University of Tokyo, Tokyo, Japan

    Makoto Kuwata-Gonokami

  5. Department of Physics, The Ohio State University, Columbus, Ohio, USA

    Louis DiMauro

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© 2015 Springer International Publishing Switzerland

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Steinbacher, A., Roeding, S., Brixner, T., Nuernberger, P. (2015). The Ultrafast Wolff Rearrangement in the Gas Phase. In: Yamanouchi, K., Cundiff, S., de Vivie-Riedle, R., Kuwata-Gonokami, M., DiMauro, L. (eds) Ultrafast Phenomena XIX. Springer Proceedings in Physics, vol 162. Springer, Cham. https://doi.org/10.1007/978-3-319-13242-6_43

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