Abstract
The demands on materials increase rapidly. To meet these demands, more and more complex microstructures and microstructural architectures are used. However, currently used strategies to develop increasingly complex structures are unsuited to create tomorrow’s materials. For example, the main challenge in determining micro structure–property relationships is that any kind of individual variation in feature properties inevitably changes other properties. This is due to the fabrication methods, which do not permit completely independently vary just one microstructure feature. As an example, if one attempts to alter, for instance, the spacing of a phase in a microstructure, at the same time, length, volume, composition, dispersity, and density of this phase will also change because all the properties are interconnected. This contribution consists of an in-depth study of investigating microstructure-property relationships in bulk metallic glasses using a novel quantitative approach by which influence of the second phase features on mechanical properties can be independently and systematically analyzed. We adopted this strategy to evaluate and optimize the elastic and plastic deformation, as well as the overall toughness of cellular honeycombs under in-plane compression and porous heterostructures under uniaxial tension.
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References
Schwarz M, Karma A, Eckler K, Herlach DM. Physical-Mechanism of Grain-Refinement in Solidification of Undercooled Melts. Phys Rev Lett. 1994;73:2940.
Schroers J, HollandMoritz D, Herlach DM, Grushko B, Urban K. Undercooling and solidification behaviour of a metastable decagonal quasicrystalline phase and crystalline phases in Al-Co. Mat Sci Eng a-Struct. 1997;226:990.
Falk ML, Langer JS, Pechenik L. Thermal effects in the shear-transformation-zone theory of amorphous plasticity: comparisons to metallic glass data. Phys Rev E. 2004;70:011507–1.
Yamakov V, Wolf D, Salazar M, Phillpot SR, Gleiter H. Length-scale effects in the nucleation of extended dislocations in nanocrystalline Al by molecular-dynamics simulation. Acta Mater. 2001;49:2713.
Yamakov V, Wolf D, Phillpot SR, Gleiter H. Grain-boundary diffusion creep in nanocrystalline palladium by molecular-dynamics simulation. Acta Mater. 2002;50:61.
Lund AC, Schuh CA. Strength asymmetry in nanocrystalline metals under multiaxial loading. Acta Mater. 2005;53:3193.
Li QK, Li M. Free volume evolution in metallic glasses subjected to mechanical deformation. Mater Trans. 2007;48:1816.
Hood RQ, Galli G. Insulator to metal transition in fluid deuterium. J Chem Phys. 2004;120:5691.
Torquato S, Stillinger FH. Jammed hard-particle packings: from Kepler to Bernal and beyond. Rev Mod Phys. 2010;82:2633.
Song C, Wang P, Makse HA. A phase diagram for jammed matter. Nature. 2008;453:629.
Bernal JD, Finney JL. Random close-packed hard-sphere model. 2. Geometry of random packing of hard spheres. Discuss Faraday Soc. 1967;43:62.
12. Bernal JD. Geometry of the structure of monatomic liquids. Nature. 1960;185:68.
Bernal JD, Mason J. Co-ordination of randomly packed spheres. Nature. 1960;188:910.
Pusey PN, Vanmegen W. Phase-behavior of concentrated suspensions of nearly hard colloidal spheres. Nature. 1986;320:340.
15. Vanblaaderen A, Wiltzius P. Real-space structure of colloidal hard-sphere glasses. Science. 1995;270:1177.
Royall CP, Poon WCK, Weeks ER. In search of colloidal hard spheres. Soft Matter. 2013;9:17.
Pusey PN, Zaccarelli E, Valeriani C, Sanz E, Poon WCK, Cates ME. Hard spheres: crystallization and glass formation. Philos T R Soc A. 2009;367:4993.
Schall P, Weitz DA, Spaepen F. Structural rearrangements that govern flow in colloidal glasses. Science. 2007;318:1895.
Schroers J. Bulk metallic glasses. Phys Today. 2013;66:32.
Chen MW. A brief overview of bulk metallic glasses. Npg Asia Mater. 2011;3:82.
Wang WH, Dong C, Shek CH. Bulk metallic glasses. Mat Sci Eng R. 2004;44:45.
Telford M. The case for bulk metallic glass. Mater. Today March. 2004;7:36.
Greer AL. Metallic glasses … on the threshold. Mater Today. 2009;12:14.
Schroers J. The superplastic forming of bulk metallic glasses. Jom-Us. 2005;57:35.
Kumar G, Tang HX, Schroers J. Nanomoulding with amorphous metals. Nature. 2009;457:868.
Kumar G, Desai A, Schroers J. Bulk metallic glass: the smaller the better. Adv Mater. 2011;23:461.
Schroers J. On the formability of bulk metallic glass in its supercooled liquid state. Acta Mater. 2008;56:471.
Sarac B, Kumar G, Hodges T, Ding SY, Desai A, Schroers J. Three-dimensional shell fabrication using blow molding of bulk metallic glass. J Microelectromech S. 2011;20:28.
Schroers J, Pham Q, Desai A. Thermoplastic forming of bulk metallic glass—a technology for MEMS and microstructure fabrication. J Microelectromech S. 2007;16:240.
Sarac B, Ketkaew J, Popnoe DO, Schroers J. Honeycomb structures of bulk metallic glasses. Adv Funct Mater. 2012;22:3161.
Sarac B, Schroers J. From brittle to ductile: density optimization for Zr-BMG cellular structures. Scripta Mater. 2013;68:921.
Conner RD, Johnson WL, Paton NE, Nix WD. Shear bands and cracking of metallic glass plates in bending. J Appl Phys. 2003;94:904.
Wada T, Inoue A, Greer AL. Enhancement of room-temperature plasticity in a bulk metallic glass by finely dispersed porosity. Appl Phys Lett. 2005;86:251907–1.
Hofmann DC, Suh JY, Wiest A, Duan G, Lind ML, Demetriou MD, Johnson WL. Designing metallic glass matrix composites with high toughness and tensile ductility. Nature. 2008;451:1085.
Volkert CA, Donohue A, Spaepen F. Effect of sample size on deformation in amorphous metals. J Appl Phys. 2008;103:083539–1.
Sarac B, Schroers J. Designing tensile ductility in metallic glasses. Designing tensile ductility in metallic glasses. Nat Commun. 2013;4:2158–1.
Johnson WL. Bulk glass-forming metallic alloys: science and technology. Mrs Bull. 1999;24:42.
Demetriou MD, Launey ME, Garrett G, Schramm JP, Hofmann DC, Johnson WL, Ritchie RO. A damage-tolerant glass. Nat Mater. 2011;10:123.
Schroers J. Processing of bulk metallic glass. Adv Mater. 2010;22:1566.
Schroers J, Pham Q, Peker A, Paton N, Curtis RV. Blow molding of bulk metallic glass. Scripta Mater. 2007;57:341.
Martinez R, Kumar G, Schroers J. Hot rolling of bulk metallic glass in its supercooled liquid region. Scripta Mater. 2008;59:187.
Schroers J, Paton N. Amorphous metal alloys form like plastics. Adv Mater Process. 2006;164:61.
Saotome Y, Itoh K, Zhang T, Inoue A. Superplastic nanoforming of Pd-based amorphous alloy. Scripta Mater. 2001;44:1541.
Sharma P, Kaushik N, Kimura H, Saotome Y, Inoue A. Nano-fabrication with metallic glass—an exotic material for nano-electromechanical systems. Nanotechnology. 2007;18:035302–1.
Chu JP, Wijaya H, Wu CW, Tsai TR, Wei CS, Nieh TG, Wadsworth J. Nanoimprint of gratings on a bulk metallic glass. Appl Phys Lett. 2007;90:034101–1.
Kumar G, Schroers J. Write and erase mechanisms for bulk metallic glass. Appl Phys Lett. 2008;92:031901–1.
Pan CT, Wu TT, Chang YC, Huang JC. Experiment and simulation of hot embossing of a bulk metallic glass with low pressure and temperature. J Micromech Microeng. 2008;18:025010–1.
Inoue A, Nishiyama N. New bulk metallic glasses for applications as magnetic-sensing, chemical, and structural materials. Mrs Bull. 2007;32:651.
Henann DL, Srivastava V, Taylor HK, Hale MR, Hardt DE, Anand L. Metallic glasses: viable tool materials for the production of surface microstructures in amorphous polymers by micro-hot-embossing. J Micromech Microeng. 2009;19:115030–1.
Ashby MF, Greer AL. Metallic glasses as structural materials. Scripta Mater. 2006;54:321.
Busch R, Schroers J, Wang WH. Thermodynamics and kinetics of bulk metallic glass. Mrs Bull. 2007;32:620.
Kumar G, Neibecker P, Liu YH, Schroers J. Critical fictive temperature for plasticity in metallic glasses. Nat Commun. 2013;4:1536–1.
Kumar G, Rector D, Conner RD, Schroers J. Embrittlement of Zr-based bulk metallic glasses. Acta Mater. 2009;57:3572.
Schroers J, Lohwongwatana B, Johnson WL, Peker A. Gold based bulk metallic glass. Appl Phys Lett 2005;87:061912–1.
Zhang B, Zhao DQ, Pan MX, Wang WH, Greer AL. Amorphous metallic plastic. Phys Rev Lett. 2005;94:205502–1.
Legg BA, Schroers J, Busch R. Thermodynamics, kinetics, and crystallization of Pt57.3Cu14.6Ni5.3P22.8 bulk metallic glass. Acta Mater. 2007;55:1109.
Duan G, Wiest A, Lind ML, Li J, Rhim WK, Johnson WL. Bulk metallic glass with benchmark thermoplastic processability. Adv Mater. 2007;19:4272.
Schroers J, Johnson WL. Highly processable bulk metallic glass-forming alloys in the Pt-Co-Ni-Cu-P system. Appl Phys Lett. 2004;84:3666.
Schroers J, Hodges TM, Kumar G, Raman H, Barnes AJ, Quoc P, Waniuk TA. Thermoplastic blow molding of metals. Mater Today. 2011;14:14.
Carmo M, Sekol RC, Ding SY, Kumar G, Schroers J, Taylor AD. Bulk metallic glass nanowire architecture for electrochemical applications. Acs Nano. 2011;5:2979.
Xing LQ, Li Y, Ramesh KT, Li J, Hufnagel TC. Enhanced plastic strain in Zr-based bulk amorphous alloys. Phys Rev B. 2001;64:180201–1.
Schroers J, Johnson WL. Ductile bulk metallic glass. Phys Rev Lett. 2004;93:255506–1.
Das J, Tang MB, Kim KB, Theissmann R, Baier F, Wang WH, Eckert J. “Work-hardenable” ductile bulk metallic glass. Phys Rev Lett. 2005;94:205501–1.
Liu YH, Wang G, Wang RJ, Zhao DQ, Pan MX, Wang WH. Super plastic bulk metallic glasses at room temperature. Science. 2007;315:1385.
Lewandowski JJ, Wang WH, Greer AL. Intrinsic plasticity or brittleness of metallic glasses. Phil Mag Lett. 2005;85:77.
Schuh CA, Hufnagel TC, Ramamurty U. Overview No.144—mechanical behavior of amorphous alloys. Acta Mater. 2007;55:4067.
Schuh CA, Lund AC, Nieh TG. New regime of homogeneous flow in the deformation map of metallic glasses: elevated temperature nanoindentation experiments and mechanistic modeling. experiments Acta Mater. 2004;52:5879.
Guo H, Yan PF, Wang YB, Tan J, Zhang ZF, Sui ML, Ma E. Tensile ductility and necking of metallic glass. Nat Mater. 2007;6:735.
Spaepen F. Microscopic mechanism for steady-state inhomogeneous flow in metallic glasses. Acta Metallurgica. 1977;25:407.
Bharathula A, Lee SW, Wright WJ, Flores KM. Compression testing of metallic glass at small length scales: effects on deformation mode and stability. Acta Mater. 2010;58:5789.
Inoue A, Zhang W, Tsurui T, Yavari AR, Greer AL. Unusual room-temperature compressive plasticity in nanocrystal-toughened bulk copper-zirconium glass. Phil Mag Lett. 2005;85:221.
Hays CC, Kim CP, Johnson WL. Microstructure controlled shear band pattern formation and enhanced plasticity of bulk metallic glasses containing in situ formed ductile phase dendrite dispersions. Phys Rev Lett. 2000;84:2901.
Fan C, Ott RT, Hufnagel TC. Metallic glass matrix composite with precipitated ductile reinforcement. Appl Phys Lett. 2002;81:1020.
Kuhn U, Eckert J, Mattern N, Schultz L. ZrNbCuNiAl bulk metallic glass matrix composites containing dendritic bcc phase precipitates. Appl Phys Lett. 2002;80:2478.
Louzguine DV, Kato H, Inoue A. High-strength Cu-based crystal-glassy composite with enhanced ductility. Appl Phys Lett. 2004;84:1088.
Kundig AA, Ohnuma M, Ping DH, Ohkubo T, Hono K. In situ formed two-phase metallic glass with surface fractal microstructure. Acta Mater. 2004;52:2441.
Choi-Yim H, Johnson WL. Bulk metallic glass matrix composites. Appl Phys Lett. 1997;71:3808.
Szuecs F, Kim CP, Johnson WL. Title: Mechanical properties of Zr56.2Ti13.8Nb5.0Cu6.9Ni5.6Be12.5 ductile phase reinforced bulk metallic glass composite. Acta Mater. 2001;49:1507.
Siegrist ME, Loffler JF. Bulk metallic glass-graphite composites. Scripta Mater. 2007;56:1079.
Schroers J, Veazey C, Johnson WL. Amorphous metallic foam. Appl Phys Lett. 2003;82:370.
Wada T, Inoue A. Formation of porous Pd-based bulk glassy alloys by a high hydrogen pressure melting-water quenching method and their mechanical properties. Mater Trans. 2004;45:2761.
Schroers J, Veazey C, Demetriou MD, Johnson WL. Synthesis method for amorphous metallic foam. J Appl Phys. 2004;96:7723.
Brothers AH, Dunand DC. Porous and foamed amorphous metals. Mrs Bull. 2007;32:639.
Brothers AH, Dunand DC. Ductile bulk metallic glass foams. Adv Mater. 2005;17:484.
Siegrist ME. Bulk metallic glass composites. Doctoral Thesis. 2007.
Hess PA, Poon SJ, Shiflet GJ, Dauskardt RH. Indentation fracture toughness of amorphous steel. J Mater Res. 2005;20:783.
Gilbert CJ, Ritchie RO, Johnson WL. Fracture toughness and fatigue-crack propagation in a Zr-Ti-Ni-Cu-Be bulk metallic glass. Appl Phys Lett. 1997;71:476.
Xing LQ, Herlach DM, Cornet M, Bertrand C, Dallas JP, Trichet MF, Chevalier JP. Mechanical properties of Zr57Ti5Al10Cu20Ni8 amorphous and partially nanocrystallized alloys. Mat Sci Eng a-Struct. 1997;226:874.
Xing LQ, Eckert J, Schultz L. Deformation mechanism of amorphous and partially crystallized alloys. Nanostruct Mater. 1999;12:503.
Conner RD, Dandliker RB, Scruggs V, Johnson WL. Dynamic deformation behavior of tungsten-fiber/metallic-glass matrix composites. Int J Impact Eng. 2000;24:435.
Fan C, Inoue A. Ductility of bulk nanocrystalline composites and metallic glasses at room temperature. Appl Phys Lett. 2000;77:46.
Sordelet DJ, Rozhkova E, Huang P, Wheelock PB, Besser MF, Kramer MJ, Calvo-Dahlborg M, Dahlborg U. Synthesis of Cu47Ti34Zr11Ni8 bulk metallic glass by warm extrusion of gas atomized powders. J Mater Res. 2002;17:186.
Bae DH, Lee MH, Kim DH, Sordelet DJ. Plasticity in Ni59Zr20Ti16Si2Sn3 metallic glass matrix composites containing brass fibers synthesized by warm extrusion of powders. Appl Phys Lett. 2003;83:2312.
Schroers J, Nguyen T, Croopnick GA. A novel metallic glass composite synthesis method. Scripta Mater. 2007;56:177.
Schroers J, Samwer K, Szuecs F, Johnson WL. Characterization of the interface between the bulk glass forming alloy Zr41Ti14Cu12Ni10Be23 with pure metals and ceramics. J Mater Res. 2000;15:1617.
Ma H, Xu J, Ma E. Mg-based bulk metallic glass composites with plasticity and high strength. Appl Phys Lett. 2003;83:2793.
Launey ME, Hofmann DC, Suh JY, Kozachkov H, Johnson WL, Ritchie RO. Fracture toughness and crack-resistance curve behavior in metallic glass-matrix composites. Appl Phys Lett. 2009;94:241910–1.
He G, Eckert J, Loser W, Schultz L. Novel Ti-base nanostructure-dendrite composite with enhanced plasticity. Nat Mater. 2003;2:33.
He G, Eckert J, Loser W, Hagiwara M. Composition dependence of the microstructure and the mechanical properties of nano/ultrafine-structured Ti-Cu-Ni-Sn-Nb alloys. Acta Mater. 2004;52:3035.
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Sarac, B. (2015). General Introduction. In: Microstructure-Property Optimization in Metallic Glasses. Springer Theses. Springer, Cham. https://doi.org/10.1007/978-3-319-13033-0_1
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DOI: https://doi.org/10.1007/978-3-319-13033-0_1
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