Abstract
Several in situ recovery methods have been developed to extract heavy oil and bitumen from deep reservoirs. Once produced, bitumen is transferred to upgraders that convert low-quality oil to synthetic crude oil. However, the heavy oil and bitumen exploitation process is not just high-energy and water-intensive but also has a significant environmental footprint as it produces large amounts of gaseous emissions and wastewater. In addition, the level of contaminants in bitumen requires special equipment. Therefore, nanotechnology has emerged as an alternative technology for in situ heavy oil upgrading and recovery enhancement. Nanoparticle catalysts are an important example of nanotechnology applications. Nanocatalysts portray unique catalytic and sorption properties due to their exceptionally high surface area-to-volume ratio and active surface sites. In situ catalytic conversion or upgrading of heavy oil with the aid of multimetallic nanocatalysts is a promising cost-effective and environmentally friendly technology for production of high-quality oils that meet pipeline and refinery specifications. Further, nanoparticles could be employed as inhibitors for preventing or delaying asphaltene precipitation and coke formation and subsequently enhance oil recovery. Nevertheless, as with any new technologies, there are a number of challenges facing the employment of nanoparticles for in situ catalytic upgrading and recovery enhancement. The main goal of this chapter is to provide an overview of nanoparticle technology usage, such as ultradispersed nanomaterials, for enhancing the in situ catalytic upgrading and recovery processes of crude oil. Furthermore, the chapter sheds lights on the advantages of the employment of nanoparticles in the heavy oil industry and addresses some of the limitations and challenges facing this new technology.
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Notes
- 1.
Vapor extraction.
- 2.
Expanding solvent SAGD.
- 3.
Steam and gas push.
- 4.
Toe-heel-air-injection.
- 5.
Catalytic upgrading process in situ.
References
Thomas, S. (2008). Enhanced oil recovery-an overview. Oil & Gas Science and Technology-Revue de l'IFP, 63(1), 9-19.
Shah, A., Fishwick, R., Wood, J., Leeke, G., Rigby, S., & Greaves, M. (2010). A review of novel techniques for heavy oil and bitumen extraction and upgrading. Energy & Environmental Science, 3(6), 700-714.
Dietz, D. N. (1967, April). Hot-water drive. In 7th World Petroleum Congress. OnePetro.
Curtis, C., Kopper, R., Decoster, E., Guzman-Garcia, A., Huggins, C., Knauer, L., Minner, M., Kupsch, N., Linares, L.M., Rough, H. & Waite, M. (2002). Heavy-oil reservoirs. Oilfield Review, 14(3), 30-51.
Lake, L. W., Schmidt, R. L., & Venuto, P. B. (1992). A niche for enhanced oil recovery in the 1990s. Oilfield Review;(Netherlands), 4(1).
Ali, S. M. (1982, March). Steam Injection Theories-A Unified Approach. In SPE California Regional Meeting. OnePetro.
Meldau, R. F. (1979). Current steamflood technology. J Petrol Technol, 31(10), 1332-1342.
Speight, J. G. (2013). Enhanced recovery methods for heavy oil and tar sands. Elsevier.
W. G. Graves, J.E.L.D. Cardenas, M. E. Gurfinkel, A. W. Peats, Heavy oil. 2007: Working Document of the NPC Global Oil & Gas Study
Owens, W. D., & Suter, V. E. (1965). Steam stimulation–newest form of secondary petroleum recovery. Oil and Gas J, 82-87.
Alberta Chamber of Resources. 2002: Oil Sands Technology Roadmap
Butler, R. M. (1985). A new approach to the modelling of steam-assisted gravity drainage. Journal of Canadian Petroleum Technology, 24(03), 42-51.
Akin, S., & Bagci, S. (2001). A laboratory study of single-well steam-assisted gravity drainage process. Journal of petroleum science and engineering, 32(1), 23-33.
Kamath, V. A., Sinha, S., & Hatzignatiou, D. G. (1993, May). Simulation study of steam-assisted gravity drainage process in ugnu tar sand reservoir. In SPE Western Regional Meeting. OnePetro.
Queipo, N. V., Goicochea, J. V., & Pintos, S. (2002). Surrogate modeling-based optimization of SAGD processes. Journal of Petroleum Science and Engineering, 35(1-2), 83-93.
S. Purkayastha, Control and Optimization of Steam Injection for Steam-Assisted Gravity Drainage (SAGD)
Das, S. K., & Butler, R. M. (1995, October). Extraction of heavy oil and bitumen using solvents at reservoir pressure. In Technical meeting/petroleum conference of the South Saskatchewan section. OnePetro.
Gates, I. D. (2007). Oil phase viscosity behaviour in expanding-solvent steam-assisted gravity drainage. Journal of Petroleum Science and Engineering, 59(1-2), 123-134.
Jiang, Q., Butler, R., & Yee, C. T. (1998, June). The steam and gas push (SAGP)-2: mechanism analysis and physical model testing. In Annual Technical Meeting. OnePetro.
Grant, B. F., & Szasz, S. E. (1954). Development of an underground heat wave for oil recovery. Journal of Petroleum Technology, 6(05), 23-33.
Howard, F. A. (1923). U.S. Patent No. 1,473,348. Washington, DC: U.S. Patent and Trademark Office.
Wolcott, E. R. (1923). U.S. Patent No. 1,457,479. Washington, DC: U.S. Patent and Trademark Office.
Ali, S. M. (1972). A current appraisal of in-situ combustion field tests. Journal of Petroleum Technology, 24(04), 477-486.
Brigham, W. E., Satman, A., & Soliman, M. Y. (1980). Recovery correlations for in-situ combustion field projects and application to combustion pilots. Journal of Petroleum Technology, 32(12), 2132-2138.
Chu, C. (1977). A study of fireflood field projects (includes associated paper 6504). Journal of Petroleum Technology, 29(02), 111-120.
Cheih, C. (1982). State-of-the-art review of fireflood field projects (includes associated papers 10901 and 10918). Journal of Petroleum Technology, 34(01), 19-36.
Lake, L. W. (1989). Enhanced oil recovery.
Martin, W. L., Alexander, J. D., & Dew, J. N. (1958). Process variables of in situ combustion. Transactions of the AIME, 213(01), 28-35.
Dietz, D. N., & Weijdema, J. (1968). Wet and partially quenched combustion. Journal of Petroleum Technology, 20(04), 411-415.
Greaves, M., & Al-Shamali, O. (1996). In situ combustion isc process using horizontal wells. Journal of Canadian Petroleum Technology, 35(04).
Greaves, M., Tuwil, A. A., & Bagci, A. S. (1993). Horizontal producer wells in in situ combustion (ISC) processes. Journal of Canadian Petroleum Technology, 32(04).
Kendall, R., Chopra, S., Lines, L. R., Schmitt, D. R., & Batzle, M. L. (2010). Using time-lapse seismic to monitor the toe-to-heel-air-injection (THAI™) heavy-oil production process. In Heavy Oils: Reservoir characterization and production monitoring (pp. 275-284). Society of Exploration Geophysicists.
Greaves, M., Xia, T. X., Turta, A. T., & Ayasse, C. (2000, April). Recent laboratory results of THAI and its comparison with other IOR processes. In SPE/DOE Improved Oil Recovery Symposium. OnePetro.
Ameli, F., Alashkar, A., & Hemmati-Sarapardeh, A. (2018). Thermal Recovery Processes. Fundamentals of Enhanced Oil and Gas Recovery from Conventional and Unconventional Reservoirs.
Suncor, E., & Canadian Heavy Oil Association. (2005). Proceedings of the 2005 SPE/PS-CIM/CHOA International Thermal Operations and Heavy Oil Symposium: Heavy Oil: Integrating the Pieces.
Moore, R. G., Laureshen, C. J., Mehta, S. A., Ursenbach, M. G., Belgrave, J. D. M., Weissman, J. G., & Kessler, R. V. (1999). A downhole catalytic upgrading process for heavy oil using in situ combustion. Journal of Canadian Petroleum Technology, 38(13).
Weissman, J. G., Kessler, R. V., Sawicki, R. A., Belgrave, J. D. M., Laureshen, C. J., Mehta, S. A., ... & Ursenbach, M. G. (1996). Down-hole catalytic upgrading of heavy crude oil. Energy & fuels, 10(4), 883-889.
Weissman, J. G., & Kessler, R. V. (1996). Downhole heavy crude oil hydroprocessing. Applied Catalysis A: General, 140(1), 1-16.
Greaves, M., & Xia, T. (2001, June). CAPRI-Downhole catalytic process for upgrading heavy oil: Produced oil properties and composition. In Canadian international petroleum conference. OnePetro.
Secure Fuels from Domestic Resources, The Continuing Evolution of America’s Oil Shale and Tar Sands Industries (U.S. Department of Energy, 2007), pp. 28–29
Husein, M. M., & Nassar, N. N. (2008). Nanoparticle preparation using the single microemulsions scheme. Current Nanoscience, 4(4), 370-380.
Niemeyer, C. M. (2001). Nanoparticles, proteins, and nucleic acids: biotechnology meets materials science. Angewandte Chemie International Edition, 40(22), 4128-4158.
Almao, P. P. (2012). In situ upgrading of bitumen and heavy oils via nanocatalysis. The Canadian Journal of Chemical Engineering, 90(2), 320-329.
Khoudiakov, M., Gupta, M. C., & Deevi, S. (2005). Au/Fe2O3 nanocatalysts for CO oxidation: a comparative study of deposition–precipitation and coprecipitation techniques. Applied Catalysis A: General, 291(1-2), 151-161.
Nassar, N. N. (2012). Iron oxide nanoadsorbents for removal of various pollutants from wastewater: an overview. Application of adsorbents for water pollution control, 81-118.
Nassar, N. N., & Husein, M. M. (2007). Study and modeling of iron hydroxide nanoparticle uptake by AOT (w/o) microemulsions. Langmuir, 23(26), 13093-13103.
Somorjai, G. A., Tao, F., & Park, J. Y. (2008). The nanoscience revolution: merging of colloid science, catalysis and nanoelectronics. Topics in Catalysis, 47(1), 1-14.
Wang, D., Xie, T., & Li, Y. (2009). Nanocrystals: Solution-based synthesis and applications as nanocatalysts. Nano Research, 2(1), 30-46.
Alivisatos, A. P., Johnsson, K. P., Peng, X., Wilson, T. E., Loweth, C. J., Bruchez, M. P., & Schultz, P. G. (1996). Organization of'nanocrystal molecules' using DNA. Nature, 382(6592), 609-611.
Bock, C., Paquet, C., Couillard, M., Botton, G. A., & MacDougall, B. R. (2004). Size-selected synthesis of PtRu nano-catalysts: reaction and size control mechanism. Journal of the American Chemical Society, 126(25), 8028-8037.
Galarraga, C. E. (2011). Upgrading Athabasca bitumen using submicronic NiWMo catalysts at conditions near to in-reservoir operation.
Gobe, M. (1983). Preparation and characterization of monodisperse magnetite sols in W/O microemulsion.
Hellweg, T. (2002). Phase structures of microemulsions. Current opinion in colloid & interface science, 7(1-2), 50-56.
Murray, C., Norris, D. J., & Bawendi, M. G. (1993). Synthesis and characterization of nearly monodisperse CdE (E= sulfur, selenium, tellurium) semiconductor nanocrystallites. Journal of the American Chemical Society, 115(19), 8706-8715.
Pluym, T. C., Powell, Q. H., Gurav, A. S., Ward, T. L., Kodas, T. T., Wang, L. M., & Glicksman, H. D. (1993). Solid silver particle production by spray pyrolysis. Journal of aerosol science, 24(3), 383-392.
Shen, S. C., Hidajat, K., Yu, L. E., & Kawi, S. (2004). Simple hydrothermal synthesis of nanostructured and nanorod Zn–Al complex oxides as novel nanocatalysts. Advanced Materials, 16(6), 541-545.
Yao, Y. L., Ding, Y., Ye, L. S., & Xia, X. H. (2006). Two-step pyrolysis process to synthesize highly dispersed Pt–Ru/carbon nanotube catalysts for methanol electrooxidation. Carbon, 44(1), 61-66.
Galarraga, C. E., Scott, C., Loria, H., & Pereira-Almao, P. (2012). Kinetic models for upgrading athabasca bitumen using unsupported NiWMo catalysts at low severity conditions. Industrial & engineering chemistry research, 51(1), 140-146.
Capek, I. (2004). Preparation of metal nanoparticles in water-in-oil (w/o) microemulsions. Advances in colloid and interface science, 110(1-2), 49-74.
Pereira, P., Marzin, R., Zacarias, L., Cordova, J., Carrazza, J., & Marino, M. (1999). U.S. Patent No. 5,885,441. Washington, DC: U.S. Patent and Trademark Office.
Vasquez, A. (2007, February). Synthesis, characterization and model reactivity of ultra dispersed catalysts for hydroprocessing. In Masters Abstracts International (Vol. 47, No. 03).
Thompson, J., Vasquez, A., Hill, J. M., & Pereira-Almao, P. (2008). The synthesis and evaluation of up-scalable molybdenum based ultra dispersed catalysts: effect of temperature on particle size. Catalysis letters, 123(1), 16-23.
Lapeira, C. C. (2009). Development of a new methodology for preparing nanometric Ni, Mo and NiMo catalytic particles using transient emulsions (Doctoral dissertation, University of Calgary, Department of Chemistry).
Molina, L., & Javier, H. (2009). Transport of catalytic particles immersed in fluid media through cylindrical geometries under heavy oil upgrading conditions (Vol. 70, No. 12).
Alamolhoda, S., Vitale, G., Hassan, A., Nassar, N. N., & Pereira Almao, P. (2019). Development and characterization of novel combinations of Ce‐Ni‐MFI solids for water gas shift reaction. The Canadian Journal of Chemical Engineering, 97(1), 140-151.
Li, Y., Fu, Q., & Flytzani-Stephanopoulos, M. (2000). Low-temperature water-gas shift reaction over Cu-and Ni-loaded cerium oxide catalysts. Applied Catalysis B: Environmental, 27(3), 179-191.
Hart, A., Shah, A., Leeke, G., Greaves, M., & Wood, J. (2013). Optimization of the CAPRI process for heavy oil upgrading: effect of hydrogen and guard bed. Industrial & Engineering Chemistry Research, 52(44), 15394-15406.
Shah, A. A., Fishwick, R. P., Leeke, G. A., Wood, J., Rigby, S. P., & Greaves, M. (2011). Experimental optimization of catalytic process in situ for heavy-oil and bitumen upgrading. Journal of Canadian Petroleum Technology, 50(11), 33-47.
Ortiz-Moreno, H., Ramírez, J., Sanchez-Minero, F., Cuevas, R., & Ancheyta, J. (2014). Hydrocracking of Maya crude oil in a slurry-phase batch reactor. II. Effect of catalyst load. Fuel, 130, 263-272.
Hart, A., Greaves, M., & Wood, J. (2015). A comparative study of fixed-bed and dispersed catalytic upgrading of heavy crude oil using-CAPRI. Chemical Engineering Journal, 282, 213-223.
Noguera, G., Araujo, S., Hernández, J., Rivas, A., Mendoza, D., & Castellano, O. (2012). A comparative activity study of a new ultra-dispersed catalyst system for a hydrocracking/hydrotreating technology using vacuum residue oil: Merey/Mesa. Chemical Engineering Research and Design, 90(11), 1979-1988.
Panariti, N., Del Bianco, A., Del Piero, G., & Marchionna, M. (2000). Petroleum residue upgrading with dispersed catalysts: Part 1. Catalysts activity and selectivity. Applied Catalysis A: General, 204(2), 203-213.
Speight, J. G. (1981). The Desulfurization of Heavy Oils and Residua, Mercel Dekker. Inc., NY, 119-127.
Leprince, P. (2001). Petroleum refining. Vol. 3 conversion processes (Vol. 3). Editions Technip.
Alemán-Vázquez, L. O., Torres-Mancera, P., Ancheyta, J., & Ramírez-Salgado, J. (2016). Use of hydrogen donors for partial upgrading of heavy petroleum. Energy & Fuels, 30(11), 9050-9060.
Albertazzi, S., Rodríguez-Castellón, E., Livi, M., Jiménez-López, A., & Vaccari, A. (2004). Hydrogenation and hydrogenolysis/ring-opening of naphthalene on Pd/Pt supported on zirconium-doped mesoporous silica catalysts. Journal of Catalysis, 228(1), 218-224.
Liu, Y., & Fan, H. (2002). The effect of hydrogen donor additive on the viscosity of heavy oil during steam stimulation. Energy & fuels, 16(4), 842-846.
Satchell Jr, D. P. (2009). U.S. Patent No. 7,594,990. Washington, DC: U.S. Patent and Trademark Office.
E.L. Wilson Jr, W.N. Mitchell, Hydrogen-donor coal liquefaction process, USA Patent US 4210518, 1980
Derbyshire, F. J., Mitchell, T. O., & Whitehurst, D. D. (1981). U.S. Patent No. 4,292,168. Washington, DC: U.S. Patent and Trademark Office.
Chen, Q., Gao, Y., Wang, Z. X., & Guo, A. J. (2014). Application of coker gas oil used as industrial hydrogen donors in visbreaking. Petroleum science and technology, 32(20), 2506-2511.
Langer, A. W., Stewart, J., Thompson, C. E., White, H. T., & Hill, R. M. (1962). Hydrogen donor diluent visbreaking of residua. Industrial & Engineering Chemistry Process Design and Development, 1(4), 309-312.
Hart, A., Lewis, C., White, T., Greaves, M., & Wood, J. (2015). Effect of cyclohexane as hydrogen-donor in ultradispersed catalytic upgrading of heavy oil. Fuel Processing Technology, 138, 724-733.
Martínez-Palou, R., de Lourdes Mosqueira, M., Zapata-Rendón, B., Mar-Juárez, E., Bernal-Huicochea, C., de la Cruz Clavel-López, J., & Aburto, J. (2011). Transportation of heavy and extra-heavy crude oil by pipeline: A review. Journal of petroleum science and engineering, 75(3-4), 274-282.
Billon, A., & Bigeard, P. H. (2001). Chapter 10. Hydrocracking. Petroleum refining.
Gates, B. C., Katzer, J. R., & Schuit, G. C. (1979). Chemistry of catalytic processes. Mcgraw-Hill College.
Galarraga, C. E., & Pereira-Almao, P. (2010). Hydrocracking of Athabasca bitumen using submicronic multimetallic catalysts at near in-reservoir conditions. Energy & Fuels, 24(4), 2383-2389.
Hashemi, R., Nassar, N. N., & Almao, P. P. (2014). Nanoparticle technology for heavy oil in-situ upgrading and recovery enhancement: Opportunities and challenges. Applied Energy, 133, 374-387.
Pauls, R. W., Abboud, S. A., & Turchenek, L. W. (1996). Pollutant deposition impacts on lichens, mosses, wood and soil in the Athabasca Oil Sands area.
Anderson, B. S., Chambers, J. I., & McMurray, D. R. (1995, June). Market Outlook For Athabasca Bitumen--The Economics of Location. In SPE International Heavy Oil Symposium. OnePetro.
Elahi, S. M., Scott, C. E., Chen, Z., & Pereira-Almao, P. (2019). In-situ upgrading and enhanced recovery of heavy oil from carbonate reservoirs using nano-catalysts: Upgrading reactions analysis. Fuel, 252, 262-271.
Hassan, A., Carbognani, L., & Pereira-Almao, P. (2008). Development of an alternative setup for the estimation of microcarbon residue for heavy oil and fractions: Effects derived from air presence. Fuel, 87(17-18), 3631-3639.
Hashemi, R., Nassar, N. N., & Pereira Almao, P. (2014). In situ upgrading of Athabasca bitumen using multimetallic ultradispersed nanocatalysts in an oil sands packed-bed column: Part 1. Produced liquid quality enhancement. Energy & fuels, 28(2), 1338-1350.
Hashemi, R., Nassar, N. N., & Pereira Almao, P. (2014). In situ upgrading of athabasca bitumen using multimetallic ultradispersed nanocatalysts in an oil sands packed-bed column: Part 2. Solid analysis and gaseous product distribution. Energy & fuels, 28(2), 1351-1361.
Breysse, M., Djega-Mariadassou, G., Pessayre, S., Geantet, C., Vrinat, M., Pérot, G., & Lemaire, M. (2003). Deep desulfurization: reactions, catalysts and technological challenges. Catalysis Today, 84(3-4), 129-138.
Farshid, D., Reynolds, B. Process for upgrading heavy oil using a highly active slurry catalyst composition. USA Patent, US7431823B2, 2008
M.R. de Agudelo, C. Galarraga, Catalyst for the simultaneous hydrodemetallization and hydroconversion of heavy hydrocarbon feedstocks. USA patent US4729980A, 1988
de Agudelo, M. R., & Galarraga, C. (1991). A stable catalyst for heavy oil processing: III. Activity and selectivity. The Chemical Engineering Journal, 46(2), 61-68.
Kennepohl, D., & Sanford, E. (1996). Conversion of Athabasca bitumen with dispersed and supported Mo-based catalysts as a function of dispersed catalyst concentration. Energy & Fuels, 10(1), 229-234.
Sanford, E. C. (1995). Conradson carbon residue conversion during hydrocracking of Athabasca bitumen: Catalyst mechanism and deactivation. Energy & fuels, 9(3), 549-559.
Newson, E. (1975). Catalyst deactivation due to pore-plugging by reaction products. Industrial & Engineering Chemistry Process Design and Development, 14(1), 27-33.
Altgelt, K. H. (1993). Composition and analysis of heavy petroleum fractions. CRC press.
Ancheyta, J., Rana, M. S., & Furimsky, E. (2005). Hydroprocessing of heavy petroleum feeds: Tutorial. Catalysis today, 109(1-4), 3-15.
Pereira-Almao, P. (2007, May). Fine tuning conventional hydrocarbon characterization to highlight catalytic upgrading pathways. In Proceedings of Variability of the Oil Sands Resource Workshop, Lake Louise, AB.
Lee, D. K., Koon, P. S., Yoon, W. L., Lee, I. C., & Woo, S. I. (1995). Residual oil hydrodesulfurization using dispersed catalysts in a carbon-packed trickle bed flow reactor. Energy & fuels, 9(1), 2-9.
Jordaan, S. M. (2011). Governance of Impacts to Land and Water Resources from Oil Sands Development in Alberta. Laboratory on International Law and Regulation, UC San Diego, La Jolla.
Gosselin, P., Hrudey, S. E., Naeth, M. A., Plourde, A., Therrien, R., Van Der Kraak, G., & Xu, Z. (2010). Environmental and health impacts of Canada’s oil sands industry. Royal Society of Canada, Ottawa, ON, 10.
McEachern, P. (2009). Environmental management of Alberta's oil sands.
Zamani, A., & Maini, B. (2009). Flow of dispersed particles through porous media—deep bed filtration. Journal of Petroleum Science and Engineering, 69(1-2), 71-88.
Zamani, A., Maini, B., & Pereira-Almao, P. (2010). Experimental study on transport of ultra-dispersed catalyst particles in porous media. Energy & Fuels, 24(9), 4980-4988.
Hashemi, R., Nassar, N. N., & Pereira-Almao, P. (2012). Transport behavior of multimetallic ultradispersed nanoparticles in an oil-sands-packed bed column at a high temperature and pressure. Energy & Fuels, 26(3), 1645-1655.
Adamczyk, Z., & Van De Ven, T. G. (1981). Deposition of particles under external forces in laminar flow through parallel-plate and cylindrical channels. Journal of Colloid and Interface Science, 80(2), 340-356.
Brady, J. F. (1994). The long-time self-diffusivity in concentrated colloidal dispersions. Journal of Fluid Mechanics, 272, 109-134.
Sarimeseli, A., & Kelbaliyev, G. (2004). Modeling of the break-up of deformable particles in developed turbulent flow. Chemical engineering science, 59(6), 1233-1240.
Yoshioka, N., Karaoka, C., & Emi, H. (1972). On the deposition of aerosol particles to the horizontal pipe wall from turbulent stream. Kagaku Kogaku, 36(9), 1010-1016.
Hashemi, R., Nassar, N. N., & Pereira Almao, P. (2013). Enhanced heavy oil recovery by in situ prepared ultradispersed multimetallic nanoparticles: A study of hot fluid flooding for Athabasca bitumen recovery. Energy & Fuels, 27(4), 2194-2201.
Ancheyta, J., Sánchez, S., & Rodríguez, M. A. (2005). Kinetic modeling of hydrocracking of heavy oil fractions: A review. Catalysis Today, 109(1-4), 76-92.
Gray, M. R. (1990). Lumped kinetics of structural groups: hydrotreating of heavy distillate. Industrial & engineering chemistry research, 29(4), 505-512.
Martens, G. G., & Marin, G. B. (2001). Kinetics for hydrocracking based on structural classes: Model development and application. AIChE journal, 47(7), 1607-1622.
Singh, J., Kumar, M. M., Saxena, A. K., & Kumar, S. (2005). Reaction pathways and product yields in mild thermal cracking of vacuum residues: A multi-lump kinetic model. Chemical Engineering Journal, 108(3), 239-248.
Gray, M. R. (2015). Upgrading oilsands bitumen and heavy oil. University of Alberta.
Alhumaizi, K. I., Akhmedov, V. M., Al-Zahrani, S. M., & Al-Khowaiter, S. H. (2001). Low temperature hydrocracking of n-heptane over Ni-supported catalysts: study of global kinetics. Applied Catalysis A: General, 219(1-2), 131-140.
Krishna, R., & Saxena, A. K. (1989). Use of an axial-dispersion model for kinetic description of hydrocracking. Chemical engineering science, 44(3), 703-712.
Sánchez, S., Rodríguez, M. A., & Ancheyta, J. (2005). Kinetic model for moderate hydrocracking of heavy oils. Industrial & engineering chemistry research, 44(25), 9409-9413.
Scherzer, J., & Gruia, A. J. (1996). Hydrocracking science and technology. Crc Press.
Köseoḡlu, R. Ö., & Phillips, C. R. (1987). Kinetics of non-catalytic hydrocracking of Athabasca bitumen. Fuel, 66(6), 741-748.
Köseoḡlu, R. Ö., & Phillips, C. R. (1988). Kinetic models for the non-catalytic hydrocracking of Athabasca bitumen. Fuel, 67(7), 906-915.
Loria, H., Trujillo-Ferrer, G., Sosa-Stull, C., & Pereira-Almao, P. (2011). Kinetic modeling of bitumen hydroprocessing at in-reservoir conditions employing ultradispersed catalysts. Energy & Fuels, 25(4), 1364-1372.
Da Silva De Andrade, F. J. (2014). Kinetic modeling of catalytic in situ upgrading for Athabasca bitumen, deasphalting pitch and vacuum residue (Master's thesis, Graduate Studies).
Nassar, N. N., Hassan, A., Luna, G., & Pereira-Almao, P. (2013). Kinetics of the catalytic thermo-oxidation of asphaltenes at isothermal conditions on different metal oxide nanoparticle surfaces. Catalysis today, 207, 127-132.
Nassar, N. N., Hassan, A., Luna, G., & Pereira-Almao, P. (2013). Comparative study on thermal cracking of Athabasca bitumen. Journal of thermal analysis and calorimetry, 114(2), 465-472.
Nassar, N. N., Hassan, A., & Pereira-Almao, P. (2011). Application of nanotechnology for heavy oil upgrading: Catalytic steam gasification/cracking of asphaltenes. Energy & Fuels, 25(4), 1566-1570.
Nassar, N. N., Hassan, A., & Pereira-Almao, P. (2012). Thermogravimetric studies on catalytic effect of metal oxide nanoparticles on asphaltene pyrolysis under inert conditions. Journal of thermal analysis and calorimetry, 110(3), 1327-1332.
Nassar, N. N., Hassan, A., & Vitale, G. (2014). Comparing kinetics and mechanism of adsorption and thermo-oxidative decomposition of Athabasca asphaltenes onto TiO2, ZrO2, and CeO2 nanoparticles. Applied Catalysis A: General, 484, 161-171.
Nares, H. R., Schachat, P., Ramirez-Garnica, M. A., Cabrera, M., & Noe-Valencia, L. (2007, April). Heavy-crude-oil upgrading with transition metals. In Latin American & caribbean petroleum engineering conference. OnePetro.
Peluso, E. (2011). Hydroprocessing full-range of heavy oils and bitumen using ultradispersed catalysts at low severity (Vol. 73, No. 05).
Bergeson, L. L., & Auerbach, B. E. T. H. A. M. I. (2004). Reading the small print. In Environmental Forum (Vol. 21, No. 2, pp. 30-32). THE ENVIRONMENTAL LAW INSTITUTE.
Morris, J., & Willis, J. (2007). US Environmental Protection Agency nanotechnology white paper. US Environmental Protection Agency, Washington, DC.
Kahan, D. M., & Rejeski, D. (2009). PRoject on emeRging nanotechnologies.
Nel, A., Xia, T., Mädler, L., & Li, N. (2006). Toxic potential of materials at the nanolevel. science, 311(5761), 622-627.
Thomas, T., Thomas, K., Sadrieh, N., Savage, N., Adair, P., & Bronaugh, R. (2006). Research strategies for safety evaluation of nanomaterials, part VII: evaluating consumer exposure to nanoscale materials. Toxicological Sciences, 91(1), 14-19.
Breggin, L. K., & Carothers, L. (2006). Governing uncertainty: the nanotechnology environmental, health, and safety challenge. Colum. J. Envtl. L., 31, 285.
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Ashoorian, S., Montoya, T., Nassar, N.N. (2021). Nanoparticles for Heavy Oil Upgrading. In: Nassar, N.N., Cortés, F.B., Franco, C.A. (eds) Nanoparticles: An Emerging Technology for Oil Production and Processing Applications. Lecture Notes in Nanoscale Science and Technology, vol 32. Springer, Cham. https://doi.org/10.1007/978-3-319-12051-5_6
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DOI: https://doi.org/10.1007/978-3-319-12051-5_6
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