Abstract
Self-assembled monolayers (SAMs) have played and still continue playing a major role in the control of the interface behaviors, especially in fluidic and as lubrication coatings. This chapter introduces and focuses on frictional properties of molecular homogeneous thin films; particularly the influence of chain length, terminal group and packing state of SAMs on the one hand, and that of the environmental and experimental conditions on the other hand, on energy dissipation during friction. Then, we will address the important issue of nanoscale heterogeneities and their influence on the frictional behavior and nanotribological performance of SAMs, using binary molecular films of both regular and random distribution of the heterogeneities. Because real surfaces are often heterogeneous in their chemical composition, these nanoscale heterogeneous SAMs provide good model systems to study and tune the frictional properties of tribological coatings.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
H.-S. Ahn, P.D. Cuong, S. Park, Y.-W. Kim, J.-C. Lim, Wear 255, 819 (2003)
M.K. Corbierre, N.S. Cameron, R.B. Lennox, Langmuir 20, 2867 (2004)
J.J. Storhoff, S.S. Marla, P. Bao et al., Biosens. Bioelectron. 19, 875 (2004)
H.I. Kim, T. Koin, T.R. Lee, S.S. Perry, Langmuir 13, 7192 (1997)
M.J. Azzopardi, H. Arribart, J. Adhes. 46, 103 (1994)
R.H. Yoon, D.A. Guzonas, Colloid Surf. A: Physicochem. Eng. Aspects 87, 163 (1994)
C.R. Tripp, M.L. Hair, Langmuir 8, 1120 (1992)
P. Silberzan, L. Leger, D. Ausserré, J.J. Benattar, Langmuir 7, 1647 (1991)
D. Angst, G.W. Simmons, Langmuir 7, 2236 (1991)
C.R. Kessel, S. Granick, Langmuir 7, 532 (1991)
A.G. Carson, S. Granick, J. Mat. Res. 5, 1745 (1990)
D.K. Schwartz, S. Stienberg, J. Israelchvili, J. Azasadzinski, Phys. Rev. Lett. 69, 3354 (1992)
J.V. Davidovits, V. Pho, P. Silberzan, M. Goldman, Surf. Sci. 352–354, 369 (1996)
J. Gun, J. Sagiv, J. Colloid Interface Sci. 112, 457 (1986)
E. Delamerche, B. Michel, C. Gerber et al., Langmuir 10, 2869 (1994)
K. Kendall, Nature 319, 203 (1986)
A. Lio, D.H. Charych, M. Salmeron, J. Phys. Chem. B 101, 3800 (1997)
X. Xiao, J. Hu, D.H. Charych, M. Salmeron, Langmuir 12, 235 (1996)
M.T. McDermott, J.-B.D. Green, M.D. Porter, Langmuir 13, 2504 (1997)
D. Dominguez, R.L. Mowery, N.H. Turner, Tribol. Trans. 37(1), 59 (1994)
H.J. Eyring, J. Chem. Phys. 3, 107 (1935)
D. Tabor, in Fundamentals of Friction: Macroscopic and Microscopic Processes, ed. by I.L. Singer, H.M. Pollock (Kluwer Academic, Dordrect, The Netherlands, 1992), p. 3
B. Bhushan, A.V. Kulkarni, V.N. Koinkar et al., Langmuir 11, 3189 (1995)
H. Liu, B. Bhushan, Ultramicroscopy 91, 185 (2002)
A.J. Kinloch, Adhesion and Adhesives (Chapman and Hall, New York, 1987)
C.J. Drummond, G. Georgaklis, C. Chan, Langmuir 12, 2617 (1996)
H.I. Kim, T. Koini, T.R. Lee, S.S. Perry, Langmuir 13, 7192 (1997)
M. Graupe, T. Koini, H.I. Kim, N.G. Arg, Y.F. Miura, M. Takenaga, S.S. Perry, T.R. Lee, Langmuir 15, 3179 (1999)
C.O. Timmons, W.A. Zisman, J. Colloid, Interface Sci. 22, 165 (1966)
T. Stoebe, P. Mach, S. Grantz, C.C. Huang, Phys. Rev. 53, 1662 (1996)
M. Graupe, T. Koini, H.I. Kim, N. Garg, Y.F. Miura, M. Takenaga, S.S. Perry, T.R. Lee, Colloids Surf. A: Physicochem. Eng. Aspects 154, 239 (1999)
B.N.J. Person, Phys. Rev. B 44, 3277 (1991)
M.K. Chaudhury, M.J. Owen, Langmuir 9, 29 (1993)
H. Yoshizawa, Y-L. Chen, J. Israelachvili J. Phys. Chem. 97, 4128 (1993)
R.M. Overney, E. Meyer, J. Frommer, H.-J. Giintherodt, M. Fujihira, H. Takano, Y. Gotoh, Langmuir 10, 1281 (1994)
M. Garcia-Parajo, C. Longo, J. Servat, P. Gorostiza, F. Sanz, Langmuir 13, 2333 (1997)
B. Bhushan, H. Liu, Phys. Rev. B 63, 245412 (2001)
F. Tian, X. Xiao, M.M. Moy, C. Wang, C. Bai, Langmuir 15, 244 (1999)
E. Riedo, F. Lévy, H. Brune, Phys. Rev. Lett. 88, 185505 (2002)
Y. Liu, D.F. Evans, Q. Song, D.W. Grainger, Langmuir 12, 1235 (1996)
R. Yerushalmi-Rozen, J. Klein, Langmuir 11, 2806 (1995)
S.R. Cohen, R. Naaman, J. Sagiv, J. Phys. Chem. 90, 3054 (1986)
M.C. Yeh, E.J. Kramer, R. Sharma, W. Zhao, M.H. Rafailovich, J. Sokolov, J.D. Brock, Langmuir 12, 2747 (1996)
E. Gnecco et. al., Phys. Rev. Lett. 84, 1172 (2000)
Y. Liu, T. Wu, D.F. Evans, Langmuir 10, 2241 (1994)
J. Wagner, T. Kirner, G. Mayer, J. Albert, J.M. Köhler, Chem. Eng. J. (Article in Press)
G.B. Khomutov, V.V. Kislov, M.N. Antipina, R.V. Gainutdinov et al., Microelectron. Eng. 69, 373 (2003)
W. Li, L. Huo, D. Wang, G. Zeng, S. Xi, B. Zhao, J. Wang, Y. Shen, Z. Lu, Colloids Surf. A: Physicochem. Eng. Aspects 175, 217 (2000)
L.M. Tender, R.L. Worley, H. Fan, G.P. Lopez, Langmuir 12, 5515 (1996)
R. Klauser, M.-L. Huang, S.-C. Wang, C.-H. Chen, T.J. Chuang, A. Terfort, M. Zharnikov, Langmuir 20, 2050 (2004)
M.M. Alkaisi, W. Jayatissa, M. Konijn, Curr. Appl. Phys. 4, 111 (2004)
M. Tormen, L. Businaro, M. Altissimo, F. Romanato, S. Cabrini, F. Perennes, R. Proietti, H-B. Sun, S. Kawata, E.D. Fabrizio, Microelectron. Eng. (2004) (in press)
O. Cherniavskaya, A. Adzic, C. Knutson, B.J. Gross, L. Zang, R. Liu, D.M. Adams, Langmuir 18, 7029 (2002)
M.R. Shadnam, S.E. Kirkwood, R. Fedosejevs, A. Amirfazli, Langmuir 20, 2667 (2004)
R.D. Piner, J. Zhu, F. Xu, S. Hong, C.A. Mirkin, Science 283, 661 (1999)
S. Hong, J. Zhu, C.A. Mirkin, Science 286, 523 (1999)
O.J. Schueller, D.C. Duffy, J.A. Rogers, S.T. Brittain, G.M. Whitesides, Sens. Actuators 78, 149 (1998)
H. Haidara, K. Mougin, J. Schultz, Langmuir 16, 7773 (2000)
J.P. Folkers, P.E. Laibnis, G.M. Whitesides, Langmuir 8, 1330 (1992)
M.J. Wirth, R.W. Fairbank, H.O. Fatunmbi, Science 275, 44 (1997)
S.P. Li, A. Lebib, D. Peyrade, M. Natali, Y. Chen, Appl. Phys. Lett. 77, 2743 (2000)
Y. Chen, A. Lebib, S. Li, A. Pépin, D. Peyrade, M. Natali, E. Cambril, Eur. Phys. J. AP 12, 223 (2000)
M. Natali, A. Lebib, E. Cambril, Y. Chen, I.L. Prejbeanu, K. Ounadjela, J. Vac. Sci. Technol. B 19, 2779 (2001)
Y. Xia, G.M. Whitesides, Angew. Chem. Int. Ed. 37, 550 (1990)
S.Y. Chou, P.R. Krauss, P.J. Renstrom, Appl. Phys. Lett. 67, 3114 (1995)
K. Mougin, G. Castelein, H. Haidara, Tribol. Lett. 17(1), 11 (2004)
J. Drelich, J.L. Wilbur, J.D. Miller, G.M. Whitesides, Langmuir 1996, 12 (1913)
F.M. Fowkes, Contact Angle: Wettability and Adhesion (American Chemical Society, Washington D.C., 1964)
H. Haidara, K. Mougin, J. Schultz, Langmuir 16, 9121 (2000)
Y.G. Zhou, H. Fan, T. Fong, G.P. Lopez, Langmuir 14, 660 (1998)
H. Schonherr, G.J. Vansco, Mat. Sci. Eng. C 8–9, 243 (1999)
S. Gauthier, J.P. Aimé, T. Bouhacina, A.J. Attias, B. Desbat, Langmuir 12, 5126 (1996)
B. Bushan, J.N. Israelachvili, U. Landman, Nature 374, 607 (1995)
M. Schoen, C. Rhykerd, D. Diestler, J. Cushamn, Science 245, 1223 (1989)
A. Sidorenko, H.-S. Ahn, D.-I. Kimb, H. Yanga, V.V. Tsukruk,, H., Wear 252, 946 (2002)
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2015 Springer International Publishing Switzerland
About this chapter
Cite this chapter
Mougin, K., Hamidou, H. (2015). Nanoscale Friction of Self-assembled Monolayers. In: Gnecco, E., Meyer, E. (eds) Fundamentals of Friction and Wear on the Nanoscale. NanoScience and Technology. Springer, Cham. https://doi.org/10.1007/978-3-319-10560-4_22
Download citation
DOI: https://doi.org/10.1007/978-3-319-10560-4_22
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-319-10559-8
Online ISBN: 978-3-319-10560-4
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)