Abstract
The nonlinear viscoelastic behavior of cured rubber is quite different from that of uncured compound, since the presence of crosslink networks. The factors for the influence of the crosslink networks on the nonlinear viscoelastic behaviors of cured rubbers are very complex and obscure. One of the reasons is that the crosslink networks may be consisted of several different types of networks. However, there are few literatures reporting the nonlinear viscoelastic behaviors of cured rubbers with mutle-networks. We reviewed the literatures dedicated to the topic of the non-linear viscoelasticity of simplest mutle-networks—double-network and summarized the useful information as much as possible in the present paper. Song’s transient double-network model, double-network formed by twice curing and the specific crosslink network formed in metal salts of unsaturated carboxylic acids reinforced rubbers are introduced in detail.
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References
Medalia AI (1978) Effects of carbon black on dynamic properties of rubber. Rubber Chem Technol 51(3):437–523
Wang MJ (1998) Effect of polymer-filler and filler-filler interactions on dynamic properties of filled vulcanizates. Rubber Chem Technol 71(3):520–589
Meier JG, Kluppel M (2008) Carbon Black Networking in Elastomers Monitored by Dynamic Mechanical and Dielectric Spectroscopy. Macromol Mater Eng 293(1):12–38
Vieweg S, Unger R, Heinrich G, Donth E (1999) Comparison of dynamic shear properties of styrene-butadiene vulcanizates filled with carbon black or polymeric fillers. J Appl Polym Sci 73(4):495–503
Payne AR (1965) In Kraus G (ed) Reinforcement of elastomers. Interscience Publisher, New York (Chap 3)
Payne AR (1964) The role of hysteresis in polymers. Rubber J 146(1):36–49
Zhao F, Shi XY, Chen X, Zhao SG (2010) Interaction of Vulcanization and Reinforcement of CB on Dynamic Property of NR Characterized by RPA2000. J Appl Polym Sci 117(2):1168–1172
Song MS, Wen Z, Hu GX (1999) Rheological behavior of polymer melts and concentrated solutions. part V: a new molecular theory of non-linear viscoelasticity for polymeric suspensions. J Mater Sci Technol 15(2):169–177
Collier AA, Clegg DW (1988) Rheological measurement. Elsevier Appl Sci, New York, 483
Stephen TS, Winter HH, Gottlieb M (1988) The steady shear viscosity of filled polymeric liquids described by a linear superposition of two relaxation mechanisms. Rheol Acta 27(3):263–272
Song MS, He ZR (1990) The molecular theory of viscoelasticity for thermoplastic elastomer SBS(SIS) at large deformations. Rheol Acta 29(1):31–45
Song MS (1989) Studies on the relationship between the network structure and the mechanical properties of rubber vulcanizates (1) theory of elasticity for rubber vulcanizates with carbon black fillers in large deformation. Chin J Chem Eng 4(2):162–177
Roland CM, Warzel ML (1990) Orientation effects in rubber double networks. Rubber Chem Technol 63(2):285–297
Santangelo PG, Roland CM (1994) The mechanical behavior of double network elastomers. Rubber Chem Technol 67(2):359–365
Santangelo PG, Roland CM (1995) Failure properties of natural rubber double networks. Rubber Chem Technol 68(1):124–131
Roland CM, Peng KL (1991) Electrical conductivity in rubber double networks. Rubber Chem Technol 64(5):790–800
Hamed GR, Huang MY (1998) Tensile and tear behavior of anisotropic double networks of a black-filled natural rubber vulcanizate. Rubber Chem Technol 71(5):846–860
Kaang S, Nah C (1998) Fatigue crack growth of double-networked natural rubber. Polymer 39(11):2209–2214
Hvidt S, Kramer O, Batsberg W, Ferry JD (1980) Contribution of entanglements to the equilibrium modulus of 1,2-polybutadiene networks at small strains and estimate of the front factor. Macromolecules 13(4):933–939
Batsberg W, Kramer O (1981) A direct experimental determination of the elastic contribution of chain entangling in a tightly cross-linked elastomer. J Chem Phys 74(11):6507–6508
Granick S, Ferry JD (1983) Entangled chain structure trapped in a styrene-butadiene random copolymer by cross-linking in simple extension. Macromolecules 16(1):39–45
Kramer O (1988) Selective quenching of large-scale molecular motions by cross-linking in the strained state. ACS Symp Ser 367:48–58
Twardowski TE, Gaylord RJ (1989) The localization model of rubber elasticity and the stress-strain behavior of a network formed by cross-linking a deformed melt. Polym Bull 21(4):393–400
Gaylord RJ, Twardowski TE, Douglas JF (1988) The localization model of rubber elasticity and the deformation of a network formed by cross-linking a strained melt. Polym Bull 20(3):305–310
Tobolsky AV, Takahashi Y, Naganuma S (1972) Effect of additional cross-linking of continuous chemical stress relaxation of cis-polybutadiene. Polym J 3(1):60–66
Gillen KT (1988) Effect of cross-links which occur during continuous chemical stress-relaxation. Macromolecules 21(2):442–446
Flory PJ (1956) Theory of elastic mechanisms in fibrous proteins. J Am Chem Soc 78(20):5222–5235
Mandelkern L, Roberts DE, Diorio AF, Posner AS (1959) Dimensional changes in system of fibrous macromolecules: polyethylene. J Am Chem Soc 81(16):4148–4157
Hikmet RAM, Lub J, Vanderbrink PM (1992) Structure and mobility within anisotropic networks obtained by photopolymerization of liquid crystal molecules. Macromolecules 25(16):4194–4199
Reichert WF, Goritz D, Duschl EJ (1993) The double network, a model describing filled elastomers. Polymer 34(6):1216–1221
Mott PH, Roland CM (2000) Mechanical and optical behavior of double network rubbers. Macromolecules 33(11):4132–4137
Kaang S, Gong D, Nah C (1997) Some physical characteristics of double-networked natural rubber. J Appl Polym Sci 65(5):917–924
Aprem AS, Joseph K, Thomas S (2004) Studies on double networks in natural rubber vulcanizates. J Appl Polym Sci 91(2):1068–1076
Wang J, Hamed GR, Umetsu K, Roland CM (2005) The Payne effect in double betwork elastomers. Rubber Chem Technol 78(1):76–83
Flory PJ (1960) Elasticity of polymer networks cross-linked in state of strain. Trans Faraday Soc 56:722–743
Baxandall LG, Edwards SF (1988) Deformation-dependent properties of polymer networks constructed by addition of crosslinks under strain. Macromolecules 21(6):1763–1772
Termonia Y (1990) Molecular model for the mechanical properties of elastomers. 3. networks cross-linked in a state of strain. Macromolecules 23(7):1976–1979
Dontsov A, Decandia F, Amelino L (1972) Elastic properties and structure of polybutadiene vulcanized with magnesium methaceylate. J Appl Polym Sci 16(2):505–518
Saito Y, Nishimura K, Asada M, Toyoda A (1994) Polymerization behavior of zinc methacrylate study of zinc methacrylate/rubber/peroxide compounds; Part 2. J Jpn Rubber Soc 67(12):867–872
Gao GX, Zhang ZC, Zheng YS, Jin ZH (2009) Effect of magnesium methacrylateand zinc methacrylate on bond properties of thermal insulation material based on NBR/EPDM blends. J Appl Polym Sci 113(6):3901–3909
Yin DH, Zhang Y, Zhang YX, Peng ZL, Fan Y, Sun K (2002) Reinforcement of peroxide-cured styrene-butadiene rubber vulcanizates by mathacrylic acid and magnesium oxide. J Appl Polym Sci 85(13):2667–2676
Yin DH, Zhang Y, Peng ZL, Zhang YX (2003) A comparison between the SBR vulcanizates reinforced by magnesium methacrylate added directly or prepared in situ. Eur Polym J 39(1):99–105
Lu YL, Liu L, Yang C, Tian M, Zhang LQ (2005) The morphology of zinc dimethacrylate reinforced elastomers investigated by SEM and TEM. Eur Polym J 41(3):577–588
Peng ZL, Liang X, Zhang YX, Zhang Y (2002) Reinforcement of EPDM by in situ prepared zinc dimethacrylate. J Appl Polym Sci 84(7):1339–1345
Yuan XH, Peng ZL, Zhang Y, Zhang YX (1999) The properties and structure of peroxide-cured NBR containing magnesium methacrylate. Polym Polym Comp 7(6):431–436
Du AH, Peng ZL, Zhang Y, Zhang YX (2003) Properties of EVM vulcanizates reinforced by in situ prepared sodium methacrylate. J Appl Polym Sci 89(8):2192–2200
Nie YJ, Huang GS, Qu LL, Zhang P, Weng GS, Wu JR (2010) Cure kinetics and morphology of natural rubber reinforced by the in situ polymerization of zinc dimethacrylate. J Appl Polym Sci 115(1):99–106
Du AH, Peng ZL, Zhang Y, Zhang YX (2002) Effect of magnesium methacrylate on the mechanical properties of EVM vulcanizate. Polym Test 21(8):889–895
Lu YL, Liu L, Shen DY, Yang C, Zhang LQ (2004) Infrared study on in situ polymerization of zinc dimethacrylate in poly(α-octylene-co-ethylene) elastomer. Polym Int 53(6):802–808
Klingender RC, Oyama M, Saito Y (1990) High-strength compound of highly saturated nitrile and its applications. Rubber World 202(3):26–31
Lu YL, Liu L, Tian M, Geng HP, Zhang LQ (2005) Study on mechanical properties of elastomers reinforced by zinc dimethacrylate. Eur Polym J 41(3):589–598
Du AH, Peng ZL, Zhang Y, Zhang YX (2004) Fracture morphology and mechanical properties of ethylene/vinyl acetate rubber vulcanizates reinforced by in situ prepared sodium methacrylate. J Polym Sci B 42(9):1715–1724
Chen YK, Xu CH (2012) Stress-strain behaviors and crosslink networks studies of natural rubber-zinc dimethacrylate composites. J Macro Sci B Phys 51(7):1384–1400
Xu CH, Chen YK, Cao LM, Wang YP, Zeng XR (2013) Study of the crosslinking evolution of the styrene-butadiene rubber/zinc dimethacrylate based on dissolution/swelling experiments. J Macro Sci B Phys 52(2):319–333
Xu CH, Chen YK, Huang J, Zeng XR, Ding JP (2012) Thermal aging on mechanical properties and crosslink network of natural nubber/zinc dimethacrylate composites. J Appl Polym Sci 124(3):2240–2249
Xu CH, Chen YK, Zeng XR (2012) A Study on the crosslink network evolution of magnesium dimethacrylate/natural rubber composite. J Appl Polym Sci 125(3):2449–2459
Chen YK, Xu CH, Wang YP (2012) Viscoelasticity behaviors of lightly cured natural rubber/zinc dimethacrylate composites. Polym Compos 33(6):967–975
Chen YK, Xu CH (2012) Specific nonlinear viscoelasticity behaviors of natural rubber and zinc dimethacrylate composites due to multi-crosslinking bond interaction by using rubber process analyzer 2000. Polym Compos 32(10):1593–1600
Xu CH, Chen YK, Cao LM, Zeng XR (2012) Dynamic viscoelasticity behaviors of magnesium dimethacrylate/natural rubber composites with different cure extent. Polym Compos 33(7):1244–1253
Chen YK, Xu CH (2011) Crosslink network evolution of nature rubber/zinc dimethacrylate composite during peroxide vulcanization. Polym Compos 32(10):1505–151
Chen YK, Xu CH (2012) Stress softening of NR reinforced by in situ prepared zinc dimethacrylate. J Appl Polym Sci 123(2):833–841
Roozbeh D, Mikhail I (2009) A network evolution model for the anisotropic Mullins effect in carbon black filled rubbers. Int J Solids Struct 46(16):2967–2977
Jong L (2005) Dynamic mechanical properties of soy protein filled elastomers. J Polym Environ 13(4):329–338
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Chen, Y., Xu, C. (2014). Effect of Double Networking on Non-Linear Viscoelasticity of Elastomers. In: Ponnamma, D., Thomas, S. (eds) Non-Linear Viscoelasticity of Rubber Composites and Nanocomposites. Advances in Polymer Science, vol 264. Springer, Cham. https://doi.org/10.1007/978-3-319-08702-3_7
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DOI: https://doi.org/10.1007/978-3-319-08702-3_7
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