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Diradical Character View of (Non)Linear Optical Properties

  • Masayoshi Nakano
Chapter
Part of the SpringerBriefs in Molecular Science book series (BRIEFSMOLECULAR)

Abstract

In this chapter, we clarify the diradical character dependences of (hyper)polarizabilities, which are molecular origins of (non)linear optical responses, in static and resonant cases based on the diradical character dependences of excitation energies and properties of two-site symmetric and asymmetric diradical models with two electrons in two active orbitals. The analysis results highlight the differences of optical response properties between open-shell and closed-shell molecular systems, and contribute to the construction of novel molecular design guidelines for highly efficient nonlinear optical systems.

Keywords

Nonlinear optics Hyperpolarizability Diradical character Excitation energy Transition moment Molecular design 

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Copyright information

© The Author(s) 2014

Authors and Affiliations

  1. 1.Division of Chemical Engineering, Department of Materials Engineering Science, Graduate School of Engineering ScienceOsaka UniversityToyonakaJapan

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