Skip to main content

MWI Synthesis and Characterization of RGO-AgNPs/Polymethyl Methacrylate Nanocomposites

  • Conference paper
  • First Online:
International Multidisciplinary Microscopy Congress

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 154))

  • 1123 Accesses

Abstract

Polymethyl methacrylate and reduced graphene oxide/silver (PMMA/RGO/(RGO))AgNPs) nanocomposites were prepared via in situ bulk polymerization method using two different preparation techniques. In the first approach, mixture of silver nitrate, Hydrazine hydrate and polymethyl methacrylate containing graphene oxide (PMMA/GO) were reduced by microwave irradiation (MWI) to obtain R-(GO-PMMA)/AgNPs nanocomposites. In the second approach, a mixture of (RGO/AgNPs) nanocomposite, which was produced by microwave, and MMA monomers were polymerized using in situ bulk polymerization method to obtain PMMA-RGO/AgNPs nanocomposites. The two nanocomposites were compared and characterized by FTIR, XRD, XPS, HRTEM, and TGA. The results indicate that the nanocomposites obtained using the first approach, which involved MWI, had a better morphology and dispersion with enhanced thermal stability compared with the nanocomposites pre-pared without MWI.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. A.A. Balandin, S. Ghosh, W.Z. Bao, I. Calizo, D. Teweldebrhan, F. Miao, C.N. Lau, Superior thermal conductivity of single-layer graphene. Nano Lett. 8(3), 902–907 (2008). doi:10.1021/nl0731872

    Article  ADS  Google Scholar 

  2. S. Park, R.S. Ruoff, Chemical methods for the production of graphenes. Nat. Nanotechnol. 4(4), 217–224 (2009). doi:10.1038/nnano.2009.58

    Article  ADS  Google Scholar 

  3. S. Stankovich, D.A. Dikin, G.H.B. Dommett, K.M. Kohlhaas, E.J. Zimney, E.A. Stach, R.D. Piner, S.T. Nguyen, R.S. Ruoff, Graphene-based composite materials. Nature 442(7100), 282–286 (2006). doi:10.1038/nature04969

    Article  ADS  Google Scholar 

  4. T. Ramanathan, A.A. Abdala, S. Stankovich, D.A. Dikin, M. Herrera-Alonso, R.D. Piner, D.H. Adamson, H.C. Schniepp, X. Chen, R.S. Ruoff, S.T. Nguyen, I.A. Aksay, R.K. Prud’homme, L.C. Brinson, Functionalized graphene sheets for polymer nanocomposites. Nat. Nanotechnol. 3(6), 327–331 (2008). doi:10.1038/nnano.2008.96

    Article  ADS  Google Scholar 

  5. D.A. Dikin, S. Stankovich, E.J. Zimney, R.D. Piner, G.H.B. Dommett, G. Evmenenko, S.T. Nguyen, R.S. Ruoff, Preparation and characterization of graphene oxide paper. Nature 448(7152), 457–460 (2007). doi:10.1038/nature06016

    Article  ADS  Google Scholar 

  6. D.R. Paul, L.M. Robeson, Polymer nanotechnology: nanocomposites. Polymer 49(15), 3187–3204 (2008). doi:10.1016/j.polymer.2008.04.017

    Article  Google Scholar 

  7. J.R. Potts, D.R. Dreyer, C.W. Bielawski, R.S. Ruoff, Graphene-based polymer nanocomposites. Polymer 52(1), 5–25 (2011). doi:10.1016/j.polymer.2010.11.042

    Article  Google Scholar 

  8. C. Lee, X.D. Wei, J.W. Kysar, J. Hone, Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321(5887), 385–388 (2008). doi:10.1126/science.1157996

    Article  ADS  Google Scholar 

  9. H.M.A. Hassan, V. Abdelsayed, A. Khder, K.M. AbouZeid, J. Terner, M.S. El-Shall, S.I. Al-Resayes, A.A. El-Azhary, Microwave synthesis of graphene sheets supporting metal nanocrystals in aqueous and organic media. J. Mater. Chem. 19(23), 3832–3837 (2009). doi:10.1039/b906253j

    Article  Google Scholar 

  10. J.Y. Jang, M.S. Kim, H.M. Jeong, C.M. Shin, Graphite oxide/poly(methyl methacrylate) nanocomposites prepared by a novel method utilizing macroazoinitiator. Compos. Sci. Technol. 69(2), 186–191 (2009). doi:10.1016/j.compscitech.2008.09.039

    Article  Google Scholar 

  11. S. Pasupuleti, G. Madras, Ultrasonic degradation of poly (styrene-co-alkyl methacrylate) copolymers. Ultrason. Sonochem. 17(5), 819–826 (2010). doi:10.1016/j.ultsonch.2010.02.003

    Article  Google Scholar 

  12. M. Coşkun, P. Seven (2011) Synthesis, characterization and investigation of dielectric properties of two-armed graft copolymers prepared with methyl methacrylate and styrene onto PVC using atom transfer radical polymerization. React. Funct. Polym. 71 (4), 395–401. doi: http://dx.doi.org/10.1016/j.reactfunctpolym.2010.12.012

  13. M.S. El-Shall, V. Abdelsayed, A.E.R.S. Khder, H.M.A. Hassan, H.M. El-Kaderi, T.E. Reich, Metallic and bimetallic nanocatalysts incorporated into highly porous coordination polymer MIL-101. J. Mater. Chem. 19(41), 7625–7631 (2009). doi:10.1039/b912012b

    Article  Google Scholar 

  14. J.R. Potts, S.H. Lee, T.M. Alam, J. An, M.D. Stoller, R.D. Piner, R.S. Ruoff, Thermomechanical properties of chemically modified graphene/poly(methyl methacrylate) composites made by in situ polymerization. Carbon 49(8), 2615–2623 (2011). doi:10.1016/j.carbon.2011.02.023

    Article  Google Scholar 

  15. R.D. Priestley, C.J. Ellison, L.J. Broadbelt, J.M. Torkelson, Structural relaxation of polymer glasses at surfaces, interfaces, and in between. Science 309(5733), 456–459 (2005). doi:10.1126/science.1112217

    Article  ADS  Google Scholar 

  16. M. Fang, K. Wang, H. Lu, Y. Yang, S. Nutt, Single-layer graphene nanosheets with controlled grafting of polymer chains. J. Mater. Chem. 20(10), 1982–1992 (2010). doi:10.1039/b919078c

    Article  Google Scholar 

  17. X.Y. Yuan, L.L. Zou, C.C. Liao, J.W. Dai, Improved properties of chemically modified graphene/poly(methyl methacrylate) nanocomposites via a facile in-situ bulk polymerization. Exp. Polym. Lett. 6(10), 847–858 (2012). doi:10.3144/expresspolymlett.2012.90

    Article  Google Scholar 

  18. J.C. Wang, H.T. Hu, X.B. Wang, C.H. Xu, M. Zhang, X.P. Shang, Preparation and mechanical and electrical properties of graphene nanosheets-poly(methyl methacrylate) nanocomposites via in situ suspension polymerization. J. Appl. Polym. Sci. 122(3), 1866–1871 (2011). doi:10.1002/app.34284

    Article  Google Scholar 

  19. S. Gilje, S. Han, M. Wang, K.L. Wang, R.B. Kaner, A chemical route to graphene for device applications. Nano Lett. 7(11), 3394–3398 (2007). doi:10.1021/nl0717715

    Article  ADS  Google Scholar 

  20. M. Aldosari, A. Othman, E. Alsharaeh, Synthesis and characterization of the in situ bulk polymerization of PMMA containing graphene sheets using microwave irradiation. Molecules 18(3), 3152–3167 (2013)

    Article  Google Scholar 

  21. W.S. Hummers, R.E. Offeman, Preparation of graphitic oxide. J. Am. Chem. Soc. 80(6), 1339–1339 (1958). doi:10.1021/ja01539a017

    Article  Google Scholar 

  22. L.-B. Luo, S.-H. Yu, H.-S. Qian, T. Zhou, Large-scale fabrication of flexible silver/cross-linked poly(vinyl alcohol) coaxial nanocables by a facile solution approach. J. Am. Chem. Soc. 127(9), 2822–2823 (2005). doi:10.1021/ja0428154

    Article  Google Scholar 

Download references

Acknowledgments

This study is part of research Project No. 405010111127. The authors gratefully acknowledge the continued support from Alfaisal University and its Office of Research.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Edreese H. Alsharaeh .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2014 Springer International Publishing Switzerland

About this paper

Cite this paper

Alsharaeh, E.H. (2014). MWI Synthesis and Characterization of RGO-AgNPs/Polymethyl Methacrylate Nanocomposites. In: Polychroniadis, E., Oral, A., Ozer, M. (eds) International Multidisciplinary Microscopy Congress. Springer Proceedings in Physics, vol 154. Springer, Cham. https://doi.org/10.1007/978-3-319-04639-6_2

Download citation

Publish with us

Policies and ethics