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Baran reagents

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Abstract

Zinc bis(alkanesulfinate) salts, which permit direct C–H functionalization of heteroarenes. Several of these reagents are now commercially available.

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References

  1. Tordeux, M.; Langlois, B.; Wakselman, C. J. Chem. Soc., Perkin Trans. 1 1990, 2293–2299.

    Google Scholar 

  2. Langlois, B. R.; Laurent, E.; Roidot, N. Tetrahedron Lett. 1991, 32, 7525–7528.

    Article  CAS  Google Scholar 

  3. Clavel, J. L.; Langlois, B.; Laurent, E.; Roidot, N. Phosphorus, Sulfur, and Silicon 1991, 58, 463–466.

    Google Scholar 

  4. Kino, T.; Nagase, Y.; Ohtsuka, Y.; Yamamoto, K.; Uraguchi, D.; Tokuhisa, K.; Yamakawa, T. J. Fluorine Chem. 2010, 131, 98–105.

    Article  CAS  Google Scholar 

  5. Ji, Y.; Brueckl, T.; Baxter, R. D.; Fujiwara, Y.; Seiple, I. B.; Su, S.; Blackmond, D. G.; Baran, P. S. Proc. Natl. Acad. Sci. U. S. A. 2011, 108, 14411–14415. Phil S. Baran is currently a Professor in the Department of Chemistry at The Scripps Research Institute and Member of The Skaggs Institute for Chemical Biology. He was born in New Jersey in 1977, received his B.S. in chemistry from NYU in 1997, his Ph.D. at The Scripps Research Institute in 2001 (NSF fellow with K.C. Nicolaou), and from 2001–2003 he was an NIH postdoctoral fellow at Harvard in the laboratory of E. J. Corey. He has published over 120 scientific articles (H-Factor = 40) and has recently released a book in heterocyclic chemistry. His laboratory is focused on the invention of new reactions of broad utility and synthesizing complex natural products in a scalable, economic fashion. He recently won the John D. and Catharine T. MacArthur award.

    Google Scholar 

  6. Fujiwara, Y.; Dixon, J. A.; Rodriguez, R. A.; Baxter, R. D.; Dixon, D. D.; Collins, M. R.; Blackmond, D. G.; Baran, P. S. J. Am. Chem. Soc. 2012, 134, 1494–1497.

    Article  CAS  Google Scholar 

  7. Fujiwara, Y.; Dixon, J. A.; O’Hara, F.; Funder, E. D.; Dixon, D. D.; Rodriguez, R. A.; Baxter, R. D.; Herle, B.; Sach, N.; Collins, M. R.; Ishihara, Y.; Baran, P. S. Nature 2012, 492, 95–99.

    Article  CAS  Google Scholar 

  8. Zhou, Q.; Ruffoni, A.; Gianatassio, R.; Fujiwara, Y.; Sella, E.; Shabat, D.; Baran, P. S. Angew. Chem. Int. Ed. 2013, 52, 3949–3952

    Article  CAS  Google Scholar 

  9. O’Hara, F.; Baxter, R. D.; O’Brien, A. G.; Collins, M. R.; Dixon, J. A.; Fujiwara, Y.; Ishihara, Y.; Baran, P. S. Nature Protocols 2013, 8, 1042–1047.

    Article  Google Scholar 

  10. Baxter, R. D.; Blackmond, D. G. Tetrahedron 2013, 69, 5604–5608.

    Article  CAS  Google Scholar 

  11. O’Hara, F.; Blackmond, D. G.; Baran, P. S. J. Am. Chem. Soc. 2013, 135, 12122–12134.

    Article  Google Scholar 

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Li, J.J. (2014). Baran reagents. In: Name Reactions. Springer, Cham. https://doi.org/10.1007/978-3-319-03979-4_9

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