Abstract
This article overviews methods for preparation of micrometer-sized particles having hydrogel core and hydrophobic shell. It demonstrates that water-in-oil inverse suspension polymerization is a versatile method for one-step synthesis of either non-hollow spherical hydrogel particles or hollow capsules, depending on the nature of the gel-forming polymer. It further shows that rather thin hydrophobic shell provides a good stability of the particles in organic solvents while still does not preclude swellability of the hydrophilic core with water and small water-soluble molecules. A stepwise approach for fabrication of the core-shell hydrogel particles is also described which assumes preparation of hydrogel particles as the first step, their arrangement on surfaces followed by growing of the hydrophobic shell. Two methods for preparation of the hydrophobic shell were explored. The first one assumes free-radical polymerization of the polyisoprene from adsorbed hydrogel particles while the second one implies electrostatically-driven adsorption of polyisoprene latex particles onto oppositely charged hydrogels. Thus-obtained core-shell particles were used in fabrication of switchable coatings.
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References
Gonsalves K, Halberstadt C, Laurencin CT, Nair LS (2007) Biomedical nanostructures. Wiley-Interscience, Hoboken
Lu Y, Proch S, Schrinner M, Drechsler M, Kempeb R, Ballauff M (2009) J Mater Chem 19:3955; Welsch N, Becker AL, Dzubiella J, Ballauff M (2012) Soft Matter 8:1428
Jones CD, Lyon LA (2000) Macromolecules 33:8301
Berndt I, Richtering W (2003) Macromolecules 36:8780; Berndt I, Pedersen JS, Richtering W (2005) J Am Chem Soc 127:9372
Christodoulakis KE, Vamvakaki M (2010) Langmuir 26:639; Lapeyre V, Ancla C, Catargi B, Ravaine V (2008) J Colloid Interface Sci 327:316; Rodríguez-Fernández J, Fedoruk M, Hrelescu C, Lutich AA, Feldmann J (2011) Nanotechnology 22:245708
Nayak S, Gan D, Serpe MJ, Lyon LA (2005) Small 1:416
Xia F, Ge H, Hou Y, Sun TL, Chen L, Zhang GZ, Jiang L (2007) Adv Mater 19:2520
Jiang JQ, Tong X, Morris D, Zhao Y (2006) Macromolecules 39:4633
Kovarik ML, Jacobson SC (2009) Anal Chem 81:7133
Brown AA, Azzaroni O, Huck WTS (2009) Langmuir 25:1744
Ruckenstein E, Lee SH (1987) Colloid Interface Sci 120:529, Lee SH, Ruckenstein EJ (1987) Colloid Interface Sci 117:172
Hopken J, Moller, M (1992) Macromolecules 25:482; Vaidya A, Chaudhury MK (2002) J Colloid Interface Sci 249:235; Senshu K, Yamashita S, Mori H, Ito M, Hirao A, Nakahama S (1999) Langmuir 15: 1754; Mori H, Hirao A, Nakahama S, Senshu K (1994) Macromolecules 27:4093; Pientka Z, Oike H, Tezuka Y (1999) Langmuir 15:3197
Minko S, Muller M, Motornov M, Nitschke M, Grundke K, Stamm M (2003) J Am Chem Soc 125:3896, Retsos H, Senkovskyy V, Kiriy A, Stamm M, Feldstein M, Creton C (2006) Adv Mater 18:2624
Retsos H, Gorodyska G, Kiriy A, Stamm M, Creton C (2005) Langmuir 21:7722
Hemmerle J, Roucoules V, Fleith G, Nardin M, Ball V, Lavalle P, Marie P, Voegel JC, Schaaf P (2005) Langmuir 21:10328
Tamber H, Johansen P, Merkle HP, Gander B (2005) Adv Drug Deliv Rev 57:376; Hammer DA, Discher DE (2001) Annu Rev Mater Sci 31:387
Caruso F, Caruso RA, Mohwald H (1998) Science 282:1111; Johnson SA, Ollivier PJ, Mallouk TE (1999) Science 283:963; Bronich TK, Ouyang M, Kabanov VA, Eisenberg A, Szoka FC, Kabanov AV (2002) J Am Chem Soc 124:11872
Dowding PJ, Atkin R, Vincent B, Bouillot P (2004) Langmuir 20:11374; Dinsmore AD, Hsu MG, Nikolaides MG, Marques M, Bausch AR, Weitz DA (2002) Science 298:1006; Qian J, Wu FP (2007) Chem Mater 19:5839; Peyratout CS, Dahne L (2004) Angew Chem Int Ed 43:3762
Sidorenko A, Minko S, Schenk-Meuser K, Duschner H, Stamm M (1999) Langmuir 15:8349; Tiarks F, Landfester K, Antonietti M (2001) Langmuir 17:908
Khongtong S, Ferguson GS (2001) J Am Chem Soc 123:3588; Makal U, Wynne KJ (2005) Langmuir 21:3742; Makal U, Uslu N, Wynne KJ (2007) Langmuir 23:209
Horecha M, Senkovskyy V, Schneider K, Kiriy A, Stamm M (2011) Colloid Polym Sci 289:603
Cassie A, Baxter S (1944) Trans Faraday Soc 40:546; Cassie A, Baxter S (1948) Discuss Faradey Soc 3:5041
Pelton R (2000) Adv Colloid Interface Sci 85:1; Jones CD, Lyon LA (2000) Macromolecules 33:8301; Dowding PJ, Vincent B, Williams EJ (2000) Colloid Interface Sci 221:268; Zhou S, Chu B (1998) J Phys Chem 102:1364; Saunders BR, Vincent B (1999) Adv Colloid Interface Sci 80:1
Nerapusri V, Keddie JL, Vincent B, Bushnak IA (2006) Langmuir 22:5036; Serpe MJ, Jones CD, Lyon LA (2003) Langmuir 19:8759; Schmidt S, Motschmann H, Hellweg T, von Klitzing R (2008) Polymer 49:749
Schmidt S, Hellweg T, von Klitzing R (2008) Langmuir 24: 12595; Sorrell CD, Lyon LA (2008) Langmuir 24: 7216; Lu Y, Drechsler M (2009) Langmuir 25:13100
Sakai T, Takeoka Y, Seki T, Yoshida R (2007) Langmuir 23: 8651; Tian E, Wang J, Zheng Y, Song Y, Jiang L, Zhu DJ (2008) Mater Chem 18:1116
Nakahama K, Fujimoto K (2002) Langmuir 18:10095
Tsuji S, Kawaguchi H (2005) Langmuir 21:8439
Suzuki D, McGrath J, Kawaguchi H, Lyon LA (2007) J Phys Chem 111:5667
Serpe MJ, Jones CD, Lyon LA (2003) Langmuir 19:8759
Lyon LA, Meng Z, Singh N, Sorrell CD (2009) Chem Soc Rev 38:865
Chen MQ, Serizava T, Li M, Wu C, Akashi M (2003) Polymer J 35:901, Chen Y, Gautrot JE, Zhu XX (2007) Langmuir 23:1047, Pabon M, Corpart JM, Selb J, Candau F (2004) J Appl Polym Sci 91:916, Paunov J (2004) Mater Chem 14:3351
Horecha M (2011) Coatings with inversely switching behaviour: new applications of core-shell hydrogel particles. http://tud.qucosa.de/recherche/frontdoor/cache.off?tx_slubopus4frontend[id]=6517
Takahashi K, Takigawa T, Masuda T (2004) J Chem Phys 120:2972; Suarez IJ, Fernandez-Nieves A, Marquez M (2006) JChem Phys B 110:25729; Owens DE, Jian Y, Fang JE, Slaughter BV, Chen YH, Peppas NA (2007) Macromolecules 40:7306
Winnik FM, Ottaviani MF, Bossmann SH, Pan WS, Garciagaribay M, Turro NJ (1993) Macromolecules 26:4577
Horecha M, Senkovskyy V, Synytska A, Stamm M, Chervanyov AI, Kiriy A (2010) Soft Matter 6:5980
Pelton RH, Chibante P (1986) Colloids Surf 20:247
Elachari A, Coqueret X, Lablachecombier A, Loucheux C (1993) Makromolekulare Chemie-Macromol Chem Phys 194:1879
Edmondson S, Osborne VL, Huck WT (2004) Chem Soc Rev 33:14
Tsuji S, Kawaguchi H (2005) Langmuir 21:2434, Serpe MJ, Jones CD, Lyon LA (2003) Langmuir 19:8759
Khanduyeva N, Senkovskyy V, Beryozkina T, Horecha M, Stamm M, Uhrich C, Riede M, Leo K, Kiriy A (2009) J Am Chem Soc 131:153
Beryozkina T, Boyko K, Khanduyeva N, Senkovskyy V, Horecha M, Oertel U, Simon F, Komber H, Stamm M, Kiriy A (2009) Angew Chem 48:2695
Li R, Yang XL, Li GL, Li SN, Huang WQ (2006) Langmuir 22:8127
Bon SAF, Cauvin S, Colver PJ (2007) Soft Matter 3:194
Wang Y, Hu HP, Zhang X (2009) Adv Mater 21:2849; Lou XW, Archer LA, Yang Z (2008) Adv Mater 20:3987; Lan Y, Yang L, Zhang MC, Zhang WQ, Wang SN (2010) ACS Appl Mater Interf 2:127; Khanal A, Inoue Y, Yada M, Nakashima K (2007) J Am Chem Soc 129:1534; Li GL, Lei C, Wang C, Neoh KG, Kang ET, Yang X (2008) Macromolecules 41:9487
Arnal P, Comotti M, Schüth F (2006) Angew Chem Int Ed 45:8224; Kamata K, Lu Y, Xia Y (2003) J Am Chem Soc 125:2384; Lee J, Park JC, Bang JU, Song H (2008) Chem Mater 20:5839; Wu XJ, Xu D (2010) Adv Mater 22:1516; Zoldesi CI, Imhof A (2005) Adv Mater 17:924
Peyratout CS, Dähne L (2004) Angew Chem Int Ed 43:3762, Sukhorukov G, Fery A, Möhwald H (2005) Prog Polym Sci 30:885, Klaikherd A, Nagamani C, Thayumanavan S (2009) J Am. Chem. Soc. 131:4830, Li G, Shi L, Ma R, An Y, Huang N (2006) Angew Chem Int Ed 45:4959, Sauer M, Meier W (2001) Chem Commun 1:55, Sauer M, Streich D, Meier W (2001) Adv Mater 13:1649, Seiffert S, Weitz DA (2010) Polymer 51:5883
Li GL, Xu LQ, Tang XZ, Neoh KG, Kang ET (2010) Macromolecules 43:5797
Heskins M, Guillet JE (1968) J Macromol Sci A2:1441; Hirotsu S (1988) J Chem Phys 88:427
Wie W, Zhang C, Ding S, Qu X, Liu J, Yang Z (2008) Colloid Polym Sci 286:881
Gao H, Yang W, Min K, Zha L, Wang C, Fu S (2005) Polymer 46:1087
Huang CJ, Chang FC (2009) Macromolecules 42:5155
Choi CH, Jung JH, Kim DW, Chung YM, Lee CS (2008) Lab Chip 8:1544
Sun Q, Deng Y (2005) J Am Chem Soc 127:8274
Horecha M, Senkovskyy V, Stamm M, Kiriy A (2009) Macromolecules 42:5811
McPhee W, Tam KC, Pelton RH (1993) J Colloid Interface Sci 156:24
Zha LS, Zhang Y, Yang WL, Fu SK (2002) Adv Mater 14:1090
Wolf BA, Willms MM (1978) Makromol Chem 179:2265; Nandi AK, Sen UK, Bhattacharyya SN, Mandel BM (1983) Eur Polym J 19:283; Horta A, Fernandez-Pierola I (1980) Polym Bull 3:273; Schild HG, Muthukumar M, Tirrell DA (1991) Macromolecules 24:948
Zhang K, Wu W, Guo K, Chen J, Zhang P (2010) Langmuir 26:7971
Cao Z, Ziener U, Landfester K (2010) Macromolecules 43:6353
Kobitskaya E, Ekinci D, Manzke A, Plettl A, Wiedwald U, Ziemann P, Biskupek J, Kaiser U, Ziener U, Landfester K (2010) Macromolecules 43:3294
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Financial support by the Deutsche Forschungsgemeinschaft (SPP 1259/1 “Intelligente Hydrogele”) is greatly acknowledged.
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Horecha, M., Senkovskyy, V., Kiriy, A., Stamm, M. (2013). Hydrophobically Covered Hydrogels: Preparation Approaches and Possible Applications. In: Sadowski, G., Richtering, W. (eds) Intelligent Hydrogels. Progress in Colloid and Polymer Science, vol 140. Springer, Cham. https://doi.org/10.1007/978-3-319-01683-2_12
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