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Nickel and Copper Complexes

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The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist

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Abstract

The synthesized novel Siamese-twin porphyrin LH4 was designed as a chelating macrocyclic ligand to bind two metals in close proximity. The twin N4 pockets are negatively charged twice after deprotonation. Most first row transition metals exhibit a stable oxidation state of 2 + [1]. With these M2+ metals, neutral complexes of the Siamese-twin porphyrin can be formed and the oxidation of neutral complexes usually is easier compared to positively charged complexes. This may facilitate the formation of high-valent species, including metal-oxo species.

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  1. Department of Chemistry, University of British Columbia, Main Mall 2036, Vancouver, BC, V6T 1Z1, Canada

    Lina K. Blusch

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Blusch, L.K. (2013). Nickel and Copper Complexes. In: The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist. Springer Theses. Springer, Cham. https://doi.org/10.1007/978-3-319-01674-0_5

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