Abstract
Sol-gel techniques are particularly suitable for the preparation of antireflective (AR) coatings and optical filters: Chemical compositions and thus optical properties can be adjusted over a wide range; different films are easily combined to multilayer arrangements. The selective implementation of porosity allows the preparation if films with unique optical characteristics. Additionally micro- and nanopatterns can be fabricated by embossing techniques that are difficult or impossible to be produced otherwise. This chapter shortly reviews the general strategies for AR coatings. Methods for the sol-gel processing of single- and multilayer interference-type films are described; references to respective commercial products are given. Elaborate stack arrangements are used as optical filters beyond the scope of AR-coatings. Index-gradient films are finally introduced including “moth-eye” films prepared by the embossing and subsequent thermal curing of specific coatings.
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References
Wilson SJ, Hutley MC (1982) The optical properties of ‘moth eye’ antireflection surfaces. Opt Acta 29:993–1009
Moulton H (1949) US Patent 2474061
Schroeder H (1969) Oxide layers deposited from organic solutions. In: Hass G, Thun RE (eds) Physics of thin films: advances in research and development, vol 5. Academic, New York, NY, pp 87–141
Iler RK (1979) The chemistry of silica. Wiley, New York, NY
Vincent A, Babu S, Brinley E, Karakoti A, Deshpande S, Seal S (2007) Role of catalyst on refractive index tunability of porous antireflective coatings by sol-gel technique. J Phys Chem C 111:8291–8298
Yoldas B (1981) US Patent 4271210
Chen D (2001) Anti-reflection (AR) coatings made by sol-gel process: a review. Sol Energy Mater 68:313–336
Baklanov MR, Mogilnikov KP (2002) Non-destructive characterization of porous low-k dielectric films. Microelectron Eng 64:335–349
Rouquerol F, Rouquerol J, Sing K (1999) Adsorption by powders and porous solids: principles, methodology and applications. Academic, London
Bockmeyer M, Herbig B, Löbmann P (2009) Microstructure of sol–gel derived TiO2 thin films characterized by atmospheric ellipsometric porosimetry. Thin Solid Films 517:1596–1600
Hussmann E (1998) Sol-gel coatings on large glass substrates for multilayer interference systems. Key Eng Mater 150:49–66
Glaubitt W, Kursawe M, Gombert A, Hofmann T (2002) Novel hybrid sol for producing abrasion-resistant SiO2 antireflection coatings on glass. PCT/EP 2002/010492
Gombert A, Glaubitt W (2000) Antireflective transparent coatings for solar devices. Sol Energy 68:357–360
Fujihara S, Tada M, Kimura T (1997) Preparation and characterization of MgF2 thin film by a trifluoroacetic acid method. Thin Solid Films 304:252–255
Kemnitz E, Gross U, Rudiger S, Shekar C (2003) Amorphous metal fluorides with extraordinary high surface areas. Angew Chem Int Ed 42:4251–4254
Krüger H, Kemnitz E, Hertwig A, Beck U (2008) Transparent MgF2-films by sol-gel coating: synthesis and optical properties. Thin Solid Films 516:4175–4177
Macleod H (2001) Thin-film optical filters, 3rd edn. Institute of Physica Publishing, London
Löbmann P (2005) Soluble precursor powders as precursors for TiO2 thin films. J Sol Gel Sci Technol 33:275–282
Löbmann P, Röhlen P (2003) Industrial processing of TiO2 thin films from soluble precursor powders. J Glass Sci Technol 76:1–7
Debsikdar J (1989) US Patent 4830879
Lowdermilk W, Milam D (1980) Graded-index antireflection surfaces for high-power laser applications. Appl Phys Lett 36:891
McCollister H, Boling N (1981) US Patent 4273826
Mukherjee S (1981) Gel-derived single-layer antireflection films with a refractive index gradient. Thin Solid Films 81:L89–L90
Yoldas B, Partlow P (1985) Formation of broad band antireflective coatings on fused silica for high power laser applications. Thin Solid Films 129:1–14
Bernhard C (1967) Structural and functional adaption in a visual system. Endeavour 26:79–84
DellaGiustina G, Brusatin G, Guglielmi M, Romanato F (2007) Direct nanopattern of hybrid sol-gel films. Mater Sci Eng C 27:1382–1385
Heermann J, Löbmann P (2001) Coating and structuring of glass surfaces by sol-gel and embossing techniques. In: 19th International congress on glass, Edinburgh, UK, 1–6 July 2001
Linn N, Sun C, Jianga P, Jiang B (2007) Self-assembled biomimetic antireflection coatings. Appl Phys Lett 91:101108
Yamaguchi N, Tadanaga K, Matsuda A, Minami T, Tatsumisago M (2007) Antireflective properties of flowerlike alumina thin films on soda–lime silica glass substrates prepared by the sol–gel method with hot water treatment. Thin Solid Films 515:3914–3917
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Löbmann, P. (2013). Antireflective Coatings and Optical Filters. In: Schneller, T., Waser, R., Kosec, M., Payne, D. (eds) Chemical Solution Deposition of Functional Oxide Thin Films. Springer, Vienna. https://doi.org/10.1007/978-3-211-99311-8_28
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DOI: https://doi.org/10.1007/978-3-211-99311-8_28
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