Skip to main content

Antireflective Coatings and Optical Filters

  • Chapter
  • First Online:
Chemical Solution Deposition of Functional Oxide Thin Films

Abstract

Sol-gel techniques are particularly suitable for the preparation of antireflective (AR) coatings and optical filters: Chemical compositions and thus optical properties can be adjusted over a wide range; different films are easily combined to multilayer arrangements. The selective implementation of porosity allows the preparation if films with unique optical characteristics. Additionally micro- and nanopatterns can be fabricated by embossing techniques that are difficult or impossible to be produced otherwise. This chapter shortly reviews the general strategies for AR coatings. Methods for the sol-gel processing of single- and multilayer interference-type films are described; references to respective commercial products are given. Elaborate stack arrangements are used as optical filters beyond the scope of AR-coatings. Index-gradient films are finally introduced including “moth-eye” films prepared by the embossing and subsequent thermal curing of specific coatings.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Wilson SJ, Hutley MC (1982) The optical properties of ‘moth eye’ antireflection surfaces. Opt Acta 29:993–1009

    Article  Google Scholar 

  2. Moulton H (1949) US Patent 2474061

    Google Scholar 

  3. Schroeder H (1969) Oxide layers deposited from organic solutions. In: Hass G, Thun RE (eds) Physics of thin films: advances in research and development, vol 5. Academic, New York, NY, pp 87–141

    Google Scholar 

  4. Iler RK (1979) The chemistry of silica. Wiley, New York, NY

    Google Scholar 

  5. Vincent A, Babu S, Brinley E, Karakoti A, Deshpande S, Seal S (2007) Role of catalyst on refractive index tunability of porous antireflective coatings by sol-gel technique. J Phys Chem C 111:8291–8298

    Article  Google Scholar 

  6. Yoldas B (1981) US Patent 4271210

    Google Scholar 

  7. Chen D (2001) Anti-reflection (AR) coatings made by sol-gel process: a review. Sol Energy Mater 68:313–336

    Article  Google Scholar 

  8. Baklanov MR, Mogilnikov KP (2002) Non-destructive characterization of porous low-k dielectric films. Microelectron Eng 64:335–349

    Article  Google Scholar 

  9. Rouquerol F, Rouquerol J, Sing K (1999) Adsorption by powders and porous solids: principles, methodology and applications. Academic, London

    Google Scholar 

  10. Bockmeyer M, Herbig B, Löbmann P (2009) Microstructure of sol–gel derived TiO2 thin films characterized by atmospheric ellipsometric porosimetry. Thin Solid Films 517:1596–1600

    Article  Google Scholar 

  11. Hussmann E (1998) Sol-gel coatings on large glass substrates for multilayer interference systems. Key Eng Mater 150:49–66

    Article  Google Scholar 

  12. Glaubitt W, Kursawe M, Gombert A, Hofmann T (2002) Novel hybrid sol for producing abrasion-resistant SiO2 antireflection coatings on glass. PCT/EP 2002/010492

    Google Scholar 

  13. Gombert A, Glaubitt W (2000) Antireflective transparent coatings for solar devices. Sol Energy 68:357–360

    Article  Google Scholar 

  14. Fujihara S, Tada M, Kimura T (1997) Preparation and characterization of MgF2 thin film by a trifluoroacetic acid method. Thin Solid Films 304:252–255

    Article  Google Scholar 

  15. Kemnitz E, Gross U, Rudiger S, Shekar C (2003) Amorphous metal fluorides with extraordinary high surface areas. Angew Chem Int Ed 42:4251–4254

    Article  Google Scholar 

  16. Krüger H, Kemnitz E, Hertwig A, Beck U (2008) Transparent MgF2-films by sol-gel coating: synthesis and optical properties. Thin Solid Films 516:4175–4177

    Article  Google Scholar 

  17. Macleod H (2001) Thin-film optical filters, 3rd edn. Institute of Physica Publishing, London

    Book  Google Scholar 

  18. Löbmann P (2005) Soluble precursor powders as precursors for TiO2 thin films. J Sol Gel Sci Technol 33:275–282

    Article  Google Scholar 

  19. Löbmann P, Röhlen P (2003) Industrial processing of TiO2 thin films from soluble precursor powders. J Glass Sci Technol 76:1–7

    Google Scholar 

  20. Debsikdar J (1989) US Patent 4830879

    Google Scholar 

  21. Lowdermilk W, Milam D (1980) Graded-index antireflection surfaces for high-power laser applications. Appl Phys Lett 36:891

    Article  Google Scholar 

  22. McCollister H, Boling N (1981) US Patent 4273826

    Google Scholar 

  23. Mukherjee S (1981) Gel-derived single-layer antireflection films with a refractive index gradient. Thin Solid Films 81:L89–L90

    Article  Google Scholar 

  24. Yoldas B, Partlow P (1985) Formation of broad band antireflective coatings on fused silica for high power laser applications. Thin Solid Films 129:1–14

    Article  Google Scholar 

  25. Bernhard C (1967) Structural and functional adaption in a visual system. Endeavour 26:79–84

    Google Scholar 

  26. DellaGiustina G, Brusatin G, Guglielmi M, Romanato F (2007) Direct nanopattern of hybrid sol-gel films. Mater Sci Eng C 27:1382–1385

    Article  Google Scholar 

  27. Heermann J, Löbmann P (2001) Coating and structuring of glass surfaces by sol-gel and embossing techniques. In: 19th International congress on glass, Edinburgh, UK, 1–6 July 2001

    Google Scholar 

  28. Linn N, Sun C, Jianga P, Jiang B (2007) Self-assembled biomimetic antireflection coatings. Appl Phys Lett 91:101108

    Article  Google Scholar 

  29. Yamaguchi N, Tadanaga K, Matsuda A, Minami T, Tatsumisago M (2007) Antireflective properties of flowerlike alumina thin films on soda–lime silica glass substrates prepared by the sol–gel method with hot water treatment. Thin Solid Films 515:3914–3917

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Peer Löbmann .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2013 Springer-Verlag Wien

About this chapter

Cite this chapter

Löbmann, P. (2013). Antireflective Coatings and Optical Filters. In: Schneller, T., Waser, R., Kosec, M., Payne, D. (eds) Chemical Solution Deposition of Functional Oxide Thin Films. Springer, Vienna. https://doi.org/10.1007/978-3-211-99311-8_28

Download citation

Publish with us

Policies and ethics