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Enthalpimetric Measurements in Solid-Solid Reactions. III. The Uranylnitrate-Phenylurea System

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Thermal Analysis

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Abstract

Solid UO2(NO3)2.6H2O, at suitable temperature, reacts with solid Phenylurea (Ph). By using a 1:2 stoichiometric ratio UO2(NO3)2Ph2 is obtained. This compound for reaction with Ph gives several other complexes. DSC is used to study the reactions: UO2(NO3)2Phn + mPh → UO2(NO3)2Phn+m (where n = 2÷5 m = 1÷4; n+m =3÷6). The enthalpic values were determined and rationalized.

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Authors and Affiliations

  1. Istituto Dipartimentale di Chimica e Chimica Industriale, l’Università di Catania, Viale A. Doria, 8, 95125, Catania, Italy

    G. Siracusa, L. Abate & S. Gurrieri

Authors
  1. G. Siracusa
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  2. L. Abate
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  3. S. Gurrieri
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Editor information

Editors and Affiliations

  1. Institut für Werkstoffkunde, Universität Braunschweig, Federal Republic of Germany

    W. Hemminger

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© 1980 Springer Basel AG

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Siracusa, G., Abate, L., Gurrieri, S. (1980). Enthalpimetric Measurements in Solid-Solid Reactions. III. The Uranylnitrate-Phenylurea System. In: Hemminger, W. (eds) Thermal Analysis. Birkhäuser, Basel. https://doi.org/10.1007/978-3-0348-6736-8_12

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  • DOI: https://doi.org/10.1007/978-3-0348-6736-8_12

  • Publisher Name: Birkhäuser, Basel

  • Print ISBN: 978-3-0348-6737-5

  • Online ISBN: 978-3-0348-6736-8

  • eBook Packages: Springer Book Archive

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