Abstract
The conception presented in this paper aims at consistent investigations into problems which may be summarized under the term “Reactivity of Solids”. In work of this kind, a careful consideration of relations between structure and morphology on the one hand and chemical reactivity (resp. behaviour in solid-solid phase transitions) on the other hand is indispensable. Structural and morphological results are mainly collected by X-rays and chemical electron microscopy, whereas thermoanalytical techniques are used to induce resp. follow reactions and phase transitions. Topochemical aspects and topotaxy are of central importance in our concept.
By a typical example is proved that it is often not possible to set up a realistic reaction mechanism from thermoanalytical curves only. Results on thermal decomposition of small single crystals of model compounds selected from coordination chemistry show how important a careful control of the experimental conditions is.
Furthermore, in situ thermogravimetry as an aid for preparative solid state chemical research in low pressure plasmas is described, and recent results on Jahn-Teller phase transitions are presented.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
H. R. Oswald and E. Dubler, Reviews on Analytical Chemistry, Euroanalysis II, Budapest, 1975, ed. W. Fresenius, Akadémiai Kiadó, Budapest, 1977, pp. 153–194.
W. Meierhöfer, Ph.D. thesis, Univ. of Zurich, 1972.
W. Meierhöfer and H. R. Oswald, Thermal Analysis, Proc.3rd ICTA, Davos, 1971, Vol. 2, ed. H. G. Wiedemann, Birkhäuser, Basel, 1972, pp. 409–421.
V. Kohlschütter, Z.anorg.allg.Chem. 105 (1919) 1; ibid. 35.
V.V. Boldyrev, J.Thermal Anal. 7 (1975) 685; 8 (1975) 175.
F.K. Lotgering, J.Inorg.Nucl.Chem. 9 (1959) 113.
J.R. Günter and H.R. Oswald, Bull.Inst.Chem.Res.Kyoto Univ. 53 (1975) 249.
H.R. Oswald and J.R. Günter, 1976 Crystal Growth and Materials, ed. E. Kaldis and H.J. Scheel, North-Holland, Amsterdam, 1977, pp. 415–433.
J.R. Günter, J.Solid State Chem. 5 (1972) 354.
H.R. Oswald, J.R. Günter and E. Dubler, J. Solid State Chem. 13 (1975) 330.
A. Relier, H.R. Beer and H.R. Oswald, Experientia Suppl. 37, eds. E. Marti, H.R. Oswald and H.G. Wiedemann, Birkhäuser, Basel, 1979, p. 61.
H.R. Oswald and A. Reller, Proc. 9th Int.Sympos. on the React, of Solids, Cracow, 1980, Elsevier, Amsterdam, 1980, to be printed.
A. Reller and H.R. Oswald, Thermal Analysis, Proc. 6th ICTA ′80, Bayreuth, Vol. 1, ed. H.G. Wiedemann, Birkhäuser, Basel, 1980, p. 65.
W. Bachmann, J. R. Günter and H. R. Oswald, Experientia Suppl. 37, eds. E. Marti, H.R. Oswald and H.G. Wiedemann, Birkhäuser, Basel, 1979, p. 36.
S. Vepřek, Current Topics in Material Science, Vol. 4, ed. E. Kaldis, North-Holland, Amsterdam, 1980.
H. Winters, Plasma Chemistry, Vol. III, eds. S. Vepřek and M. Venugopalan, Springer, Berlin, 1980.
A.P. Webb and S. Vepřek, Chem.Phys. Letters 68 (1980) 173.
S. Vepřek and A.P. Webb, Proc. 4th Int.Symp. on Plasma Chemistry, eds. S. Vepřek and J. Hertz, Univ. of Zurich, 1979, p. 79.
E. Wirz, H.R. Oswald and S. Vepřek, Proc. 4th Int.Symp. on Plasma Chemistry, eds. S. Vepřek and J. Hertz, Univ. of Zurich, 1979, p. 492.
H.U. Beyeler and S. Vepřek, Phil.Magazine, in press.
Z. Iqbal, A.P. Webb and S. Vepřek, Appl.Phys.Letters 36 (1980) 163.
D. Gruen, S. Vepřek and R.B. Wright, Plasma Chemistry, Vol. I, eds. S. Vepřek and M. Venugopalan, Springer, Berlin, 1980.
S. Vepřek, A.P. Webb, H.R. Oswald and H. Stuessi, J.Nucl.Mat. 68 (1977) 32.
H.R. Beer and H.R. Oswald, Thermal Analysis, Proc. 6th ICTA ’80, Bayreuth, Vol. 2, ed. W. Hemminger, Birkhäuser, Basel, 1980, in press.
E. Dubler, J.P. Matthieu and H.R. Oswald, Thermal Analysis, Proc. 4th ICTA, Budapest, 1974, Vol. 1, ed. I. Buzás, Akadémiai Kiadó, Budapest, 1975, p. 377.
P. Holba, M. Nevřiva and E. Pollert, Mat.Res.Bull. 10 (1975) 853.
H.R. Oswald, J.P. Matthieu and M. Wirz, Thermochim.Acta 20 (1977) 23, and so far unpublished work with A.Lüscher.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1980 Springer Basel AG
About this chapter
Cite this chapter
Oswald, H.R. (1980). Thermal Analysis in Inorganic Solid State Chemistry. In: Wiedemann, H.G. (eds) Thermal Analysis. Birkhäuser, Basel. https://doi.org/10.1007/978-3-0348-6719-1_1
Download citation
DOI: https://doi.org/10.1007/978-3-0348-6719-1_1
Publisher Name: Birkhäuser, Basel
Print ISBN: 978-3-0348-6720-7
Online ISBN: 978-3-0348-6719-1
eBook Packages: Springer Book Archive