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Mechanism of Electrochemical Reduction of 2-Pyrimidone, Cytosine and Cytidine

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Biological Aspects of Electrochemistry

Part of the book series: Experientia Supplementum ((EXS,volume 18))

Summary

2-Pyrimidone, cytosine and cytidine have been reduced electrochemically and the reduction products identified. The product of the reduction of 2-pyrimidone shows the properties of a dimer. Cytosine gives several products which differ in neutral and acidic media; one, 5,6-dihydrocytosine, indicates the initial reduction step in the 5,6 bond. A secondary product has been found to be the same as that of the reduction of 2-pyrimidone. 5,6-Dihydrocytidine has been identified in the reduction of cytidine.

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© 1971 Springer Basel AG

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Czochralska, B., Shugar, D. (1971). Mechanism of Electrochemical Reduction of 2-Pyrimidone, Cytosine and Cytidine. In: Milazzo, G., Jones, P.E., Rampazzo, L. (eds) Biological Aspects of Electrochemistry. Experientia Supplementum, vol 18. Birkhäuser, Basel. https://doi.org/10.1007/978-3-0348-5848-9_20

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  • DOI: https://doi.org/10.1007/978-3-0348-5848-9_20

  • Publisher Name: Birkhäuser, Basel

  • Print ISBN: 978-3-0348-5850-2

  • Online ISBN: 978-3-0348-5848-9

  • eBook Packages: Springer Book Archive

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