Summary
2-Pyrimidone, cytosine and cytidine have been reduced electrochemically and the reduction products identified. The product of the reduction of 2-pyrimidone shows the properties of a dimer. Cytosine gives several products which differ in neutral and acidic media; one, 5,6-dihydrocytosine, indicates the initial reduction step in the 5,6 bond. A secondary product has been found to be the same as that of the reduction of 2-pyrimidone. 5,6-Dihydrocytidine has been identified in the reduction of cytidine.
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References
D. Smith and P.J. Elving, J. Am. Chem. Soc. 84, 2741 (1962).
B. Janik and E. Palzcek, Arch. Biochem. Biophys. 105, 225 (1964).
C. Janion and D. Shugar, Acta Biochim. Polon. 14, 293 (1967).
V. Skaric, B. Gaspert and D. Skaric, Croatica. Chem. Acta 36, 87 (1964).
R.M. Fink, R.E. Cline, C.Mc. Gaughey and K. Fink, Anal. Chem. 28, 4 (1956).
A. Vogel, A Textbook of Quantitative Inorganic Analysis, Longman, London, 1948.
A.R. Hanze, J. Am. Chem. Soc. 89, 6720 (1967).
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Czochralska, B., Shugar, D. (1971). Mechanism of Electrochemical Reduction of 2-Pyrimidone, Cytosine and Cytidine. In: Milazzo, G., Jones, P.E., Rampazzo, L. (eds) Biological Aspects of Electrochemistry. Experientia Supplementum, vol 18. Birkhäuser, Basel. https://doi.org/10.1007/978-3-0348-5848-9_20
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DOI: https://doi.org/10.1007/978-3-0348-5848-9_20
Publisher Name: Birkhäuser, Basel
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Online ISBN: 978-3-0348-5848-9
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