Abstract
This research has examined how the rotational speed affects the structural, morphological, and optical characteristics of the compound copper iron cobalt tin sulfide Cu2Fe0.5Co0.5SnS4 (CFCTS). CFCTS thin films were applied to a glass substrate using the straightforward spin coating method, with varying rotational speeds, and without the need for a sulfurization step. The result of X-ray diffraction revealed the tetragonal phase with preferential orientation as (112). The morphological surface become homogenous and dense with increase of rotational speed. The elementary analysis determined the presence of the important element Cu, Fe, Co, Sn, S, so stoichiometry of CFCTS thin films improved with increased of rotational speed. The direct band gap of the CFCTS thin films was demonstrated by the optical result. The increase in rotational speed from 2500 to 4000 rpm resulted in a reduction of the optical band gap in CFCTS thin films, attributed to the quantum confinement effect, decreasing from 1.38 to 1.05 eV. These results confirm that it is possible to use this CFCTS material as potential absorber in solar cells in order to generate renewable energy. Also, a very high conversion efficiency can be achieved under the ideal synthesis conditions for this material.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Barman, B., Kalita, P.K.: Influence of back surface field layer on enhancing the efficiency of CIGS solar cell. Sol. Energy 216, 329–337 (2021). https://doi.org/10.1016/j.solener.2021.01.032
Hajji, M., Ajili, M., Jebbari, N., et al.: First investigation into the physical characteristics of GO-Doped CuO-ZnO thin films as a secondary absorption layer in CIGS solar cells. Mater. Lett. 357, 135806 (2024). https://doi.org/10.1016/j.matlet.2023.135806
Hafaifa, L., Maache, M., Allam, Z., Zebeir, A.: Simulation and performance analysis of CdTe thin film solar cell using different Cd-free zinc chalcogenide-based buffer layers. Results Opt. 14, 100596 (2024). https://doi.org/10.1016/j.rio.2023.100596
Mughal, M.A., Engelken, R., Sharma, R.: Progress in indium (III) sulfide (In2S3) buffer layer deposition techniques for CIS, CIGS, and CdTe-based thin film solar cells. Sol. Energy 120, 131–146 (2015). https://doi.org/10.1016/j.solener.2015.07.028
Aitelhaj, D., El kissani, A., Aitdads, H. et al.: A simple route for synthesis of copper iron tin sulfide thin films. Mater. Lett. 292, 129646 (2021). https://doi.org/10.1016/j.matlet.2021.129646
El, A., Ait, D., Drissi, S., et al.: Structural, optical and electrical properties of Cu 2 CoSnS 4 thin film solar cells prepared by facile sol-gel route. Thin Solid Films 758, 139430 (2022). https://doi.org/10.1016/j.tsf.2022.139430
El kissani, A., Nkhaili, L., Ammar, A., et al.: Synthesis, annealing, characterization, and electronic properties of thin films of a quaternary semiconductor. file:///C:/Users/HP/Desktop/nouv article/les refereces article/[20].pdf file:///C:/Users/HP/Desktop/nouv article/les refereces article/[4].pdf f. Spectrosc. Lett. 49, 343–347 (2016). https://doi.org/10.1080/00387010.2016.1167086
Aitelhaj, D., El kissani, A., Elyaagoubi, M., et al.: Development of Cu2NiSnS4 based thin film solar cells without a sulfurization step. Mater. Sci. Semicond. Process 107, 104811 (2020). https://doi.org/10.1016/j.mssp.2019.104811
Nefzi, C., Souli, M., Costa-Krämer, J.L., et al.: Growth of the next generation promising Cu2 Fe1-xCoxSnS4 thin films and efficient p-CCTS/n-In2S3/n-SnO2F heterojunction for optoelectronic applications. Mater. Res. Bull. 133, 111028 (2021). https://doi.org/10.1016/j.materresbull.2020.111028
Drissi, S., Kissani, E.L., A., Abali, et al.: Substitution effects on physical and chemical properties of Cu2Fe1-xCoxSnS4 thin films synthesized by the sol-gel technique. Phys. B. Condens. Matter. 667, 415184 (2023). https://doi.org/10.1016/j.physb.2023.415184
Abali, A., El Kissani, A., Drissi, S., et al.: Effect of annealing time on different properties of the next generation Cu2Ni0.50Co0.50SnS4Thin films. EPJ. Appl. Phys. 97 (2022). https://doi.org/10.1051/epjap/2022220068
Elmassi, S., Narjis, A., Nkhaili, L., et al.: Effect of annealing on structural, optical and electrical properties of nickel oxide thin films synthesized by the reactive radio frequency sputtering. Phys B Condens Matter 639, 413980 (2022). https://doi.org/10.1016/j.physb.2022.413980
Daza, L.G.: Effect of substrate rotation speed on structure and properties of Al-doped ZnO thin films prepared by rf-sputtering. 27, 2055–2062 (2017). https://doi.org/10.1016/S1003-6326(17)60230-9
Prasad, M.V.V., Thyagarajan, K., Kumar, B.R.: Effect of rotational speed on linear and non-linear optical properties of Sol- Gel Spin coated nanostructured CdS thin films (2019). https://doi.org/10.30799/jnst.238.19050210
Mokurala, K., Mallick, S., Bhargava, P.: Alternative quaternary chalcopyrite sulfides (Cu2FeSnS4 and Cu2CoSnS4) as electrocatalyst materials for counter electrodes in dye-sensitized solar cells. J. Power. Sour. 305, 134–143 (2016). https://doi.org/10.1016/j.jpowsour.2015.11.081
Sebai, M., Bousselmi, G., Lazzari, J.L., Kanzari, M.: Preparation and characterization of Cu2ZnxFe1−xSnS4 thin films deposited on intrinsic silicon substrates. Mater. Today Commun. 35,(2023). https://doi.org/10.1016/j.mtcomm.2023.105558
Prasad, S., Bansal, S., Pandey, S.P.: Materials today : proceedings effect of substrate rotation speed on structural, morphological, vibrational and optical properties of sol-gel derived Mn-Ni co-doped ZnO thin films. Mater. Today Proc. 49, 3008–3014 (2022). https://doi.org/10.1016/j.matpr.2020.10.172
Acknowledgements
This research did not receive specific financial support from public, commercial, or non-profit sectors.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2024 The Author(s), under exclusive license to Springer Nature Switzerland AG
About this chapter
Cite this chapter
Drissi, S. et al. (2024). Effect of Rotational Speed on Properties of Sol–Gel Spin Coated Cu2Fe0.5Co0.5SnS4 Thin Films for Solar Cell. In: Mabrouki, J., Mourade, A. (eds) Technical and Technological Solutions Towards a Sustainable Society and Circular Economy. World Sustainability Series. Springer, Cham. https://doi.org/10.1007/978-3-031-56292-1_26
Download citation
DOI: https://doi.org/10.1007/978-3-031-56292-1_26
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-031-56291-4
Online ISBN: 978-3-031-56292-1
eBook Packages: Earth and Environmental ScienceEarth and Environmental Science (R0)