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Mixed Schiff Base and 8-hydroxyquinoline Complexes with Manganese, Iron and Zinc– Synthesis, Characterization and Properties

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Trends in Environmental Sustainability and Green Energy (CGEEE 2023)

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Abstract

Mixed complex ions of Mn (II), Fe (II) and Zn (II), with Schiff base (L) as primary ligand and 8-hydroxyquinoline as a secondary ligand were prepared, in which the condensation of acetophenone and 2- aminophenol was employed for the production of Schiff base. The Schiff base ligand was a lustrous brown crystalline solid with a melting temperature of 240 ℃ that was obtained in a low yield of 36.21%. The metal complexes were produced as solids with dark to deep brown colors that stable to oxidation and decomposed at 310 ℃ to 340 ℃. The complexes’ molar conductance in dimethylformamide (DMF) was determined to range between 3.11 and 4.15 Ω−1cm2mol−1, indicating that they are non-electrolytic in nature. The presence of 11/2 uncoordinated water molecules was detected during the crystallization process in Manganese and iron complexes, while 2 was predicted for the Zn (II) complex. According to the IR- spectrum data, Schiff base ligand does lose the phenolic hydrogen during complexation and is bidentately coordinated to the metal ions by phenolic oxygen (deprotonated) and imine nitrogen (HC = N-) as monobasic ligand. Similar to this, hydroxyquinone coordinated using quinoline nitrogen and deprotonated phenolic oxygen. Data from the experiment suggested that the mixed ligand may be expressed as [ML (HQ)] nH2O with square planar geometry in the four coordinates.

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Authors and Affiliations

  1. Department of Mathematics and Natural Sciences, Prince Mohammad Bin Fahd University, AlKhobar, Saudi Arabia

    M. Amin Mir & Syed M. Hasnain

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  1. M. Amin Mir
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  2. Syed M. Hasnain
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Correspondence to M. Amin Mir .

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Editors and Affiliations

  1. Jeju National University, Jeju, Korea (Republic of)

    Jinkeun Kim

  2. Aalborg University, Denmark, Aalborg, Denmark

    Zhe Chen

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Mir, M.A., Hasnain, S.M. (2024). Mixed Schiff Base and 8-hydroxyquinoline Complexes with Manganese, Iron and Zinc– Synthesis, Characterization and Properties. In: Kim, J., Chen, Z. (eds) Trends in Environmental Sustainability and Green Energy. CGEEE 2023. Springer Proceedings in Earth and Environmental Sciences. Springer, Cham. https://doi.org/10.1007/978-3-031-52330-4_13

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