Skip to main content

Effect of Si on Microstructural and Magnetic Behaviour of Heat-Treated High Carbon Steel

  • Conference paper
  • First Online:
Characterization of Minerals, Metals, and Materials 2024 (TMS 2024)

Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

Included in the following conference series:

  • 620 Accesses

Abstract

Silicon (Si) is a versatile alloying element that can enhance the performance of high carbon steel by contributing to deoxidation, grain refinement, hardenability, strength, and toughness. The study investigates the influence of Si (0.8–3.6%) on the microstructural and magnetic properties of high carbon steel. The arrangement and density of magnetic moments, which are affected by the microstructure determines the saturation magnetisation of the material. Industrial-grade high carbon steel samples with varying silica were microstructurally tailored to obtain multi-phase steel microstructures. The optical and SEM analyses revealed a combination of cementite and plate martensite, wherein the martensitic structures became finer with higher Si content. The evolution of martensitic microstructures along with mild oxidation of Si inclusions in the grain boundaries of the surface were observed using Confocal microscopy. An increase in the cementite with an accompanied decrease in the martensitic fraction was determined by the quantitative analysis of the X-ray diffractograms. The saturation magnetisation (MS) of the samples witnessed a gradual decrease with increase in the Si content. Silicon’s role in high carbon steel is quite notable, therefore, the nature of heat treatment and level of Si addition can be adjusted to limit the formation of cementite and increase the ferritic martensite or austenite in the microstructure.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 219.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 279.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Islam T, Rashed HMMA (2019) Classification and application of plain carbon steels. In: Reference module in materials science and materials engineering. Elsevier, Amsterdam

    Google Scholar 

  2. Raabe D (2023) Dual phase steels. https://www.dierk-raabe.com/dual-phase-steels/

  3. Speich GR, Committee AH (1990) Dual-phase steels. In: Properties and selection: irons, steels, and high-performance alloys. ASM International

    Google Scholar 

  4. Handoko W, Pahlevani F, Sahajwalla V (2017) Corrosion behaviour of dual-phase high carbon steel—microstructure influence. J Manuf Mater Process 1(2):21

    CAS  Google Scholar 

  5. Satyendra (2014) Silicon in steels. https://www.ispatguru.com/silicon-in-steels/

  6. Drumond J et al (2012) Effect of silicon content on the microstructure and mechanical properties of dual-phase steels. Metallogr Microstruct Anal 1:217–223

    Article  CAS  Google Scholar 

  7. Huang Q, et al. (2018) Influence of Si addition on the carbon partitioning process in martensitic-austenitic stainless steels. In: IOP conference series: materials science and engineering. IOP Publishing

    Google Scholar 

  8. Kim B, Sietsma J, Santofimia MJ (2017) The role of silicon in carbon partitioning processes in martensite/austenite microstructures. Mater Des 127:336–345

    Article  CAS  Google Scholar 

  9. Mola J et al (2017) Tempering of martensite and subsequent redistribution of Cr, Mn, Ni, Mo, and Si between cementite and martensite studied by magnetic measurements. Metall Mater Trans A 48:5805–5812

    Article  CAS  Google Scholar 

  10. Samanta S et al (2013) Development of multiphase microstructure with bainite, martensite, and retained austenite in a co-containing steel through quenching and partitioning (Q&P) treatment. Metall Mater Trans A 44:5653–5664

    Article  CAS  Google Scholar 

  11. Kozeschnik E, Bhadeshia H (2008) Influence of silicon on cementite precipitation in steels. Mater Sci Technol 24(3):343–347

    Article  CAS  Google Scholar 

  12. Zhou J et al (2020) Strengthening a fine-grained low activation martensitic steel by nanosized carbides. Mater Sci Eng A 769:138471

    Article  CAS  Google Scholar 

  13. Gladman T (1966) On the theory of the effect of precipitate particles on grain growth in metals. Proc R Soc Lond Ser A Math Phys Sci 294(1438):298–309

    CAS  Google Scholar 

  14. Girault E et al (2001) Comparison of the effects of silicon and aluminium on the tensile behaviour of multiphase TRIP-assisted steels. Scrip Mater 44(6):885–892

    Article  CAS  Google Scholar 

  15. Wu J et al (2003) Austenite formation and decomposition. Mater Sci Technol 19:291–309

    Google Scholar 

  16. Owen W (1954) The effect of silicon on the kinetics of tempering. Trans Am Soc Metals 46:812–829

    Google Scholar 

  17. Barnard S et al (1981) Advances in the physical metallurgy and applications of steels. Metals Soc Lond 33:32

    Google Scholar 

  18. Lashgari H et al (2014) Composition dependence of the microstructure and soft magnetic properties of Fe-based amorphous/nanocrystalline alloys: a review study. J Non-Cryst Solids 391:61–82

    Article  CAS  Google Scholar 

  19. Pepperhoff W, Acet M (2001) Constitution and magnetism of iron and its alloys. Springer, New York

    Book  Google Scholar 

  20. Anya C, Baker T (1989) The effect of silicon on the grain size and the tensile properties of low carbon steels. Mater Sci Eng A 118:197–206

    Article  Google Scholar 

  21. Chen S, Rong L (2015) Effect of silicon on the microstructure and mechanical properties of reduced activation ferritic/martensitic steel. J Nucl Mater 459:13–19

    Article  CAS  Google Scholar 

  22. Herzer G (1997) Nanocrystalline soft magnetic alloys. Handbook Magn Mater 10:415–462

    CAS  Google Scholar 

Download references

Acknowledgments

This research was supported by the Australian Research Council’s Industrial Transformation Research Hub funding scheme (Project IH190100009). The authors acknowledge the facilities and the scientific and technical assistance of Microscopy Australia at the Electron Microscope Unit (EMU) within the Mark Wainwright Analytical Centre (MWAC) at UNSW Sydney.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Negin Sarmadi .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2024 The Minerals, Metals & Materials Society

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Sarmadi, N., Pahlevani, F., Udayakumar, S., Biswal, S., Ulrich, C., Sahajwalla, V. (2024). Effect of Si on Microstructural and Magnetic Behaviour of Heat-Treated High Carbon Steel. In: Peng, Z., et al. Characterization of Minerals, Metals, and Materials 2024. TMS 2024. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-031-50304-7_1

Download citation

Publish with us

Policies and ethics