Abstract
Indium is a strategic critical metal in manufacturing indium-tin oxide (ITO) thin films for LCD/LED screens. Nevertheless, indium in Earth’s crust is a rare dispersion with an average abundance of 0.02 ppm, which is difficult to recover from primary ore. Hence, scholars focused on Indium recovery from waste LCD screens using hydrometallurgy technologies, which were always with long process. In this paper, a novel process for the separation and recovery of indium from waste LCD by roasting under an H2-H2O atmosphere is proposed. Under optimal conditions, In2O3 can be reduced selectively to gaseous In2O, and then In2O can be recovered efficiently. The effects of roasting parameters on indium recovery were studied utilizing thermodynamic analysis, XRD, and ICP. The results showed that the indium in waste LCD can be reduced to In2O(g) under the H2-H2O atmosphere at 1100–1200 ℃, the recovery of indium was up to 96.53% with an enrichment ratio of 3700.
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References
Anić Vučinić A, Šimunić S, Radetić L, Presečki I (2023) Indium recycling from waste liquid crystal displays: is it possible ? Processes 11(6):1662
Illés IB, Nagy S, Kékesi T (2022) The recycling of pure metallic indium from waste LCD screens by a combined hydro-electrometallurgical method. Hydrometallurgy 213:105945
Fortin-Lecomte C, Tran LH, Rioux G, Coudert L, Blais J (2022) Recovery of indium from acidic leach solutions of spent LCD panels using ion exchange. Hydrometallurgy 210:105845
Song Q, Liu Y, Zhang L, Zhenming X (2021) Facile indium recovery from waste liquid crystal displays: chloride-facilitated indium electroreduction and stepwise Cu/MoO2 and indium electrodeposition. J Hazard Mater 415:125599
Schuster J, Ebin B (2021) Investigation of indium and other valuable metals leaching from unground waste LCD screens by organic and inorganic acid leaching. Sep Purif Technol 279:119659
Cui J, Zhu N, Mao F, Pingxiao W, Dang Z (2021) Bioleaching of indium from waste LCD panels by Aspergillus niger: method optimization and mechanism analysis. Sci Total Environ 790:148151
Qin J, Ning S, Fujita T, Wei Y, Zhang S, Lu S (2021) Leaching of indium and tin from waste LCD by a time-efficient method assisted planetary high energy ball milling. Waste Manage 120:193–201
Zhang L, Xu Z (2017) C, H, Cl, and in element cycle in wastes: vacuum pyrolysis of PVC plastic to recover indium in LCD panels and prepare carbon coating. Acs Sustain Chem Eng 5(10):8918–8929
Ma E, Xu Z (2013) Technological process and optimum design of organic materials vacuum pyrolysis and indium chlorinated separation from waste liquid crystal display panels. J Hazard Mater 263:610–617
Takahashi K, Sasaki A, Dodbiba G, Sadaki J, Sato N, Fujita T (2009) Recovering indium from the liquid crystal display of discarded cellular phones by means of chloride-induced vaporization at relatively low temperature. Metall Mater Trans A 40:891–900
Su Z, Wang Y, Zhang Y, Tao J (2023) A novel method for synchronous separation of In/Sn from waste indium tin oxide (ITO) target: In-situ regeneration of nano-ITO powder. Sep Purif Technol 310:123104
Su Z, Zhang Y, Liu B, Zhou Y, Jiang T, Li G (2016) Reduction behavior of SnO2 in the tin-bearing iron concentrates under CO–CO2 atmosphere. Part I: effect of magnetite. Powder Technol 292:251–259
Acknowledgements
The authors recognize the independent exploration and innovation project for graduate students at Central South University (Number 2023ZZTS0787).
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© 2024 The Minerals, Metals & Materials Society
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Su, Z., Hu, X., Guo, Q., Zhang, Y. (2024). Recovery of Indium from Waste Liquid Crystal Display Screen by Reduction Roasting Under H2-H2O Atmosphere. In: Forsberg, K., et al. Rare Metal Technology 2024. TMS 2024. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-031-50236-1_3
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DOI: https://doi.org/10.1007/978-3-031-50236-1_3
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