Skip to main content

Recovery of Vanadium (IV) from Leaching Solution Using Fe-MOF Material

  • Conference paper
  • First Online:
Composite Materials (TMS 2024)

Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

Included in the following conference series:

  • 412 Accesses

Abstract

Vanadium is an important strategic material that is widely utilized in aerospace, national defense, and metallurgical and chemical engineering fields. V(IV) is a stable form which is derived from the traditional sodium salt roasting-water leaching process for vanadium extraction that widely exists in the leaching solution. To achieve the recovery of V(IV) from the leaching solution, Fe-MOF was employed as an adsorbent for the adsorption of V(IV) from solution in this paper. The influences of reaction time, adsorbent dose, and solution pH on V(IV) adsorption were systematically examined. Under the conditions of initial V(IV) concentrations of 10 mg/L and 100 mg/L, a solution pH of 7, and an adsorbent dosage of 400 mg/L, the removal rates of V(IV) were 97.27% and 52.46%, and the adsorption capacities were 17.62 mg/g and 91.68 mg/g, respectively. The results demonstrated that Fe-MOF can realize the effective recovery of vanadium resources in solution.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Li H, Wang K, Hua W et al (2016) Selective leaching of vanadium in calcification-roasted vanadium slag by ammonium carbonate. Hydrometallurgy 160:18–25

    Article  Google Scholar 

  2. Kang Q, Zhang Y, Bao S (2019) Cleaning method of vanadium precipitation from stripped vanadium solution using oxalic acid. Powder Technol 355:667–674

    Article  Google Scholar 

  3. Li H, Li D, Yang Y et al (2020) Re-examination of complexation behaviors of V(V) and V(IV): experimental investigation and theoretical simulation. J Anal At Spectrom 35(5):878–885

    Article  Google Scholar 

  4. Wang Z, Chen L, Aldahrib T et al (2020) Direct recovery of low valence vanadium from vanadium slag—Effect of roasting on vanadium leaching. Hydrometallurgy 191:105156

    Article  Google Scholar 

  5. Abigail PR, José AHV, José RP et al (2015) Synthesis of protonated chitosan flakes for the removal of vanadium (III, IV and V) oxyanions from aqueous solutions. Microchem J 118:1–11

    Article  Google Scholar 

  6. Knežević L, Cukrov N, Bura Nakić E (2020) Ion-exchange chromatography as a tool for investigating vanadium speciation in sediments: preliminary studies. J Soils Sed 20(6):2733–2740

    Article  Google Scholar 

  7. Kończyk J, Kluziak K, Kołodyńska D (2022) Adsorption of vanadium (V) ions from the aqueous solutions on different biomass-derived biochars. J Environ Manage 313:114958

    Article  PubMed  Google Scholar 

  8. Bhatnagar A, Minocha AK, Pudasainee D et al (2008) Vanadium removal from water by waste metal sludge and cement immobilization. Chem Eng J 144(2):197–204

    Article  Google Scholar 

  9. Manohar DM, Noeline BF, Anirudhan TS (2005) Removal of vanadium(IV) from aqueous solutions by adsorption process with aluminum-pillared bentonite. Ind Eng Chem Res 44(17):6676–6684

    Article  Google Scholar 

  10. Jansson Charrier M, Guibal E, Roussy J et al (1996) Vanadium (IV) sorption by chitosan: kinetics and equilibrium. Water Res 30(2):465–475

    Article  Google Scholar 

  11. Vega ED, Pedregosa JC, Narda GE et al (2003) Removal of oxovanadium(IV) from aqueous solutions by using commercial crystalline calcium hydroxyapatite. Water Res 37(8):1776–1782

    Article  PubMed  Google Scholar 

  12. Ahmadijokani F, Tajahmadi S, Bahi A et al (2021) Ethylenediamine-functionalized Zr-based MOF for efficient removal of heavy metal ions from water. Chemosphere 264:128466

    Article  PubMed  Google Scholar 

  13. Shao Z, Huang C, Wu Q et al (2019) Ion exchange collaborating coordination substitution: more efficient Cr(VI) removal performance of a water-stable CuII-MOF material. J Hazard Mater 378:120719

    Article  PubMed  Google Scholar 

  14. Wang B, Ma Y, Xu W et al (2023) A novel S, N-rich MOF for efficient recovery of Au(III): performance and mechanism. J Hazard Mater 451:131051

    Article  PubMed  Google Scholar 

  15. Maksimchuk NV, Kovalenko KA, Fedin VP et al (2012) Cyclohexane selective oxidation over metal–organic frameworks of MIL-101 family: superior catalytic activity and selectivity. Chem Commun 48(54):6812–6814

    Article  Google Scholar 

  16. da Costa JS, Bertizzolo EG, Bianchini D et al (2021) Adsorption of benzene and toluene from aqueous solution using a composite hydrogel of alginate-grafted with mesoporous silica. J Hazard Mater 418:126405

    Article  PubMed  Google Scholar 

  17. Yousif A, El-Afandy A, Dabbour G et al (2022) Selective separation of V(IV) from its solutions using modified cellulose. J Dispersion Sci Technol 43(10):1427–1437

    Article  Google Scholar 

  18. Wang W, Huang Y, Han G et al (2022) Enhanced removal of P(V), Mo(VI) and W(VI) generated oxyanions using Fe-MOF as adsorbent from hydrometallurgical waste liquid: exploring the influence of ionic polymerization. J Hazard Mater 427:128168

    Article  PubMed  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China (NSFC) (No. U2004215, 51974280, U22A20130, 52150079) and Natural Science Foundation of Henan Province of China (No. 232300421196).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Guihong Han .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2024 The Minerals, Metals & Materials Society

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Wang, W., Huang, Y., Han, G. (2024). Recovery of Vanadium (IV) from Leaching Solution Using Fe-MOF Material. In: Wisner, B., Hunyadi Murph, S.E., Mastorakos, I.N., Paramsothy, M. (eds) Composite Materials . TMS 2024. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-031-50180-7_11

Download citation

Publish with us

Policies and ethics