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Bismuth Determination by Controlled-Potential Coulometry: Developing a Highly Accurate Procedure Based on GET 176

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Reference Materials in Measurement and Technology (RMMT 2022)

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Abstract

In this work, we develop a procedure for reproducing the units of bismuth mass fraction in metallic bismuth and those of bismuth (III) mass concentration in bismuth nitrate solutions by controlled-potential coulometry based on the GET 176–2019 State primary standard of mass (molar, atomic) fraction units and mass (molar) concentration of components in liquid and solid substances and materials based on coulometry. The results obtained can be used when manufacturing certified reference materials (CRMs) for the composition of high-purity bismuth and CRMs for the composition of solutions of bismuth (III) ions directly traceable to GET 176–2019. These CRMs may find application in pharmacological, metallurgical, and nuclear industries.

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Notes

  1. 1.

    Federal Information Fund for Ensuring the Uniformity of Measurements. Available via FIF EUM. https://fgis.gost.ru/fundmetrology. Accessed 4 August 2022 (In Russ.).

  2. 2.

    GSO 2732-83–2735-83 Reference materials composition of bismuth metal grade Vi 00-02. Available via FIF EUM. https://fgis.gost.ru/fundmetrology/registry/19/items/552242. Accessed 4 August 2022 (In Russ.).

  3. 3.

    GSO 5474-90 Reference materials composition of bismuth concentrate. Available via FIF EUM. https://fgis.gost.ru/fundmetrology/registry/19/items/583301. Accessed 4 August 2022 (In Russ.).

  4. 4.

    GSO 8463-2003 Reference materials composition of a solution of bismuth ions. Available via FIF EUM. https://fgis.gost.ru/fundmetrology/registry/19/items/391720. Accessed 4 August 2022 (In Russ.).

    GSO 7477-98 Reference materials composition of a solution of bismuth (III) ions. Available via FIF EUM. https://fgis.gost.ru/fundmetrology/registry/19/items/392396 Accessed 4 August 2022 (In Russ.).

  5. 5.

    GET 176-2019 State primary standard of units of mass (molar, atomic) fraction and mass (molar) concentration of components in liquid and solid substances and materials based on coulometry (includes 3 installations on the basis of constant current coulometry, controlled potential coulometry and inductively coupled plasma mass spectrometry): Custodian Institute UNIIM—Affiliated Branch of the D. I. Mendeleyev Institute for Metrology. Available via FIF EUM. https://fgis.gost.ru/fundmetrology/registry/12/items/1382712. Accessed 4 august 2022 (In Russ.).

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Acknowledgements

The research was performed within the framework of the research theme “Development, improvement, and maintenance of the state primary measurement standards, as well as development and improvement of the state primary reference measurement procedures (methods).” All measurements were performed using the facilities of UNIIM, a branch of D.I. Mendeleyev All-Russian Institute for Metrology.

Author Contribution

Zyskin V. M.—research concept, measurement technique development, experimental data collection, literature data review, preparation of the original text of the article; Sobina A. V.—supervision, experimental data analysis, revision and editing the text of the article.

Conflict of Interest

The article was prepared on the basis of a report presented at the V International Scientific Conference “Reference materials in measurements and technologies” (Yekaterinburg, September 13–16, 2022). The article was admitted for publication after the abstract was revised, the article was formalized and the review procedure was carried out.

The version in the Russian language is published in the journal “Measurement Standards. Reference Materials” 2023;19(4):129–141. (In Russ.). https://doi.org/10.20915/2077-1177-2023-19-4-129-141.

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Authors and Affiliations

  1. UNIIM—Affiliated Branch of the D. I. Mendeleyev Institute for Metrology, Yekaterinburg, Russia

    Veniamin M. Zyskin & Alena V. Sobina

Authors
  1. Veniamin M. Zyskin
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  2. Alena V. Sobina
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Corresponding author

Correspondence to Veniamin M. Zyskin .

Editor information

Editors and Affiliations

  1. UNIIM—Affiliated Branch of the D. I. Mendeleyev Institute for Metrology, Yekaterinburg, Russia

    Egor P. Sobina

  2. UNIIM—Affiliated Branch of the D. I. Mendeleyev Institute for Metrology, Yekaterinburg, Russia

    Sergey V. Medvedevskikh

  3. UNIIM—Affiliated Branch of the D. I. Mendeleyev Institute for Metrology, Yekaterinburg, Russia

    Olga N. Kremleva

  4. All-Russian Scientific Research Institute for Optical and Physical Measurements, Moscow, Russia

    Ivan S. Filimonov

  5. All-Russian Scientific Research Institute for Metrological Service, Moscow, Russia

    Elena V. Kulyabina

  6. D. I. Mendeleyev Institute for Metrology, Saint Petersburg, Russia

    Anna V. Kolobova

  7. Saint Petersburg State University, PetroAnalytica LLC, Saint Petersburg, Russia

    Andrey V. Bulatov

  8. All-Russian Scientific Research Institute of Physicotechnical and Radio Engineering Measurements, Moscow, Russia

    Vladimir I. Dobrovolskiy

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Zyskin, V.M., Sobina, A.V. (2024). Bismuth Determination by Controlled-Potential Coulometry: Developing a Highly Accurate Procedure Based on GET 176. In: Sobina, E.P., et al. Reference Materials in Measurement and Technology . RMMT 2022. Springer, Cham. https://doi.org/10.1007/978-3-031-49200-6_15

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