Abstract
The scientific community has focused many research efforts on finding natural materials suitable for the most efficient wastewater purification. Our contribution is removing organic contaminants by exploiting the natural properties of clay and organo-clay materials. Two raw clayey materials (MIC and NC) were collected from the Basilicata region (South Italy), and another one was a Wyoming Na-montmorillonite (MMT) supplied by the Clay Minerals Society. Octadecyl-trimethyl-ammonium (Br) (ODTMA) was the organic cation used for modifying the clay surface to micelle-clay status. Unfortunately, MIC and NC could not retain a sufficient amount of surfactant. The MMT-ODTMA system, prepared using a concentration of the organic cation higher than the critical micelle concentration (CMC), was very effective in removing from water the herbicide atrazine, selected as the model contaminant for this study. This result encourages us to continue investigations to offer a low-cost and straightforward system to purify water even at home or small settlement levels.
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References
“Public Health Statement for Atrazine”. (2003, September). Toxic substances portal-atrazine. Center for Disease Control, Agency for Toxic Substances and Disease Registry, Division of Toxicology and Human Health Sciences. Retrieved from, May 2, 2015.
Andrunik, M., & Bajda, T.: Modification of bentonite with cationic and nonionic surfactants: Structural and textural features. Materials, 12(22), 3772 (2019). https://doi.org/10.3390/ma12223772
Carrizosa, J., Koskinen, W. C., Hermosin, M. C., & Cornejo, J. (2001). Dicamba adsorption–desorption on organoclays. Applied Clay Science, 18(5–6), 223–231.
Ghafar, A. H., Radwan, E. K., & El-Wakeel, S. T. (2020). Removal of hazardous contaminants from water by natural and zwitterionic surfactant-modified clay. ACS Omega, 5, 6834–6845.
Murray, H. H. (2000). Traditional and new applications for kaolin, smectite, and palygorskite: A general overview. Applied Clay Science, 17(5–6), 207–221.
Neeraj, K., & Chandra, M. (2021). Basics of clay minerals and their characteristic properties. IntechOpen Book Series. https://doi.org/10.5772/intechopen.97672, https://www.intechopen.com/online-first/76780
Rodriguez-Cruz, M. S., Sanchez-Martin, M. J., Andrades, M. S., & Sanchez-Camazano, M. (2007). Modification of clay barriers with a cationic surfactant to improve the retention of pesticides in soils. Journal of Hazardous Materials, 139, 363–372.
Sarkar, B., Rusmin, R., Ugochukwu, U. C., Mukhopadhyay, R., & Manjaiah, K. M. (2019). Chapter 5—modified clay minerals for environmental applications. In M. Mercurio, B. Sarkar, & A. Langella (Eds.), Modified clay and zeolite nanocomposite materials (pp. 113–127), Elsevier, NY.
Wang, T., Zhu, J. X., Zhu, R. L., Ge, F., Yuan, P., & He, H. P. (2010). Enhancing the sorption capacity of CTMA-bentonite by simultaneous intercalation of cationic polyacrylamide. Journal of Hazardous Materials, 178, 1078–1084.
Wang, L., & Wang, A. (2008). Adsorption properties of Congo red from aqueous solution onto surfactant modified montmorillonite. Journal of Hazardous Materials, 160, 173–180.
Xi, Y., Frost Ray, L., & He Hongping, J. (2007). Modification of the surfaces of Wyoming montmorillonite by the cationic surfactants alkyl trimethyl, dialkyl dimethyl, and trialkyl methyl ammonium bromides. Journal of Colloid and Interface Science, 305(1), 150–158. https://doi.org/10.1016/j.jcis.2006.09.033
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Scrano, L., Pallara, M., Buccioni, R., Mongelli, G., Bufo, S.A., Laviano, R. (2023). Characterization of Natural and Modified Clay Used for a Filtration System Aiming at the Removal of Contaminants from Surface Water. In: Çiner, A., et al. Recent Research on Environmental Earth Sciences, Geomorphology, Soil Science, Paleoclimate, and Karst. MedGU 2021. Advances in Science, Technology & Innovation. Springer, Cham. https://doi.org/10.1007/978-3-031-42917-0_9
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