Abstract
The influence of low-molecular weight arena’s (LMA) on the dielectric behavior of a binary system with limited compatibility between components based on styrene-acrylonitrile (SAN)-polystyrene (PS) copolymers studied. Benzene found to selectively interact with SAN and PS, blocking the polymer–polymer interaction in interphase layer (IPL). The restructuring of the IPL structure in the presence of toluene revealed, as well as the increase in the stabilization of the lyophilic fluctuation network that forms the IPL. Styrene can be used as a compatibilizer of the studied polymer–polymer system. Benzonitrile causes weakening of intermolecular interaction in IPL due to selectivity, as well as dipole–dipole interaction of nitrile groups of the copolymer and benzonitrile. It was concluded that the possibility of the formation of a rigid lyophobic network, as well as the heterogeneity of mixtures of mixtures associated with this process, is controlled, in general, by the content of SAN in the compositions.
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Anoshenko, M., Bazylyuk, T., Iukhymenko, N., Budzinska, V. (2023). Effect of Low-Molecular Weight Arenes Additives on the Interphase Layer Structure of SAN-PS Systems and Dielectric Behavior of Such Compositions. In: Fesenko, O., Yatsenko, L. (eds) Nanostructured Surfaces, Nanocomposites and Nanomaterials, and Their Applications. NANO 2022. Springer Proceedings in Physics, vol 296. Springer, Cham. https://doi.org/10.1007/978-3-031-42704-6_13
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