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Industrial Scale Applications: Reaction-Based Processes

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Product, Process and Plant Design Using Subcritical and Supercritical Fluids for Industrial Application

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Abstract

In this chapter applications of sub- and supercritical fluids as reaction media for chemical and biochemical reactions as well as the reactant for different products are presented. The solvent properties of supercritical fluids enable them to apply them as solvent and as reactant in polymerization reactions and in hydrothermal synthesis. As solvent subcritical and supercritical fluids are applied for carbonylation, oxidation, hydrogenation, hydroformylation and as reaction media for biochemical reactions. Chemical reactions in supercritical media are already realized on industrial scale. The highest volume of use of supercritical fluids as reactant and as solvent media are processes on production of various polymer grades of polyethylene. Biochemical reactions in supercritical media were not yet applied in industrial scale. But most probably—due to excellent solvent properties of dense gases, low costs of some subcritical or supercritical fluids, possibilities of products fractionation and product formulation—these processes will sooner or later be applied in industrial scale.

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  1. Faculty of Chemistry and Chemical Engineering, University of Maribor, Maribor, Slovenia

    Željko Knez

  2. Unna, Germany

    Christoph Lütge

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Knez, Ž., Lütge, C. (2023). Industrial Scale Applications: Reaction-Based Processes. In: Product, Process and Plant Design Using Subcritical and Supercritical Fluids for Industrial Application. Springer, Cham. https://doi.org/10.1007/978-3-031-34636-1_4

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