Skip to main content

Plastic Litter in SE Spain Beaches: Characterization and Metal Content

  • Conference paper
  • First Online:
Proceedings of the 3rd International Conference on Microplastic Pollution in the Mediterranean Sea (ICMPMS 2022)

Abstract

Metal concentrations have been quantified in plastic pieces collected from four beaches located in the Mediterranean coast of Spain with different characteristics (i.e. anthropogenic pressures). Several sections of the beach were sampled (i.e. coastline, middle beach and upper dunes). After an acidic extraction, metal(oid)s levels in the samples were measured for by ICP-MS. In addition to the metal content, plastics have been classified according to their characteristics such as polymer type, color or state of degradation. These characteristics have shown to influence the adsorption capacity of metal(oid)s by plastics. Some preliminary results have shown that aged and dark colored plastics accumulate higher metal(oid)s levels probably associated to plastic surface modification. The most anthropized beaches (i.e. mining or industry) showed, in general, higher levels of metal(oid)s such as Fe, Pb and Zn. This work shows that metal content in plastics can give an idea about the pollution degree of the area where these plastic pieces have been collected. Therefore, this study is a contribution to the potential use of plastics as pollution monitors.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 189.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 249.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Similar content being viewed by others

References

  1. GESAMP (2019) Guidelines for the monitoring and assessment of plastic litter in the ocean. In: Kershaw PJ, Turra A, Galgani F (eds) IMO/FAO/UNESCO-IOC/UNIDO/WMO/IAEA/UN/UNEP/UNDP/ISA Joint Group of Experts on the Scientific Aspects of Marine Environmental Prote, Rep. Stud. GESAMP. no 99, 130p. http://www.gesamp.org/publications/guidelines-for-the-monitoring-and-assessment-of-plastic-litter-in-the-ocean

  2. Plastics Europe (2017) Plastics—the Facts 2017. https://doi.org/10.1016/j.marpolbul.2013.01.015

  3. GESAMP (2015) Sources, fate and effects of microplastics in the marine environment: part 2 of a global assessment (IMO, FAO/UNESCO-IOC/UNIDO/WMO/IAEA/UN/UNEP/UNDP). In: Kershaw PJ (ed) Rep. Stud. GESAMP No. 90, 96 pp

    Google Scholar 

  4. Castro RO, da Silva ML, de Araújo FV (2018) Review on microplastic studies in Brazilian aquatic ecosystems. Ocean Coast Manag 165:385–400. https://doi.org/10.1016/j.ocecoaman.2018.09.013

    Article  Google Scholar 

  5. Robertson DE (1968) Role of contamination in trace element analysis of sea water. Anal Chem 40:1067–1072

    Article  CAS  Google Scholar 

  6. Struempler AW (1973) Adsorption characteristics of silver, lead, cadmium, zinc, and nickel on borosilicate glass, polyethylene, and polypropylene container surfaces. Anal Chem 45:2251–2254. https://doi.org/10.1021/ac60335a014

    Article  CAS  Google Scholar 

  7. Giusti L, Hamilton Taylor J, Davison W, Hewitt CN (1994) Artefacts in sorption experiments with trace metals. Sci Total Environ 152:227–238. https://doi.org/10.1016/0048-9697(94)90314-X

  8. Weijuan L, Youqian D, Zuyi T (2001) Americium(III) adsorption on polyethylene from very dilute aqueous solutions. J Radioanal Nucl Chem 250:497–500. https://doi.org/10.1023/A:1017953206851

    Article  Google Scholar 

  9. Cobelo-Garcia A, Turner A, Millward GE, Couceiro F (2007) Behaviour of palladium(II), platinum(IV), and rhodium(III) in artificial and natural waters: influence of reactor surface and geochemistry on metal recovery. Anal Chim Acta 585:202–210. https://doi.org/10.1016/j.aca.2006.12.029

    Article  CAS  Google Scholar 

  10. Rodrigues JP, Duarte AC, Santos-Echeandía J (2022) Interaction of microplastics with metal(oid)s in aquatic environments: what is done so far? J Hazard Mater Adv 6:100072. https://doi.org/10.1016/j.hazadv.2022.100072

    Article  CAS  Google Scholar 

  11. Wang Q, Zhang Y, Wangjin X, Wang Y, Meng G, Chen Y (2020) The adsorption behavior of metals in aqueous solution by microplastics effected by UV radiation. J Environ Sci 87:272–280. https://doi.org/10.1016/j.jes.2019.07.006

    Article  CAS  Google Scholar 

  12. Acosta-coley I, Mendez-cuadro D, Rodriguez-cavallo E, De J, Olivero-verbel J (2019)Trace elements in microplastics in Cartagena: a hotspot for plastic pollution at the Caribbean.Mar Pollut Bull 139:402–411.https://doi.org/10.1016/j.marpolbul.2018.12.016

  13. Santos-Echeandía J, Rivera-Hernández JR, Rodrigues JP, Moltó V (2020)Interaction of mercury with beached plastics with special attention to zonation, degradation status and polymer type.Mar Chem 222:103788. https://doi.org/10.1016/j.marchem.2020.103788

  14. Nakashima E, Isobe A, Kako S, Itai T, Takahashi S, Guo X (2016) The potential of oceanic transport and onshore leaching of additive-derived lead by marine macro-plastic debris. Mar Pollut Bull 107:333–339. https://doi.org/10.1016/j.marpolbul.2016.03.038

    Article  CAS  Google Scholar 

  15. Carbery M, MacFarlane GR, O’Connor W, Afrose S, Taylor H, Palanisami T (2020) Baseline analysis of metal(loid)s on microplastics collected from the Australian shoreline using citizen science. Mar Pollut Bull 152:110914. https://doi.org/10.1016/j.marpolbul.2020.110914

    Article  CAS  Google Scholar 

  16. OSPAR (2010) Guideline for monitoring marine litter on the beaches in the OSPAR Maritime Area, vol 1. OSPAR Comm., p 84

    Google Scholar 

  17. Maršić-Lučić J, Lušić J, Tutman P, Bojanić Varezić D, Šiljić J, Pribudić J (2018) Levels of trace metals on microplastic particles in beach sediments of the island of Vis, Adriatic Sea, Croatia. Mar Pollut Bull 137:231–236. https://doi.org/10.1016/j.marpolbul.2018.10.027

  18. Hahladakis JN, Velis CA, Weber R, Iacovidou E, Purnell P (2018) An overview of chemical additives present in plastics: migration, release, fate and environmental impact during their use, disposal and recycling. J Hazard Mater 344:179–199. https://doi.org/10.1016/j.jhazmat.2017.10.014

    Article  CAS  Google Scholar 

  19. Filella M, Turner A (2018) Observational study unveils the extensive presence of Hazardous elements in beached plastics from Lake Geneva. Front Environ Sci 6:1–8. https://doi.org/10.3389/fenvs.2018.00001

    Article  Google Scholar 

  20. Salvaggio A, Tiralongo F, Krasakopoulou E, Marmara D, Giovos I, Crupi R, Messina G, Lombardo BM, Marzullo A, Pecoraro R, Scalisi EM, Copat C, Zuccarello P, Ferrante M, Brundo MV (2019) Biomarkers of Exposure to chemical contamination in the commercial fish species Lepidopus caudatus (Euphrasen, 1788): a particular focus on plastic additives. Front Physiol 10:1–13. https://doi.org/10.3389/fphys.2019.00905

    Article  Google Scholar 

  21. Fisner M, Majer A, Taniguchi S, Bícego M, Turra A, Gorman D (2017) Colour spectrum and resin-type determine the concentration and composition of polycyclic aromatic hydrocarbons (PAHs) in plastic pellets. Mar Pollut Bull 122:323–330. https://doi.org/10.1016/j.marpolbul.2017.06.072

    Article  CAS  Google Scholar 

  22. Haarman A, Gasser M (2016) Managing hazardous additives in WEEE plastic from the Indian informal sector

    Google Scholar 

  23. Shaw EJ, Turner A (2019) Recycled electronic plastic and marine litter. Sci Total Environ 694:133644. https://doi.org/10.1016/j.scitotenv.2019.133644

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Joana Patrício Rodrigues .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2023 The Author(s), under exclusive license to Springer Nature Switzerland AG

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Patrício Rodrigues, J., Rivera-Hernández, J.R., Bernárdez, P., Rocha-Santos, T., Costa Duarte, A., Santos-Echeandía, J. (2023). Plastic Litter in SE Spain Beaches: Characterization and Metal Content. In: Cocca, M., Ambrogi, V., Avolio, R., Castaldo, R., Errico, M.E., Gentile, G. (eds) Proceedings of the 3rd International Conference on Microplastic Pollution in the Mediterranean Sea. ICMPMS 2022. Springer Water. Springer, Cham. https://doi.org/10.1007/978-3-031-34455-8_12

Download citation

Publish with us

Policies and ethics