Abstract
This chapter considers the structure and properties of CER-based nanocomposites containing mesoporous silica particles, graphene oxide (GO), carbon nanotubes (CNTs), or “unzipped” carbon nanotubes (uCNTs). It is shown that by introducing glycidyl silane functionalized mesoporous silica FMCM-41, the thermal stability increases, whereas the dielectric constant and the dielectric loss tangent of the material decrease from 3.2 to 1.98 and from 0.023 to 0.009, respectively. GO produced a strong catalytic effect on the matrix curing process, and the addition of 1% GO significantly improved its mechanical properties. Of particular interest are the results of studying nanocomposites with functionalized uCNTs. In addition to significantly improving the mechanical and thermal properties of the matrix, uCNTs significantly enhanced its luminescence properties and absorption in the UV region.
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References
M. Ariraman, R.S. Kumar, M. Alagar, Studies on FMCM-41 reinforced Cyanate Ester nanocomposites for low k applications. RSC Adv. 4, 57759–57767 (2014). https://doi.org/10.1039/C4RA09399B
D. Cai, M. Song, Recent advance in functionalized graphene/polymer nanocomposites. J. Mater. Chem 20, 7906–7916 (2010). https://doi.org/10.1039/C0JM00530D
A. Fainleib, L. Bardash, G. Boiteux, O. Grigoryeva, Thermosetting cyanate ester resins filled with CNTs. In Advances in progressive thermoplastic and thermosetting polymers, perspectives and applications, vol. 10, ed. by Y. Mamunya, M. Iurzhenko, (Tehnopress editura, Iasi, Romania, 2012) p. 379
J. Fan, Z. Shi, M. Tian, J. Wang, J. Yin, Unzipped multiwalled carbon nanotube oxide/multiwalled carbon nanotube hybrids for polymer reinforcement. ACS Appl. Mater. Interfaces 4, 5956–5965 (2012). https://doi.org/10.1021/am301623t
Z. Hu, D. Zhao, Y. Wang, L. Huang, S. Wang, S.I Mao, O. Grigoryeva, P. Strizhak, A. Fainleib, J. Tang, The created excellent thermal, mechanical and fluorescent properties by doping Eu3+-complex-anchored carbon nanotubes in polycyanate resins. Nanomaterials 12(12), 2040 (2022). https://doi.org/10.3390/nano12122040.
H. Kim, A.A. Abdala, C.W. Macosko, Graphene-polymer nanocomposites. Macromolecules 43, 6515–6530 (2010). https://doi.org/10.1021/ma100572e
D.V. Kosynkin, A.L. Higginbotham, A. Sinitskii, J.R. Lomeda, J.R. Loeda, A. Dimiev, B.K. Price, J.M. Tour, Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons. Nature 458, 872–876 (2009). https://doi.org/10.1038/nature07872
H. Li, J. Gu, C. Liu, D. Wang, Thermal and mechanical properties of cyanate ester resin modified with acid-treated multiwalled carbon nanotubes. High Perform. Polym. 30, 38–46 (2018). https://doi.org/10.1177/0954008316675208
Q. Lin, L. Qu, Q. Lü, C. Fang, Preparation and properties of graphene oxide nanosheets/Cyanate Ester resin composites. Polym. Testing 32, 330–337 (2013a). https://doi.org/10.1016/j.polymertesting.2012.11.014
Y. Lin, C.A. Stone, S.J. Shaw, M. Song, Effect of carbon nanotubes on the curing dynamics and network formation of Cyanate Ester resin. J. Polym. Res. 20, 106–117 (2013b). https://doi.org/10.1007/s10965-013-0106-8
C. Lu, L. Yuan, Q. Guan, G. Liang, A. Gu, Optimizing ply pattern and composition of layered composites based on cyanate Ester, carbon nanotube and boron nitride: toward ultralow dielectric loss and high energy storage. J. Phys. Chem. C 122, 5238–5247 (2018). https://doi.org/10.1021/acs.jpcc.7b12117
W.E. Mahmoud, F.S. Al-Hazmi, G.H. Al-Harbi, Wall by wall controllable unzipping of MWCNTs via intercalation with oxalic acid to produce multilayers graphene oxide ribbon. Chem. Eng. J. 281, 192–198 (2015). https://doi.org/10.1016/j.cej.2015.06.081
S. Rakesh, C.P. Sakthidharan, M. Sarojadevi, P.R. Sundararajan, Monomer self-assembly and organo-gelation as a route to fabricate Cyanate Ester resins and their nanocomposites with carbon nanotubes. Europ. Polym. J. 68, 161–174 (2015). https://doi.org/10.1016/j.eurpolymj.2015.04.023
T. Ramanathan, A.A. Abdala, S. Stankovich, D.A. Dikin et al., Functionalized graphene sheets for polymer nanocomposites. Nat. Nanotechnol. 3, 327–331 (2008). https://doi.org/10.1038/nnano.2008.96
S. Stankovich, D.A. Dikin, G.H.B. Dommett et al., Graphene based composite materials. Nature 442, 282–286 (2006). https://doi.org/10.1038/nature04969
W. Sun, W. Sun, M.R. Kessler et al., Multifunctional properties of Cyanate Ester composites with SiO2 coated Fe3O4 fillers. ACS Appl. Mater. Interface 5, 1636–1642 (2013). https://doi.org/10.1021/am302520e
Y. Wang, Z.X. Shi, J. Yin, Unzipped multiwalled carbon nanotubes for mechanical reinforcement of polymer composites. J. Phys. Chem. C 114, 19621–19628 (2010). https://doi.org/10.1021/jp107151e
X. Wang, J. Jin, M. Song, Cyanate Ester resin/graphene nanocomposite: Curing dynamics and network formation. Europ. Polym. J. 48, 1034–1041 (2012). https://doi.org/10.1016/j.eurpolymj.2012.03.012
N. Yang, X. Qi, D. Yang, M. Chen, Y. Wang, L. Huang, O. Grygoryeva, P. Strizhak, A. Fainleib, J. Tang, Improved mechanical, anti-UV irradiation, and imparted luminescence properties of cyanate ester resin/unzipped multiwalled carbon nanotubes/europium nanocomposites. Materials 14, 4244 (2021). https://doi.org/10.3390/ma14154244
Z. Zhang, Z. Sun, J. Yao, D.V. Kosynkin, J.M. Tour, Transforming carbon nanotube devices into nanoribbon devices. J. Am. Chem. Soc. 131, 13460–13463 (2009). https://doi.org/10.1021/ja9045923
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Bershtein, V.A., Yakushev, P.N. (2023). Other CER-Based Nanocomposites. In: High-Temperature Polymer Nanocomposites Based on Heterocyclic Networks from Nitrile Monomers. Springer Series in Materials Science, vol 334. Springer, Cham. https://doi.org/10.1007/978-3-031-32943-2_5
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