Abstract
The results of physical studies of nanostructure, dynamics, mechanical and thermal properties of DCBE-based CER/amino-MMT nanocomposites are presented. The 2D MMT nanolayers content in these composites varied from 0.01 wt.% to 5 wt.%, and their analysis was performed by TEM, EDXS, mid-IR, far-IR, XRD, DSC, DMA, CRS, and TGA methods. The process of MMT exfoliation increased with decreasing MMT content in the composite, down to the formation of individual nanolayers at 0.1 wt.%. The ambivalent influence of MMT nanolayers on matrix dynamics, Tg, and thermal stability is shown, with the most positive effect at small and ultra-low MMT contents (0.025–0.5 wt.%). Anomalous composition and mechanical properties of the subsurface micron layers in the CER-based nanocomposites were detected.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
L. Baikova, T. Pesina, D. Sakseyev, A. Fainleib, V. Bershtein, Hybrid cyanate ester resin-based nanocomposites: increased indentation size effect due to anomalous composition of micron subsurface layer. Polym. Test. 53, 15–18 (2016). https://doi.org/10.1016/j.polymertesting.2016.05.001
F. Bergaya, G. Lagaly (eds), Handbook of Clay Science (Elsevier, 2013)
V.A. Bershtein, P.N. Yakushev, Laser-interferometric creep rate spectroscopy of polymers, in Advances in Polymer Science, vol. 230, ed. by K. Dusek (Springer, Heidelberg, Dordrecht, London, New York, 2010) pp. 73–219. https://doi.org/10.1007/978-3-642-13532-3
V.A. Bershtein, A.M. Fainleib, L.M. Egorova, K.G. Gusakova, O.P. Grigoyeva, D.A. Kirilenko, S.G. Konnikov, V.A. Ryzhov, P.N. Yakushev, N. Lavrenyuk, The impact of ultralow amounts of amino-modified MMT on dynamics and properties of densely crosslinked cyanate ester resins. Nanoscale Res. Lett. 10, 165–179 (2015). https://doi.org/10.1186/s11671-015-0868-5
A.M. Diez-Pascual, M.A. Gomez-Fatou, F. Anis, A. Flores, Nanoindentation in polymer nanocomposites. Progr. Mater. Sci. 67, 1–94 (2015)
C.-S. Han, Indentation size effect in polymers, in Advanced Materials Science Research, vol. 10, ed. By M.C. Wythers (Nova Science, New York, USA, 2011), pp. 393–413 (Chapter 15)
Y. Lin, M. Song, C.A. Stone, S.J. Shaw, A comprehensive study on the curing kinetics and network formation of cyanate ester resin/clay nanocomposites. Thermochim. Acta. 552, 77–86 (2013). https://doi.org/10.1016/j.tca.2012.11.009
L. Nicolais, A. Borzacchiello, S.M. Lee (eds.), Encyclopedia of Composites (Wiley, 2012)
D.R. Paul, L.M. Robeson, Polymer nanotechnology: nanocomposites. Polymer 49, 3187–3204 (2008). https://doi.org/10.1016/j.polymer.2008.04.017
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
Copyright information
© 2023 The Author(s), under exclusive license to Springer Nature Switzerland AG
About this chapter
Cite this chapter
Bershtein, V.A., Yakushev, P.N. (2023). CER/Montmorillonite Nanocomposites. In: High-Temperature Polymer Nanocomposites Based on Heterocyclic Networks from Nitrile Monomers. Springer Series in Materials Science, vol 334. Springer, Cham. https://doi.org/10.1007/978-3-031-32943-2_3
Download citation
DOI: https://doi.org/10.1007/978-3-031-32943-2_3
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-031-32942-5
Online ISBN: 978-3-031-32943-2
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)