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Kinetics and Mechanism of Si(IV) Electroreduction in Na3AlF6–Al2O3–SiO2 Melts on Al Cathode

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Electrolytic Production of Al–Si Alloys

Part of the book series: Monographs in Electrochemistry ((MOEC))

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Abstract

It was shown that the electrochemical reduction of Si(IV) proceeds stepwise, and its intermediate has a limited solubility, above which a passivating deposit [Si(II)]solid is formed at the interface. The condition for the precipitation of the latter is the passivation criterion PCSi(II)=[СSiO2][аSi(Сu)]=(1.27± 0.25)×10-4. It is obvious that when developing a technology for producing Al‒Si alloys, it is necessary to find such mode of loading SiO2 into an electrolytic cell which eliminates this negative phenomenon.

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Authors and Affiliations

  1. Department of Metallurgical Technologies, Ecology and Technogenic Safety, Zaporizhzhya National University, Zaporizhzhia, Ukraine

    Dmitriy Pruttskov & Aleksei Kirichenko

  2. Department of Chemical Technology, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, Kyiv, Ukraine

    Aleksander Andriiko

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  1. Dmitriy Pruttskov
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  2. Aleksander Andriiko
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  3. Aleksei Kirichenko
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Correspondence to Aleksander Andriiko .

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Pruttskov, D., Andriiko, A., Kirichenko, A. (2023). Kinetics and Mechanism of Si(IV) Electroreduction in Na3AlF6–Al2O3–SiO2 Melts on Al Cathode. In: Electrolytic Production of Al–Si Alloys. Monographs in Electrochemistry. Springer, Cham. https://doi.org/10.1007/978-3-031-29249-1_2

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