Abstract
Nowadays, phosphorus compounds, like metal phosphates and phosphonates have attained considerable attention as electrode materials for energy storage devices i.e., supercapacitors (SCs) and solar cells, etc., because of their high porosity, enlarged surface area, suitable pore size, well-regulated structural stability, excellent electrochemical reversibility, and rich active sites. Porous metal phosphates/phosphonates compounds are the most explored and investigated trendsetter electrode materials owing to their non-toxic, light atom weight, rich covalent states, environmental-friendly, and low-cost nature. These electrode schemes show much good performances (i.e., high specific capacitance, extraordinary energy density, long charge–discharge cycle life, and improved power density). Herein, we have focused on the topical progress and development of metal phosphates/phosphonates by concentrating on their beneficial utilization and prospective applications for the next generation as a novel class of electrode materials in SCs. Methodologies and the modified fabrication techniques to bring out the best merits of synthesized metal phosphates/phosphonates are focused, along with the technical and systematic perceptions are elaborated, as such analysis sturdily influences the electro-chemical energy storing abilities of the devices. Specific considerations have been put to such hybrid-kind of materials, where robust synergistic properties occur. Finally, the forthcoming perceptions and challenges for the metal phosphates/phosphonates are projected and discussed.
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References
Moshiri, S.: Consumer responses to gasoline price and non-price policies. Energy Policy 137, 111078 (2020)
Sen, D., Günay, E., Murat Tunç, K.M.: Forecasting annual natural gas consumption using socio-economic indicators for making future policies. Energy 173, 1106–1118 (2019)
Hadjipaschalis, I., Poullikkas, A., Efthimiou, V.: Overview of current and future energy storage technologies for electric power applications. Renew. Sustain. Energy Rev. 13(6–7), 1513–1522 (2009)
Colbertaldo, P., Agustin, S.B., Campanari, S., Brouwer, J.: Impact of hydrogen energy storage on California electric power system: towards 100% renewable electricity. Int. J. Hydrog. Energy 44(19), 9558–9576 (2019)
Lian, J., Zhang, Y., Ma, C., Yang, Y., Chaima, E.: A review on recent sizing methodologies of hybrid renewable energy systems. Energy Convers. Manage. 199, 112027 (2019)
Emmett, R.K., Roberts, M.E.: Recent developments in alternative aqueous redox flow batteries for grid-scale energy storage. J. Power Sour. 506, 230087 (2021)
Islam, Md. S., Shudo, Y., Hayami, S.: Energy conversion and storage in fuel cells and super-capacitors from chemical modifications of carbon allotropes: state-of-art and prospect. Bull. Chem. Soc. Jpn. 95(1), 1–25 (2022)
Chen, D., Jiang, K., Huang, T., Shen, G.: Recent advances in fiber supercapacitors: materials, device configurations, and applications. Adv. Mater. 32(5), 1901806 (2020)
Chen, B., Linli, Xu., Xie, Z., Wong, W.-Y.: Supercapacitor electrodes based on metal-organic compounds from the first transition metal series. EcoMat 3(3), e12106 (2021)
Wei, Q., Fu, Y., Zhang, G., Yang, D., Meng, G., Sun, S.: Rational design of novel nanostructured arrays based on porous AAO templates for electrochemical energy storage and conversion. Nano Energy 55, 234–259 (2019)
Arfeen, Z.A., Abdullah, Md.P., Hassan, R., Othman, B.M., Siddique, A., Rehman, A.U., Sheikh, U.U.: Energy storage usages: engineering reactions, economic-technological values for electric vehicles—a technological outlook. Intern. Trans. Electr. Energy Syst. 30(9), e12422 (2020)
Yan, J., Li, S., Lan, B., Wu, Y., Lee, P.S.: Rational design of nanostructured electrode materials toward multifunctional supercapacitors. Adv. Funct. Mater. 30(2), 1902564 (2020)
Shinde, P.A., Jun, S.C.: Review on recent progress in the development of tungsten oxide based electrodes for electrochemical energy storage. ChemSusChem 13(1), 11–38 (2020)
Jiya, I.N., Gurusinghe, N., Gouws, R.: Electrical circuit modelling of double layer capacitors for power electronics and energy storage applications: a review. Electronics 7(11), 268 (2018)
Yamazaki, S., Ito, T., Murakumo, Y., Naitou, M., Shimooka, T., Yamagata, M., Ishikawa, M.: Hybrid capacitors utilizing halogen-based redox reactions at interface between carbon positive electrode and aqueous electrolytes. J. Power Sources 326, 580–586 (2016)
Jabeen, N., Hussain, A., Xia, Q, Sun, S., Zhu, J., Xia, H.: High‐performance 2.6 V aqueous asymmetric supercapacitors based on in situ formed Na0.5MnO2 nanosheet assembled nanowall arrays. Adv. Mater. 29(32), 1700804 (2017)
Jabeen, N., Xia, Q., Savilov, S.V., Aldoshin, S.M., Yan, Yu., Xia, H.: Enhanced pseudocapacitive performance of α-MnO2 by cation preinsertion. ACS Appl. Mater. Interfaces 8(49), 33732–33740 (2016)
Xu, B., Zhang, H., Mei, H., Sun, D.: Recent progress in metal-organic framework-based supercapacitor electrode materials. Coord. Chem. Rev. 420, 213438 (2020)
Jabeen, N., Xia, Q., Yang, M., Xia, H.: Unique core–shell nanorod arrays with polyaniline deposited into mesoporous NiCo2O4 support for high-performance supercapacitor electrodes. ACS Appl. Mater. Interfaces 8(9), 6093–6100 (2016)
Qiu, M., Sun, P., Shen, L., Wang, K., Song, S., Yu, X., Tan, S., Zhao, C., Mai, W.: WO3 nanoflowers with excellent pseudo-capacitive performance and the capacitance contribution analysis. J. Mater. Chem. A 4(19), 7266–7273 (2016)
Gu, Y.-J., Wen, W., Zheng, S., Jin-Ming, Wu.: Rapid synthesis of high-areal-capacitance ultrathin hexagon Fe2O3 nanoplates on carbon cloth via a versatile molten salt method. Mater. Chem. Front. 4(9), 2744–2753 (2020)
Li, X., Elshahawy, A.M., Guan, C., Wang, J.: Metal phosphides and phosphates-based electrodes for electrochemical supercapacitors. Small 13(39), 1701530 (2017)
Zhao, H., Yuan, Z.-Y.: Design strategies of transition-metal phosphate and phosphonate electrocatalysts for energy-related reactions. Chemsuschem 14(1), 130–149 (2021)
Chen, L., Ren, J.-T., Wang, Y.-S., Tian, W.-W., Gao, L.-J., Yuan, Z.-Y.: Organic–inorganic cobalt-phosphonate-derived hollow cobalt phosphate spherical hybrids for highly efficient oxygen evolution. ACS Sustain. Chem. Eng. 7(15), 13559–13568 (2019)
Huang, Z.-Q., Lu, W.-X., Wang, B., Chen, W.-J., Xie, J.-L., Pan, D.-S., Zhou, L.-L., Song, J.-L.: A mesoporous C, N–Co doped Co-based phosphate ultrathin nanosheet derived from a phosphonate-based-MOF as an efficient electrocatalyst for water oxidation. Catal. Sci. Technol. 9(17), 4718–4724 (2019)
Terban, M.W., Shi, C., Silbernagel, R., Clearfield, A., Billinge, S.J.L.: Local environment of terbium (III) ions in layered nanocrystalline zirconium (IV) phosphonate–phosphate ion exchange materials. Inorgan. Chem. 56(15), 8837–8846 (2017)
Iqbal, M.F., Ashiq, M.N., Zhang, M.: Design of metals sulfides with carbon materials for supercapacitor applications: a review. Energy Technol. 9(4), 2000987 (2021)
Yin, H., Xian, Y., Zhang, Y., Li, W., Fan, J.: Structurally stabilizing and environment friendly triggers: double-metallic lead-free perovskites. Sol. Rrl 3(9), 1900148 (2019)
Yu, D., Zhai, S., Jiang, W., Goh, K., Wei, L., Chen, X., Jiang, R., Chen, Y.: Transforming pristine carbon fiber tows into high performance solid-state fiber supercapacitors. Adv. Mater. 27(33), 4895–4901 (2015)
Wang, Y., Xueliang, Wu., Han, Y., Li, T.: Flexible supercapacitor: overview and outlooks. J. Energy Storage 42, 103053 (2021)
Wei, Y.-S., Zhang, M., Zou, R., Qiang, Xu.: Metal–organic framework-based catalysts with single metal sites. Chem. Rev. 120(21), 12089–12174 (2020)
Pramanik, M., Salunkhe, R.R., Imura, M., Yamauchi, Y.: Phosphonate-derived nanoporous metal phosphates and their superior energy storage application. ACS Appl. Mater. Interfaces 8(15), 9790–9797 (2016)
Lv, X.-W., Weng, C.-C., Zhu, Y.-P., Yuan, Z.-Y.: Nanoporous metal phosphonate hybrid materials as a novel platform for emerging applications: a critical review. Small 17(22), 2005304 (2021)
Mirghni, A.A., Oyedotun, K.O., Mahmoud, B.A., Bello, A., Ray, S.C., Manyala, N.: Nickel-cobalt phosphate/graphene foam as enhanced electrode for hybrid supercapacitor. Compos. Part B Eng. 174, 106953 (2019)
Pang, H., Yan, Z., Wang, W., Chen, J., Zhang, J., Zheng, H.: Facile fabrication of NH4CoPO4·H2O nano/microstructures and their primarily application as electrochemical supercapacitor. Nanoscale 4(19), 5946–5953 (2012)
Zhang, S., Gao, H., Zhou, J.: Reduced graphene oxide-modified Ni-Co phosphate nanosheet self-assembled microplates as high-performance electrode materials for supercapacitors. J. Alloy. Compd. 746, 549–556 (2018)
Wang, S., Pang, H., Zhao, S., Shao, W., Zhang, N., Zhang, J., Chen, J., Li, S.: NH4CoPO4·H2O microbundles consisting of one-dimensional layered microrods for high performance supercapacitors. RSC Adv. 4(1), 340–347 (2014)
Zhao, Y., Chen, Z., Xiong, D.-B., Qiao, Y., Tang, Y., Gao, F.: Hybridized phosphate with ultrathin nanoslices and single crystal microplatelets for high performance supercapacitors. Sci. Rep. 6(1), 1–10 (2016)
Wang, X., Yan, Z., Pang, H., Wang, W., Li, G., Ma, Y., Zhang, H., Li, X., Chen, J.: NH4CoPO4·H2O microflowers and porous Co2P2O7 microflowers: effective electrochemical supercapacitor behavior in different alkaline electrolytes. Int. J. Electrochem. Sci 8(3), 3768–3785 (2013)
Li, Q., Li, Y., Peng, H., Cui, X., Zhou, M., Feng, K., Xiao, P.: Layered NH4CoxNi1−xPO4·H2O (0≦ x≦ 1) nanostructures finely tuned by Co/Ni molar ratios for asymmetric supercapacitor electrodes. J. Mater. Sci. 51(22), 9946–9957 (2016)
Li, Q., Li, X., Jiawei, Gu., Li, Y., Tian, Z., Pang, H.: Porous rod-like Ni2P/Ni assemblies for enhanced urea electrooxidation. Nano Res. 14(5), 1405–1412 (2021)
Pang, H., Yan, Z., Ma, Y., Li, G., Chen, J., Zhang, J., Weimin, Du., Li, S.: Cobalt pyrophosphate nano/microstructures as promising electrode materials of supercapacitor. J. Solid State Electrochem. 17(5), 1383–1391 (2013)
Ma, L., Li, Na., Long, C., Dong, B., Fang, D., Liu, Z., Li, Y.Z.X., Fan, J., Chen, S., Zhang, S., Zhi, C.: Achieving both high voltage and high capacity in aqueous zinc-ion battery for record high energy density. Adv. Func. Mater. 29(46), 1906142 (2019)
Mirghni, A.A., Momodu, D., Oyedotun, K.O., Dangbegnon, J.K., Manyala, N.: Electrochemical analysis of Co3(PO4)2 4H2O/graphene foam composite for enhanced capacity and long cycle life hybrid asymmetric capacitors. Electrochim. Acta 283, 374–384 (2018)
Li, H., Hongwen, Yu., Zhai, J., Sun, L., Yang, H., Xie, S.: Self-assembled 3D cobalt phosphate octahydrate architecture for supercapacitor electrodes. Mater. Lett. 152, 25–28 (2015)
Pang, H., Zhang, Y., Lai, W.-Y., Zheng, Hu., Huang, W.: Lamellar K2Co3(P2O7)2 2H2O nanocrystal whiskers: High-performance flexible all-solid-state asymmetric micro-supercapacitors via inkjet printing. Nano Energy 15, 303–312 (2015)
Wei, C., Cheng, C., Zhou, B., Yuan, X., Cui, T., Wang, S., Zheng, M., Pang, H.: Hierarchically porous NaCoPO4–Co3O4 hollow microspheres for flexible asymmetric solid-state supercapacitors. Part. Part. Syst. Charact. 32(8), 831–839 (2015)
Omar, F.S., Numan, A., Duraisamy, N., Bashir, S., Ramesh, K., Ramesh, S.J.R.A.: Ultrahigh capacitance of amorphous nickel phosphate for asymmetric supercapacitor applications. RSC Adv. 6(80), 76298–76306 (2016)
Minakshi, M., Mitchell, D., Jones, R., Alenazey, F., Watcharatharapong, T., Chakraborty, S., Ahuja, R.: Synthesis, structural and electrochemical properties of sodium nickel phosphate for energy storage devices. Nanoscale 8(21), 11291–11305 (2016)
Liu, M., Li, J., Han, W., Kang, L.: Simple synthesis of novel phosphate electrode materials with unique microstructure and enhanced supercapacitive properties. J. Energy Chem. 25(4), 601–608 (2016)
Gao, Y., Zhao, J., Run, Z., Zhang, G., Pang, H.: Microporous Ni11(HPO3)8(OH)6 nanocrystals for high-performance flexible asymmetric all solid-state supercapacitors. Dalton Trans. 43(45), 17000–17005 (2014)
Wei, C., Cheng, C., Wang, S., Xu, Y., Wang, J., Pang, H.: Sodium‐doped mesoporous Ni2P2O7 hexagonal tablets for high‐performance flexible all‐solid‐state hybrid supercapacitors. Chem. Asian J. 10(8), 1731–1737 (2015)
Bendi, R., Kumar, V., Bhavanasi, V., Parida, K., Lee, P.S.: Metal organic framework‐derived metal phosphates as electrode materials for supercapacitors. Adv. Energy Mater. 6(3), 1501833 (2016)
Tang, Y., Liu, Z., Guo, W., Chen, T., Qiao, Y., Shichun, Mu., Zhao, Y., Gao, F.: Honeycomb-like mesoporous cobalt nickel phosphate nanospheres as novel materials for high performance supercapacitor. Electrochim. Acta 190, 118–125 (2016)
Chen, C., Zhang, N., He, Y., Liang, Bo., Ma, R., Liu, X.: Controllable fabrication of amorphous Co–Ni pyrophosphates for tuning electrochemical performance in supercapacitors. ACS Appl. Mater. Interfaces 8(35), 23114–23121 (2016)
Li, B., Peng, Gu., Feng, Y., Zhang, G., Huang, K., Xue, H., Pang, H.: Ultrathin nickel–cobalt phosphate 2D nanosheets for electrochemical energy storage under aqueous/solid-state electrolyte. Adv. Func. Mater. 27(12), 1605784 (2017)
Liu, M.-C., Li, J.-J., Hu, Y.-X., Yang, Q.-Q., Kang, L.: Design and fabrication of Ni3P2O8-Co3P2O8·8H2O as advanced positive electrodes for asymmetric supercapacitors. Electrochim. Acta 201, 142–150 (2016)
Mirghni, A.A., Madito, M.J., Masikhwa, T.M., Oyedotun, K.O., Bello, A., Manyala, N.: Hydrothermal synthesis of manganese phosphate/graphene foam composite for electrochemical supercapacitor applications. J. Colloid Interface Sci. 494, 325–337 (2017)
Mei, P., Pramanik, M., Young, C., Huang, Z., Hossain, Md.S.A., Sugahara, Y., Yamauchi, Y (2017) Synthesis of mesostructured manganese phosphonate and its promising energy storage application. J. Mater. Chem. A 5(44), 23259–23266 (2017)
Zhang, Fan, Yuanyuan Bao, Shuangshuang Ma, Lu Liu, and Xin Shi. Hierarchical flower-like nickel phenylphosphonate microspheres and their calcined derivatives for supercapacitor electrodes. J. Mater. Chem. A 5(16), 7474–7481 (2017)
Donnadio, A., Nocchetti, M., Costantino, F., Taddei, M., Casciola, M.: Fábio da Silva Lisboa, and Riccardo Vivani. A layered mixed zirconium phosphate/phosphonate with exposed carboxylic and phosphonic groups: X-ray powder structure and proton conductivity properties. Inorg. Chem. 53(24), 13220–13226 (2014)
Alberti, G., Costantino, U., Casciola, M., Ferroni, S., Massinelli, L., Staiti, P.: "Preparation, characterization and proton conductivity of titanium phosphate sulfophenyl phosphonate. Solid State Ion. 145(1–4), 249–255 (2001)
Chakraborty, D., Bej, S., Sahoo, S., Chongdar, S., Ghosh, A., Banerjee, P., Bhaumik, A.: Novel Nanoporous Ti-phosphonate metal-organic framework for selective sensing of 2, 4, 6-trinitrophenol and a promising electrode in an energy storage device. ACS Sustain. Chem. Eng. 9(42), 14224–14237 (2021)
Murugavel, R., Choudhury, A.: Mrinalini Ganapati Walawalkar, Ramasamy Pothiraja, and Chintamani Nagesa Ramachandra Rao. Metal complexes of organophosphate esters and open-framework metal phosphates: synthesis, structure, transformations, and applications. Chem. Rev. 108(9), 3549–3655 (2008)
Poizot, P., Gaubicher, J., Renault, S., Dubois, L., Liang, Y., Yao, Y.: Opportunities and challenges for organic electrodes in electrochemical energy storage. Chem. Rev. 120(14), 6490–6557 (2020)
Afrin, S.: Muhammad Waqas Khan, Enamul Haque, Baiyu Ren, and Jian Zhen Ou. Recent advances in the tuning of the organic framework materials-the selections of ligands, reaction conditions, and post-synthesis approaches. J. Colloid Interface Sci. 623, 378–404 (2022)
Peeples, C.A., Kober, D., Schmitt, F.J., Tholen, P., Siemensmeyer, K., Halldorson, Q., Çoşut, B., Gurlo, A., Yazaydin, A.O., Hanna, G., Yücesan, G.: A 3D Cu‐naphthalene‐phosphonate metal–organic framework with ultra‐high electrical conductivity. Adv. Funct. Mater. 31(3), 2007294 (2021)
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Jabeen, N., Hussain, A., Ali, J. (2023). Metal Phosphates/Phosphonates for Supercapacitor Applications. In: Gupta, R.K. (eds) Metal Phosphates and Phosphonates. Engineering Materials. Springer, Cham. https://doi.org/10.1007/978-3-031-27062-8_14
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