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Acids and Bases

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Principles of Inorganic Chemistry

Abstract

This chapter discusses the properties of Brønsted (protic acids and bases) and Lewis acids and bases (electron pair acceptors and donors). For the Brønsted class, topics such as strength, amphoteric species, autoprotolysis, pH, superacids, and superbases, are described. For the Lewis class, the topics include acid and base strength, the hard and soft model, and frustrated Lewis pairs. The coverage of these topics includes references published through to mid-2021.

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Notes

  1. 1.

    Brønsted, J. N. Recl. Trav. Chim. Pays-Bas Belg. 1923, 42, 718.

  2. 2.

    Lewis, G. N. Valence and the Structure of Atoms and Molecules; Chemical Catalog Co.: New York, 1923; Ibid. J. Franklin Inst. 1938, 226, 293.

  3. 3.

    Silverstein, T. P. J. Chem. Educ. 2014, 91, 608, and references therein.

  4. 4.

    Mootz, D.; RĂ¼tter, H.; Wiskemann, R. Z. Anorg. Allg. Chem. 1994, 620, 1509.

  5. 5.

    Rustad, J. R.; Felmy, A. R.; Rosso, K. M.; Bylaska, E. J. Am. Mineral. 2003, 88, 436.

  6. 6.

    Botti, A.; Bruni, F.; Imberti, S.; Ricci, M. A.; Soper, R. K. J. Chem. Phys. 2003, 119, 5001.

  7. 7.

    Crespo, Y.; Hassanali, A. J. Chem. Phys. 2016, 144, #074304; Agmon, N.; Bakker, H. J.; Campen, R. K.; Henchman, R. H.; Pohl, P.; Roke, S.; Thämer, M.; Hassanali, A. Chem. Rev. 2016, 116, 7642; Egan, C. K.; Paesani, F. J. Chem. Theory Comput. 2018, 14, 1982; Shi, H.; Gong, L.-D.; Liu, C.; Lu, L.-N.; Yang, Z.-Z. J. Phys. Chem. A 2020, 124, 5963.

  8. 8.

    Mathieu, C.; Etcheberry, A.; Herlem, M.; Iranzo-Marin, F.; Liang, J.; Sculfort, J.-L. Electrochimica Acta 1993, 38, 781.

  9. 9.

    Parsons, G. H.; Rochester, C. H. J. Chem. Soc., Faraday Trans. 1 1972, 68, 523.

  10. 10.

    Himmell, D.; Radtke, V.; Butschke, B.; Krossing, I. Angew. Chem., Int. Ed. 2018, 57, 4386, and references therein.

  11. 11.

    McCoubrey, J. C. Trans. Faraday Soc. 1955, 51, 743.

  12. 12.

    Pauling, L. J. Chem. Educ. 1956, 33, 16; Ibid. 1976, 53, 762.

  13. 13.

    Myers, R. T. J. Chem. Educ. 1976, 53, 17, 802.

  14. 14.

    Lessley, S. D.; Ragsdale, R. O. J. Chem. Educ. 1976, 53, 19; Schmid, R.; Miah, A. M. J. Chem Educ. 2001, 78, 116; Ayotte, P.; HĂ©bert, M.; Marchand, P. J. Chem. Phys. 2005, 123, #184501; Fridgen, T. D. J. Chem. Educ. 2008, 85, 1220.

  15. 15.

    Sato, H.; Hirata, F. J. Am. Chem. Soc. 1999, 121, 3460; McGrath, M. J.; Kuo, I.-F. W.; Ngouana, B. F.; Ghogomu, J. N.; Mundy, C. J.; Marenich, A. V.; Cramer, C. J.; Truhlar, D. G.; Siepmann, J. I. Phys. Chem. Chem. Phys. 2013, 15, 13578; Devarajan, D.; Gustafson, S. J.; Bickelhaupt, F. M.; Ess, D. H. J. Chem. Educ. 2015, 92, 286.

  16. 16.

    Pokrovskii, V. A. Geochim. Cosmochim. Acta 1999, 63, 1107, and references therein.

  17. 17.

    Petkovic, D. M. J. Chem. Soc. Dalton 1982, 2425.

  18. 18.

    Trummal, A.; Lipping, L.; Kaljurand, I.; Koppel, I. A.; Leito, I. J. Phys. Chem. A 2016, 120, 3663.

  19. 19.

    Levanov, A. V.; Gurbanova, U. D.; Isaikina, O. Ya.; Lunin, V. V. Rus. J. Phys. Chem. A 2019, 93, 93.

  20. 20.

    Davis, W., Jr.; De Bruin, H. J. J. Inorg. Nucl. Chem. 1964, 26, 1069.

  21. 21.

    Lewis, T.; Winter, B.; Stern, A. C.; Baer, M. D.; Mundy, C. J.; Tobias, D. J.; Hemminger, J. C. J. Phys. Chem. B 2011, 115, 9445.

  22. 22.

    Sippola, H.; Taskinen, P. J. Chem. Eng. Data 2014, 59, 2389, and references therein.

  23. 23.

    Margarella, A. M.; Perrine, K. A.; Lewis, T.; Faubel, M.; Winter, B.; Hemminger, J. C. J. Phys. Chem. C 2013, 117, 8131; Niskanen, J.; Sahle, C. J.; Ruotsalainen, K. O.; MĂ¼ller, H.; Kavcic, M.; Zitnik, M.; Bucar, K.; Petric, M.; Hakala, M.; Huotari, S. Sci. Rep. 2016, 6, #21012, and references therein.

  24. 24.

    Hlushak, S.; Simonin, J. P.; De Sio, S.; Bernard, O.; Ruas, A.; Pochon, P.; Jan, S.; Moisy, P. Dalton Trans. 2013, 42, 2853.

  25. 25.

    Baer, M. D.; Fulton, J. L.; Balasubramanian, M.; Schenter, G. K.; Mundy, C. J. J. Phys. Chem. B 2014, 118, 7211.

  26. 26.

    Hammett, L. P.; Deyrup, A. J. J. Am. Chem. Soc. 1932, 54, 2721.

  27. 27.

    Gillespie, R. J.; Peel, T. E. J. Am. Chem. Soc. 1973, 95, 5173.

  28. 28.

    Culmann, J.-C.; Fauconet, M.; Jost, R.; Sommer, J. New. J. Chem. 1999, 23, 863.

  29. 29.

    KĂ¼hn-Velten, J.; Bodenbinder, M.; Bröchler, R.; Hägele, G.; Aubke, F. Can. J. Chem. 2002, 80, 1265.

  30. 30.

    Herlem, M. Pure Appl. Chem. 1977, 49, 107; Farcasiu, D. Catal. Let. 2001, 71, 95; Busca, G. Chem. Rev. 2007, 107, 5366.

  31. 31.

    Scholz, F.; Himmel, D.; Eisele, L.; Unkrig, W.; Krossing, I. Angew. Chem., Int. Ed. 2014, 53, 1689.

  32. 32.

    Scholz, F.; Himmel, D.; Scherer, H.; Krossing, I. Chem. Eur. J. 2013, 19, 109.

  33. 33.

    Vasireddy, S.; Ganguly, S.; Sauer, J.; Cook, W.; Spivey, J. J. Chem. Commun. 2011, 47, 785.

  34. 34.

    Kraft, A.; Beck, J.; Steinfeld, G.; Scherer, H.; Himmel, D.; Krossing, I. Organometallics 2012, 31, 7485.

  35. 35.

    Reed, C. A. Chem. Commun. 2005, 1669; Reed, C. A. Acct. Chem. Res. 2010, 43, 121.

  36. 36.

    Avelar, A.; Tham, F. S.; Reed, C. A. Angew. Chem., Int. Ed. 2009, 48, 3491.

  37. 37.

    Nava, M.; Stoyanova, I. V.; Cummings, S.; Stoyanov, E. S.; Reed, C. A. Angew. Chem., Int. Ed. 2014, 53, 1131.

  38. 38.

    Stoyanov, E. S.; Hoffmann, S. P.; Juhasz, M.; Reed, C. A. J. Am. Chem. Soc. 2006, 128, 3160.

  39. 39.

    Morton, A. A.; Holden, M. E. T. J. Am. Chem. Soc. 1947, 69, 1675.

  40. 40.

    Lochmann, L.; PospĂ­sil, J.; LĂ­m, D. Tetrahedron Lett. 1966, 257; Schlosser, M. J. Organomet. Chem. 1967, 8, 9; Hsieh, H. L.; Wofford, C. F. J. Polym. Chem. Part A-1 1969, 7, 449, 461.

  41. 41.

    Lochmann, L. Eur. J. Inorg. Chem. 2000, 1115; Seyferth, D. Organometallics 2009, 28, 2.

  42. 42.

    Unkelbach, C.; O’Shea, D. F.; Strohmann, C. Angew. Chem., Int. Ed. 2014, 53, 553.

  43. 43.

    Lochmann, L.; Janata, M. Cent. Eur. J. Chem. 2014, 12, 537; Robertson, S. D.; Uzelac, M.; Mulvey, R. E. Chem. Rev. 2019, 119, 8332.

  44. 44.

    Alder, R. W.; Bowman, P. S.; Steele, W. R. S.; Winterman, D. R. Chem. Commun. 1968, 723.

  45. 45.

    Verkade, J. G. Acc. Chem. Res. 1993, 26, 483; Maksic, Z. B.; Kovacevic, B.; Vianello, R. Chem. Rev. 2012, 112, 5240; Baric, D.; Kovacevic, B. Croat. Chem. Acta 2014, 87, 459; Raczynska, E. D. Chem. Rev. 2016, 116, 13454.

  46. 46.

    Kögel, J. F.; Oelkers, B.; Kovacevic, B.; Sundermeyer, J. J. Am. Chem. Soc. 2013, 135, 17,768.

  47. 47.

    Lensink, C.; Xi, S. K.; Daniels, L. M.; Verkade, J. G. J. Am. Chem. Soc. 1989, 111, 3478.

  48. 48.

    Tshepelevitsh, S.; KĂ¼tt, A.; Lõkov, M.; Kaljurand, I.; Saame, J.; Heering, A.; Plieger, P. G.; Vianello, R.; Leito, I. Eur J. Org. Chem. 2019, 6735.

  49. 49.

    Jensen, W. B. Chem. Rev. 1978, 78, 1.

  50. 50.

    Laurence, C.; Graton, J.; Gal, J.-F. J. Chem. Educ. 2011, 88, 1651.

  51. 51.

    Laurence, C.; Gal, J.-F. Lewis Basicity and Affinity Scales. Data and Measurement. John Wiley & Sons: Chichester, U.K., 2010.

  52. 52.

    Rowsell, B. D.; Gillespie, R. J.; Heard, G. L. Inorg. Chem. 1999, 38, 4659, and references therein.

  53. 53.

    Gutmann, V. Coord. Chem. Rev. 1976, 18, 225, and references therein.

  54. 54.

    Gal, J.-F.; Laurence, C. Chem. Eur. J. 2013, 19, 16,832.

  55. 55.

    Taft, R. W.; Pienta, N. J.; Kamlet, M. J.; Arnett, E. M. J. Org. Chem. 1981, 46, 661.

  56. 56.

    Maria, P.-C.; Gal, J.-F. J. Phys. Chem. 1985, 89, 1296.

  57. 57.

    Drago, R. S.; Dadmun, A. P.; Vogel, G. C. Inorg. Chem. 1993, 32, 2473; Vogel, G. C.; Drago, R. S. J. Chem. Educ. 1996, 73, 701; Joerg, S.; Drago, R. S.; Sales, I. Organometallics 1998, 17, 589.

  58. 58.

    Romm, I. P.; Noskov, Y. G.; Malkov, A. A. Russ. Chem. Bulletin, Int. Ed. 2007, 56, 1935, and references therein.

  59. 59.

    Gilbert, T. M. J. Compt. Chem. 2011, 32, 1493, and references therein.

  60. 60.

    Erdmann, P.; Leitner, J.; Schwarz, J.; Greb, L. ChemPhysChem 2020, 21, 987.

  61. 61.

    Greb, L. Chem. Eur. J. 2018, 24, 17881.

  62. 62.

    Pearson, R. G. J. Am. Chem. Soc. 1963, 85, 3533; Ibid. J. Chem. Educ. 1968, 45, 581, 643.

  63. 63.

    Ahrland, A.; Chatt, J.; Davies, N. R. Quart. Rev. (London) 1958, 12, 265.

  64. 64.

    Pearson, R. G. Inorg. Chim. Acta 1995, 240, 93.

  65. 65.

    CĂ¡rdenas, C.; Heidar-Zadeh, F.; Ayers, P. W. Phys. Chem. Chem. Phys. 2016, 18, 25721.

  66. 66.

    Ayers, P. W.; Parr, R. G.; Pearson, R. G. J. Chem Phys. 2006, 124, #194,107.

  67. 67.

    CĂ¡rdenas, C.; Ayers, P. W. Phys. Chem. Chem. Phys. 2013, 15, 13,959.

  68. 68.

    Stephan, D. W.; Erker, G. Angew. Chem., Int. Ed. 2010, 49, 46; Erker, G. Pure Appl. Chem. 2012, 84, 2203; Hounjet, L. J.; Stephan, D. W. Org. Process Res. Dev. 2014, 18, 385; Stephan, D. W. Acc. Chem. Res. 2015, 48, 306.

  69. 69.

    Welch, G. C.; Stephan, D. W. J. Am. Chem. Soc. 2007, 129, 1880.

  70. 70.

    Ullrich, M.; Lough, A. J.; Stephan, D. W. J. Am. Chem. Soc. 2009, 131, 52.

  71. 71.

    Geier, S. J.; Stephan, D. W. J. Am. Chem. Soc. 2009, 131, 3476.

  72. 72.

    Guo, Y.; Li, S. Inorg. Chem. 2008, 47, 6212.

  73. 73.

    Rokob, T. A.; Hamza, A.; PĂ¡pai, I. J. Am. Chem. Soc, 2009, 131, 10,701; Grimme, S.; Kruse, H.; Goerigk, L.; Erker, G. Angew. Chem., Int. Ed. 2010, 4, 1402; Zeonjuk, L. L.; St. Petkov, P.; Heine, T.; Röschenthaler, G.-V.; Eicher, J.; Vankova, N. Phys. Chem. Chem. Phys. 2015, 17, 10,687; Skara, G.; De Vleeschouwer, F.; Geerlings, P.; De Proft, F.; Pinter, B. Sci. Rep. 2017, 7, #16,024; Daru, J.; BakĂ³, I.; Stirling, A.; PĂ¡pai, I. ACS Catal. 2019, 9, 6049.

  74. 74.

    Rocchigiani, L.; Ciancaleoni, G.; Zuccaccia, C.; Macchioni, A. J. Am. Chem. Soc. 2014, 136, 112.

  75. 75.

    Kehr, G.; Schwendemann, S.; Erker, G. Top. Curr. Chem. 2013, 332, 45.

  76. 76.

    Sajid, M.; Kehr, G.; Wiegand, T.; Eckert, H.; Schwickert, C.; Pöttgen, R.; Cardenas, A. J. P.; Warren, T. H.; Fröhlich, R.; Daniliuc, C. G.; Erker, G. J. Am. Chem. Soc. 2013, 135, 8882.

  77. 77.

    Wang, X.; Kehr, G.; Daniliuc, C. G.; Erker, G. J. Am. Chem. Soc. 2014, 136, 3293, and references therein.

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Jordan, R.B. (2024). Acids and Bases. In: Principles of Inorganic Chemistry. Springer, Cham. https://doi.org/10.1007/978-3-031-22926-8_5

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