Skip to main content

Group 17

  • Chapter
  • First Online:
Principles of Inorganic Chemistry
  • 118 Accesses

Abstract

This chapter covers the nonradioactive elements of Group 17 (F to I), commonly called the halogens. Many properties of these elements are tabulated. There is extensive coverage of the natural sources and preparations of these elements, their structures, properties, uses, and biological effects. The structures, syntheses, reactions, and structures of the large family of their oxides, oxoacids, and oxoanions are described. Species with halogen–halogen bonds, either with the same halogen (polyhalogens) or with the different halogens (polyinterhalogens) are discussed with regard to their synthesis, structure, and bonding. The coverage of these topics includes references published through to mid-2021.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 119.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Hardcover Book
USD 159.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Notes

  1. 1.

    Corson, D. R.; MacKenzie, K. R.; Segrè, E. Phys. Rev. 1940, 58, 672, and references therein.

  2. 2.

    Sergentu, D.-C.; Réal, F.; Montavon, G.; Galland, N.; Maurice, R. Phys. Chem. Chem. Phys. 2016, 18, 32703; Guo, N.; Pottier, F.; Aupiais, J.; Alliot, C.; Montavon, G.; Champion, J. Inorg. Chem. 2018, 57, 4926; Meyer, G.-J. J. Label. Compd. Radiopharm. 2018, 61, 154, and references therein.

  3. 3.

    Hermann, A.; Hoffmann, R.; Aschroft, N. W. Phys. Rev. Lett. 2013, 111, #116404; Rossi, E.; De Santis, M.; Sorbelli, D.; Storchi, L.; Belpassi, L.; Belanzoni, P. Phys. Chem. Chem. Phys. 2020, 22, 1897.

  4. 4.

    Matsumoto, K.; Shima, K.; Sugimoto, T.; Inoue, T.; Hagiwara, R. Angew. Chem., Int. Ed. 2021, 60, 7887.

  5. 5.

    Groult, H.; Lantelme, F.; Salanne, M.; Simon, C.; Belhomme, C.; Morel, B.; Nicolas, F. J. Fluorine Chem. 2007, 128, 285.

  6. 6.

    Garcia-Herrero, I.; Margallo, M.; Onandía, R.; Aldaco, R. Chem. Technol. Environ. Policy 2018, 20, 229; Lee, D.-Y.; Elgowainy, A.; Dai, Q. Appl. Energy 2018, 217, 467.

  7. 7.

    Cavallo, G.; Metrangolo, P.; Milani, R.; Pilati, T.; Priimagi, A.; Resnati, G.; Terraneo, G. Chem. Rev. 2016, 116, 2478.

  8. 8.

    Angarov, V.; Kozuch, S. New J. Chem. 2018, 42, 1413.

  9. 9.

    Kolár, M. H.; Hobza, P. Chem. Rev. 2016, 116, 5155.

  10. 10.

    Kellett, C. W.; Kennepohl, P.; Berlinguette, C. P. Nat. Commun. 2020, 11, 3310.

  11. 11.

    Powell, B. M.; Heal, K. M.; Torrie, B. H. Mol. Phys. 1984, 53, 929.

  12. 12.

    Ivlev, S. I.; Karttunen, A. J.; Hoelzel, M.; Conrad, M.; Kraus, F. Chem. Eur. J. 2019, 25, 3310; Mattsson, S.; Paulus, B.; Redeker, F. A.; Beckers, H.; Riedel, S.; Müller, C. Chem. Eur. J. 2019, 25, 3318.

  13. 13.

    Morel, B.; Duperret, B. J. Fluorine Chem. 2009, 130, 7; Borgard, J. M.; Herbelet, F.; Gwinner, B. J. Fluorine Chem. 2016, 185, 17; Pashkevich, D. S. Russ. J. Phys. Chem. B 2019, 13, 993.

  14. 14.

    Haynes, A. Adv. Catal. 2010, 53, 1.

  15. 15.

    Furrow, S. D.; Schmitz, G. E. Chem. Phys. Lett. 2019, 730, 186.

  16. 16.

    Studier, M. H.; Appelman, E. H. J. Am. Chem. Soc. 1971, 93, 2349.

  17. 17.

    Appelman, E. H.; Thompson, R. C. J. Am. Chem. Soc. 1984, 106, 4167.

  18. 18.

    Rozen, S.; Brand, M. Angew. Chem., Int. Ed. Engl. 1986, 25, 554.

  19. 19.

    Sertchook, R.; Boese, A. D.; Martin, J. M. L. J. Phys. Chem. A 2006, 110, 8275, and references therein.

  20. 20.

    Morris, J. C. J. Phys. Chem. 1966, 70, 3798.

  21. 21.

    Kelley, C. M.; Tartar, H. V. J. Am. Chem. Soc. 1956, 78, 5752.

  22. 22.

    Bichsel, Y.; Von Gunten, U. Water Res. 2000, 34, 3197.

  23. 23.

    Urbansky, E. T.; Cooper, B. T.; Margerum, D. W. Inorg. Chem. 1997, 36, 1338.

  24. 24.

    Schmitz, G. Int. J. Chem. Kinet. 2004, 36, 480; Sebök-Nagy, K.; Körtvélyesi, T. Int. J. Chem. Kinet. 2004, 36, 596; Buxton, G. V.; Mulazzani, Q. G. Radiat. Phys. Chem. 2007, 76, 932; Hoffmann, E. H.; Tilgner, A.; Vogelsberg, U.; Wolke, R.; Hermann, H. ACS Earth Space Chem. 2019, 3, 2452.

  25. 25.

    Cordova, E. A.; Garayburu-Caruso, V.; Pearce, C. I.; Cantrell, K. J.; Morad, J. W.; Gillispie, E. C.; Riley, B. J.; Colon, F. C.; Levitskaia, T. G.; Saslow, S. A.; Qafoku, O.; Resch, C. T.; Rigali, M. J.; Szecsody, J. E.; Heald, S. M.; Balasubramanian, M.; Meyers, P.; Freedman, V. L. ACS Appl. Mater. Interface 2020, 12, 26113.

  26. 26.

    Beach, M. W.; Margerum, D. W. Inorg. Chem. 1990, 29, 1225.

  27. 27.

    Cai, L.; Li, L.; Yu, S. Water Res. 2020, 177, #115803; Szabó, M.; Bíro, V.; Simon, F.; Fábián, I. J. Hazard. Mater. 2020, 382, #120988.

  28. 28.

    Wang, T. X.; Margerum, D. W. Inorg. Chem. 1994, 33, 1050, and references therein.

  29. 29.

    Sivey, J. D.; Roberts, A. L. Environ. Sci. Technol. 2012, 46, 2141; Lau, S. S.; Reber, K. P.; Roberts, A. L. Ibid. 2019, 53, 11133.

  30. 30.

    Kormányos, B.; Nagypál, I.; Peintler, G.; Horváth, A. K. Inorg. Chem. 2008, 47, 7914, and references therein.

  31. 31.

    Nicoson, J. S.; Perrone, T. F.; Hartz, K. E. H.; Wang, L.; Margerum, D. W. Inorg. Chem. 2003, 42, 5818.

  32. 32.

    Reid, P. J. Acc. Chem. Res. 2001, 9, 691; Quiroga, S. L.; Perissinotti, L. J. J. Photochem. Photobiol. A 2005, 171, 59; Bixby, T. J.; Bolinger, J. C.; Patterson, J. D.; Reid, P. J. J. Chem. Phys. 2009, 130, #154503.

  33. 33.

    Chis, D.; Bogatu, C.; Vlaicu, I.; Iovi, A.; Botau, D.; Ursoiu, I. J. Environ. Prot. Ecol. 2006, 7, 36.

  34. 34.

    Deshwal, B. R.; Lee, H. K. J. Ind. Eng. Chem. 2005, 11, 330.

  35. 35.

    Deshwal, B. R.; Lee, H. K. J. Ind. Eng. Chem. 2005, 11, 125.

  36. 36.

    Yin, G.; Ni, Y. Can. J. Chem. Eng. 2000, 78, 827; Qian, Y.; Chen, Y.; Jiang, Y.; Zhang, L. J. Clean. Prod. 2007, 15, 920.

  37. 37.

    Deshwal, B. R.; Lee, H. K. J. Ind. Eng. Chem. 2005, 11, 330.

  38. 38.

    Horváth, A. K.; Nagypál, I.; Peintler, G.; Epstein, I. R.; Kustin, K. J. Phys. Chem. A 2003, 107, 6966, and references therein.

  39. 39.

    Ni, Y.; Yin, G. Ind. Eng. Chem. Res. 1998, 37, 2367.

  40. 40.

    Tarvo, V.; Lehtimaa, T.; Kuitunen, S.; Alopaeus, V.; Vuorinen, T.; Aittamaa, J. Ind. Eng. Chem. Res. 2009, 48, 6280.

  41. 41.

    Taube, H.; Dodgen, H. J. Am. Chem. Soc. 1949, 71, 3330.

  42. 42.

    Levason, W.; Ogden, J. S.; Spicer, M. D.; Webster, M.; Young, N. A. J. Am. Chem. Soc. 1989, 111, 6210.

  43. 43.

    Smolentsev, A. I.; Naumov, D. Y. J. Struct. Chem. 2008, 49, 696, and references therein.

  44. 44.

    Fuchs, H.; Landsberg, R. Zeit. Anorg. Allgem. Chem. 1970, 372, 127; Noszticzius, Z.; Noszticzius, E.; Schelly, Z. A. J. Phys. Chem. 1983, 87, 510; Wang, L.; Nicoson, J. S.; Hartz, K. E. H.; Francisco, J. S.; Margerum. D. W. Inorg. Chem. 2002, 41, 108.

  45. 45.

    Kageyama, T.; Yamamoto, T. Bull. Chem. Soc. Jpn. 1980, 53, 1175; Ibid. Makromol. Chem. 1981, 182, 705.

  46. 46.

    Lee, C. L.; Lister, M. W. Can. J. Chem. 1971, 49, 2822.

  47. 47.

    Ágreda J. A.; Field, R. J. J. Phys. Chem. A 2006, 110, 7867, and references therein.

  48. 48.

    Furuseth, S.; Selte, K.; Hope, H.; Kjekshus, A.; Klewe, B. Acta Chim. Scand. 1974, 28A, 71.

  49. 49.

    Markovic, S.; Petrovic, B. Int. J. Chem. Kinet. 2010, 42, 687; Schmitz, G.; Furrow, S. D. Ibid. 2013, 45, 525.

  50. 50.

    Stanbury, D. M. J. Phys. Chem. A 2018, 122, 3956.

  51. 51.

    DeAngelo, A. B.; George, M. H.; Kilburn, S. R.; Moore, T. M.; Wolf, D. C. Toxicol. Pathol. 1998, 26, 587; Naumov, S.; Von Sonntag, C. Ozone: Sci. Eng. 2008, 30, 339; Zhang, X.; De Silva, D.; Sun, B.; Fisher, J.; Bull, R. J.; Cotruvo, J. A.; Cummings, B. S. Toxicol. 2010, 209, 13.

  52. 52.

    Bray, W. C.; Liebhafsky, H. A. J. Am. Chem. Soc. 1931, 53, 38.

  53. 53.

    Schmitz, G. Phys. Chem. Chem. Phys. 2011, 13, 7102; Szabo, E.; Sevcik, P. J. Phys. Chem. A 2013, 117, 10604.

  54. 54.

    Stevanovic, K. Z.; Bubanja, I. N. M.; Stanisavljev, D. R. J. Phys. Chem. C 2019, 123, 16671.

  55. 55.

    Field, R. J.; Försterling, H.-D. J. Phys. Chem. 1986, 90, 5400.

  56. 56.

    Agreda, J. A.; Field, R. J.; Lyons, N. J. J. Phys. Chem. A 2000, 104, 5269.

  57. 57.

    Valkai, L.; Horváth, A. K. Inorg. Chem. 2016, 55, 1595.

  58. 58.

    Appelman, E. H. J. Am. Chem. Soc. 1968, 90, 1900.

  59. 59.

    Arndt, S.; Weis, D.; Donsbach, K.; Waldvogel, S. R. Angew. Chem., Int. Ed. 2020, 59, 8036.

  60. 60.

    Appelman, E. H. Acc. Chem. Res. 1973, 6, 113.

  61. 61.

    Crouthamel, C. E.; Hayes, A. M.; Martin, D. S.; J. Am. Chem. Soc. 1951, 73, 82; Laurie, S. H.; Williams, J. M.; Nyman, C. J. J. Phys. Chem. 1964, 68, 1311; Kren, R. M.; Dodgen, H. W.; Nyman, C. J. Inorg. Chem. 1968, 7, 446; Buist, G. J.; Hipperson, W. C. P.; Lewis, J. D. J. Chem. Soc. A 1969, 307; Aveston J. J. Chem. Soc. A 1969, 273; Valkai, L.; Peintler, G.; Horváth, A. K. Inorg. Chem. 2017, 56, 11417.

  62. 62.

    Kálmán, A.; Cruickshank, D. W. J. Acta Crystallogr. B 1970, 26, 1782.

  63. 63.

    Kellersohn, T. Acta Crystallogr. C 1991, 47, 1133.

  64. 64.

    Trnoska, A.; Nachbaur, E.; Belaj, F. J. Solid State Chem. 1994, 113, 393.

  65. 65.

    Trömel, M.; Dölling, H. Zeit. Anorg. Allg. Chem. 1975, 411, 41.

  66. 66.

    Sykora, R. E.; Wells, D. M.; Albrecht-Schmitt, T. E. Inorg. Chem. 2002, 47, 2697, and references therein.

  67. 67.

    Vlessidis, A. G.; Evmiridis, N. Anal. Chimica Acta 2009, 652, 85.

  68. 68.

    Haller, H.; Riedel, S. Z. Anorg. Allg. Chem. 2014, 640, 1281; Sonnenberg, K.; Mann, L.; Redeker, F. A.; Schmidt, B.; Riedel, S. Angew. Chem., Int. Ed. 2020, 59, 5464.

  69. 69.

    Benoit, R. L.; Guay, M.; Desbarres, J. Can. J. Chem. 1968, 46, 1261; Giordano, M. C.; Macagno, V. A.; Sereno, L. E. Anal. Chem. 1973, 45, 205.

  70. 70.

    Dodgen, H. W.; Jordan, A. D.; Jordan, R. B. J. Phys. Chem. 1973, 77, 2149.

  71. 71.

    Ruasse, M.-F.; Aubard, J.; Galland, B.; Adenier, A. J. Phys. Chem. 1986, 90, 4382.

  72. 72.

    Clark, T.; Murray, J. S.; Politzer, P. ChemPhysChem 2018, 19, 3044.

  73. 73.

    Ivlev, S. I.; Gaul, K.; Chen, M.; Karttunen, A. J.; Berger, R.; Kraus, F. Chem. Eur. J. 2019, 25, 5793.

  74. 74.

    Vossnacker, P.; Keilhack, T.; Schwarze, N.; Sonnenberg, K.; Seppelt, K.; Malischewski, M.; Riedel, S. Eur. J. Inorg. Chem. 2021, 1034.

  75. 75.

    Cremer, H. W.; Duncan, D. R. J. Chem. Soc. 1933, 181.

  76. 76.

    Rozen, S. Adv. Synth. Catal. 2010, 352, 2691.

  77. 77.

    Pantenburg, I.; Müller, I. Acta Crystallogr. C 2003, 59, m427.

  78. 78.

    Pantenburg, I.; Hohn, F.; Tebbe, K.-F. Zeit. Anorg. Allg. Chem. 2002, 628, 383.

  79. 79.

    Thanthiriwatte, K. S.; Spruell, J. M.; Dixon, D. A.; Christe, K. O.; Jenkins, H. D. B. Inorg. Chem. 2014, 53, 8136.

  80. 80.

    Hoyer, S.; Seppelt, K. Angew. Chem., Int. Ed. 2000, 39, 1448.

  81. 81.

    Boswijk, K. H.; Wiebenga, E. H. Acta Crystallogr. 1954, 7, 417.

  82. 82.

    Mahjoub, A. R.; Hoser, A.; Fuchs, J.; Seppelt, K. Angew. Chem., Int. Ed. Engl. 1989, 28, 1526.

  83. 83.

    Mahjoub, A. R.; Seppelt, K. Angew. Chem., Int. Ed. Engl. 1991, 30, 323.

  84. 84.

    Dixon, D. A.; Grant, D. J.; Christe, K. O.; Peterson, K. A. Inorg. Chem. 2008, 47, 5485.

  85. 85.

    Seppelt, K. Acc. Chem. Res. 2003, 36, 147; Pilmé, J.; Robinson, E. A.; Gillespie, R. J. Inorg. Chem. 2006, 45, 6198; Peterson, K. A.; Dixon, D. A.; Stoll, H. J. Phys. Chem A 2012, 116, 9777.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Robert B. Jordan .

Rights and permissions

Reprints and permissions

Copyright information

© 2024 The Author(s), under exclusive license to Springer Nature Switzerland AG

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Jordan, R.B. (2024). Group 17. In: Principles of Inorganic Chemistry. Springer, Cham. https://doi.org/10.1007/978-3-031-22926-8_17

Download citation

Publish with us

Policies and ethics