Abstract
This chapter covers the nonradioactive elements of Group 17 (F to I), commonly called the halogens. Many properties of these elements are tabulated. There is extensive coverage of the natural sources and preparations of these elements, their structures, properties, uses, and biological effects. The structures, syntheses, reactions, and structures of the large family of their oxides, oxoacids, and oxoanions are described. Species with halogen–halogen bonds, either with the same halogen (polyhalogens) or with the different halogens (polyinterhalogens) are discussed with regard to their synthesis, structure, and bonding. The coverage of these topics includes references published through to mid-2021.
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Notes
- 1.
Corson, D. R.; MacKenzie, K. R.; Segrè, E. Phys. Rev. 1940, 58, 672, and references therein.
- 2.
Sergentu, D.-C.; Réal, F.; Montavon, G.; Galland, N.; Maurice, R. Phys. Chem. Chem. Phys. 2016, 18, 32703; Guo, N.; Pottier, F.; Aupiais, J.; Alliot, C.; Montavon, G.; Champion, J. Inorg. Chem. 2018, 57, 4926; Meyer, G.-J. J. Label. Compd. Radiopharm. 2018, 61, 154, and references therein.
- 3.
Hermann, A.; Hoffmann, R.; Aschroft, N. W. Phys. Rev. Lett. 2013, 111, #116404; Rossi, E.; De Santis, M.; Sorbelli, D.; Storchi, L.; Belpassi, L.; Belanzoni, P. Phys. Chem. Chem. Phys. 2020, 22, 1897.
- 4.
Matsumoto, K.; Shima, K.; Sugimoto, T.; Inoue, T.; Hagiwara, R. Angew. Chem., Int. Ed. 2021, 60, 7887.
- 5.
Groult, H.; Lantelme, F.; Salanne, M.; Simon, C.; Belhomme, C.; Morel, B.; Nicolas, F. J. Fluorine Chem. 2007, 128, 285.
- 6.
Garcia-Herrero, I.; Margallo, M.; Onandía, R.; Aldaco, R. Chem. Technol. Environ. Policy 2018, 20, 229; Lee, D.-Y.; Elgowainy, A.; Dai, Q. Appl. Energy 2018, 217, 467.
- 7.
Cavallo, G.; Metrangolo, P.; Milani, R.; Pilati, T.; Priimagi, A.; Resnati, G.; Terraneo, G. Chem. Rev. 2016, 116, 2478.
- 8.
Angarov, V.; Kozuch, S. New J. Chem. 2018, 42, 1413.
- 9.
Kolár, M. H.; Hobza, P. Chem. Rev. 2016, 116, 5155.
- 10.
Kellett, C. W.; Kennepohl, P.; Berlinguette, C. P. Nat. Commun. 2020, 11, 3310.
- 11.
Powell, B. M.; Heal, K. M.; Torrie, B. H. Mol. Phys. 1984, 53, 929.
- 12.
Ivlev, S. I.; Karttunen, A. J.; Hoelzel, M.; Conrad, M.; Kraus, F. Chem. Eur. J. 2019, 25, 3310; Mattsson, S.; Paulus, B.; Redeker, F. A.; Beckers, H.; Riedel, S.; Müller, C. Chem. Eur. J. 2019, 25, 3318.
- 13.
Morel, B.; Duperret, B. J. Fluorine Chem. 2009, 130, 7; Borgard, J. M.; Herbelet, F.; Gwinner, B. J. Fluorine Chem. 2016, 185, 17; Pashkevich, D. S. Russ. J. Phys. Chem. B 2019, 13, 993.
- 14.
Haynes, A. Adv. Catal. 2010, 53, 1.
- 15.
Furrow, S. D.; Schmitz, G. E. Chem. Phys. Lett. 2019, 730, 186.
- 16.
Studier, M. H.; Appelman, E. H. J. Am. Chem. Soc. 1971, 93, 2349.
- 17.
Appelman, E. H.; Thompson, R. C. J. Am. Chem. Soc. 1984, 106, 4167.
- 18.
Rozen, S.; Brand, M. Angew. Chem., Int. Ed. Engl. 1986, 25, 554.
- 19.
Sertchook, R.; Boese, A. D.; Martin, J. M. L. J. Phys. Chem. A 2006, 110, 8275, and references therein.
- 20.
Morris, J. C. J. Phys. Chem. 1966, 70, 3798.
- 21.
Kelley, C. M.; Tartar, H. V. J. Am. Chem. Soc. 1956, 78, 5752.
- 22.
Bichsel, Y.; Von Gunten, U. Water Res. 2000, 34, 3197.
- 23.
Urbansky, E. T.; Cooper, B. T.; Margerum, D. W. Inorg. Chem. 1997, 36, 1338.
- 24.
Schmitz, G. Int. J. Chem. Kinet. 2004, 36, 480; Sebök-Nagy, K.; Körtvélyesi, T. Int. J. Chem. Kinet. 2004, 36, 596; Buxton, G. V.; Mulazzani, Q. G. Radiat. Phys. Chem. 2007, 76, 932; Hoffmann, E. H.; Tilgner, A.; Vogelsberg, U.; Wolke, R.; Hermann, H. ACS Earth Space Chem. 2019, 3, 2452.
- 25.
Cordova, E. A.; Garayburu-Caruso, V.; Pearce, C. I.; Cantrell, K. J.; Morad, J. W.; Gillispie, E. C.; Riley, B. J.; Colon, F. C.; Levitskaia, T. G.; Saslow, S. A.; Qafoku, O.; Resch, C. T.; Rigali, M. J.; Szecsody, J. E.; Heald, S. M.; Balasubramanian, M.; Meyers, P.; Freedman, V. L. ACS Appl. Mater. Interface 2020, 12, 26113.
- 26.
Beach, M. W.; Margerum, D. W. Inorg. Chem. 1990, 29, 1225.
- 27.
Cai, L.; Li, L.; Yu, S. Water Res. 2020, 177, #115803; Szabó, M.; Bíro, V.; Simon, F.; Fábián, I. J. Hazard. Mater. 2020, 382, #120988.
- 28.
Wang, T. X.; Margerum, D. W. Inorg. Chem. 1994, 33, 1050, and references therein.
- 29.
Sivey, J. D.; Roberts, A. L. Environ. Sci. Technol. 2012, 46, 2141; Lau, S. S.; Reber, K. P.; Roberts, A. L. Ibid. 2019, 53, 11133.
- 30.
Kormányos, B.; Nagypál, I.; Peintler, G.; Horváth, A. K. Inorg. Chem. 2008, 47, 7914, and references therein.
- 31.
Nicoson, J. S.; Perrone, T. F.; Hartz, K. E. H.; Wang, L.; Margerum, D. W. Inorg. Chem. 2003, 42, 5818.
- 32.
Reid, P. J. Acc. Chem. Res. 2001, 9, 691; Quiroga, S. L.; Perissinotti, L. J. J. Photochem. Photobiol. A 2005, 171, 59; Bixby, T. J.; Bolinger, J. C.; Patterson, J. D.; Reid, P. J. J. Chem. Phys. 2009, 130, #154503.
- 33.
Chis, D.; Bogatu, C.; Vlaicu, I.; Iovi, A.; Botau, D.; Ursoiu, I. J. Environ. Prot. Ecol. 2006, 7, 36.
- 34.
Deshwal, B. R.; Lee, H. K. J. Ind. Eng. Chem. 2005, 11, 330.
- 35.
Deshwal, B. R.; Lee, H. K. J. Ind. Eng. Chem. 2005, 11, 125.
- 36.
Yin, G.; Ni, Y. Can. J. Chem. Eng. 2000, 78, 827; Qian, Y.; Chen, Y.; Jiang, Y.; Zhang, L. J. Clean. Prod. 2007, 15, 920.
- 37.
Deshwal, B. R.; Lee, H. K. J. Ind. Eng. Chem. 2005, 11, 330.
- 38.
Horváth, A. K.; Nagypál, I.; Peintler, G.; Epstein, I. R.; Kustin, K. J. Phys. Chem. A 2003, 107, 6966, and references therein.
- 39.
Ni, Y.; Yin, G. Ind. Eng. Chem. Res. 1998, 37, 2367.
- 40.
Tarvo, V.; Lehtimaa, T.; Kuitunen, S.; Alopaeus, V.; Vuorinen, T.; Aittamaa, J. Ind. Eng. Chem. Res. 2009, 48, 6280.
- 41.
Taube, H.; Dodgen, H. J. Am. Chem. Soc. 1949, 71, 3330.
- 42.
Levason, W.; Ogden, J. S.; Spicer, M. D.; Webster, M.; Young, N. A. J. Am. Chem. Soc. 1989, 111, 6210.
- 43.
Smolentsev, A. I.; Naumov, D. Y. J. Struct. Chem. 2008, 49, 696, and references therein.
- 44.
Fuchs, H.; Landsberg, R. Zeit. Anorg. Allgem. Chem. 1970, 372, 127; Noszticzius, Z.; Noszticzius, E.; Schelly, Z. A. J. Phys. Chem. 1983, 87, 510; Wang, L.; Nicoson, J. S.; Hartz, K. E. H.; Francisco, J. S.; Margerum. D. W. Inorg. Chem. 2002, 41, 108.
- 45.
Kageyama, T.; Yamamoto, T. Bull. Chem. Soc. Jpn. 1980, 53, 1175; Ibid. Makromol. Chem. 1981, 182, 705.
- 46.
Lee, C. L.; Lister, M. W. Can. J. Chem. 1971, 49, 2822.
- 47.
Ágreda J. A.; Field, R. J. J. Phys. Chem. A 2006, 110, 7867, and references therein.
- 48.
Furuseth, S.; Selte, K.; Hope, H.; Kjekshus, A.; Klewe, B. Acta Chim. Scand. 1974, 28A, 71.
- 49.
Markovic, S.; Petrovic, B. Int. J. Chem. Kinet. 2010, 42, 687; Schmitz, G.; Furrow, S. D. Ibid. 2013, 45, 525.
- 50.
Stanbury, D. M. J. Phys. Chem. A 2018, 122, 3956.
- 51.
DeAngelo, A. B.; George, M. H.; Kilburn, S. R.; Moore, T. M.; Wolf, D. C. Toxicol. Pathol. 1998, 26, 587; Naumov, S.; Von Sonntag, C. Ozone: Sci. Eng. 2008, 30, 339; Zhang, X.; De Silva, D.; Sun, B.; Fisher, J.; Bull, R. J.; Cotruvo, J. A.; Cummings, B. S. Toxicol. 2010, 209, 13.
- 52.
Bray, W. C.; Liebhafsky, H. A. J. Am. Chem. Soc. 1931, 53, 38.
- 53.
Schmitz, G. Phys. Chem. Chem. Phys. 2011, 13, 7102; Szabo, E.; Sevcik, P. J. Phys. Chem. A 2013, 117, 10604.
- 54.
Stevanovic, K. Z.; Bubanja, I. N. M.; Stanisavljev, D. R. J. Phys. Chem. C 2019, 123, 16671.
- 55.
Field, R. J.; Försterling, H.-D. J. Phys. Chem. 1986, 90, 5400.
- 56.
Agreda, J. A.; Field, R. J.; Lyons, N. J. J. Phys. Chem. A 2000, 104, 5269.
- 57.
Valkai, L.; Horváth, A. K. Inorg. Chem. 2016, 55, 1595.
- 58.
Appelman, E. H. J. Am. Chem. Soc. 1968, 90, 1900.
- 59.
Arndt, S.; Weis, D.; Donsbach, K.; Waldvogel, S. R. Angew. Chem., Int. Ed. 2020, 59, 8036.
- 60.
Appelman, E. H. Acc. Chem. Res. 1973, 6, 113.
- 61.
Crouthamel, C. E.; Hayes, A. M.; Martin, D. S.; J. Am. Chem. Soc. 1951, 73, 82; Laurie, S. H.; Williams, J. M.; Nyman, C. J. J. Phys. Chem. 1964, 68, 1311; Kren, R. M.; Dodgen, H. W.; Nyman, C. J. Inorg. Chem. 1968, 7, 446; Buist, G. J.; Hipperson, W. C. P.; Lewis, J. D. J. Chem. Soc. A 1969, 307; Aveston J. J. Chem. Soc. A 1969, 273; Valkai, L.; Peintler, G.; Horváth, A. K. Inorg. Chem. 2017, 56, 11417.
- 62.
Kálmán, A.; Cruickshank, D. W. J. Acta Crystallogr. B 1970, 26, 1782.
- 63.
Kellersohn, T. Acta Crystallogr. C 1991, 47, 1133.
- 64.
Trnoska, A.; Nachbaur, E.; Belaj, F. J. Solid State Chem. 1994, 113, 393.
- 65.
Trömel, M.; Dölling, H. Zeit. Anorg. Allg. Chem. 1975, 411, 41.
- 66.
Sykora, R. E.; Wells, D. M.; Albrecht-Schmitt, T. E. Inorg. Chem. 2002, 47, 2697, and references therein.
- 67.
Vlessidis, A. G.; Evmiridis, N. Anal. Chimica Acta 2009, 652, 85.
- 68.
Haller, H.; Riedel, S. Z. Anorg. Allg. Chem. 2014, 640, 1281; Sonnenberg, K.; Mann, L.; Redeker, F. A.; Schmidt, B.; Riedel, S. Angew. Chem., Int. Ed. 2020, 59, 5464.
- 69.
Benoit, R. L.; Guay, M.; Desbarres, J. Can. J. Chem. 1968, 46, 1261; Giordano, M. C.; Macagno, V. A.; Sereno, L. E. Anal. Chem. 1973, 45, 205.
- 70.
Dodgen, H. W.; Jordan, A. D.; Jordan, R. B. J. Phys. Chem. 1973, 77, 2149.
- 71.
Ruasse, M.-F.; Aubard, J.; Galland, B.; Adenier, A. J. Phys. Chem. 1986, 90, 4382.
- 72.
Clark, T.; Murray, J. S.; Politzer, P. ChemPhysChem 2018, 19, 3044.
- 73.
Ivlev, S. I.; Gaul, K.; Chen, M.; Karttunen, A. J.; Berger, R.; Kraus, F. Chem. Eur. J. 2019, 25, 5793.
- 74.
Vossnacker, P.; Keilhack, T.; Schwarze, N.; Sonnenberg, K.; Seppelt, K.; Malischewski, M.; Riedel, S. Eur. J. Inorg. Chem. 2021, 1034.
- 75.
Cremer, H. W.; Duncan, D. R. J. Chem. Soc. 1933, 181.
- 76.
Rozen, S. Adv. Synth. Catal. 2010, 352, 2691.
- 77.
Pantenburg, I.; Müller, I. Acta Crystallogr. C 2003, 59, m427.
- 78.
Pantenburg, I.; Hohn, F.; Tebbe, K.-F. Zeit. Anorg. Allg. Chem. 2002, 628, 383.
- 79.
Thanthiriwatte, K. S.; Spruell, J. M.; Dixon, D. A.; Christe, K. O.; Jenkins, H. D. B. Inorg. Chem. 2014, 53, 8136.
- 80.
Hoyer, S.; Seppelt, K. Angew. Chem., Int. Ed. 2000, 39, 1448.
- 81.
Boswijk, K. H.; Wiebenga, E. H. Acta Crystallogr. 1954, 7, 417.
- 82.
Mahjoub, A. R.; Hoser, A.; Fuchs, J.; Seppelt, K. Angew. Chem., Int. Ed. Engl. 1989, 28, 1526.
- 83.
Mahjoub, A. R.; Seppelt, K. Angew. Chem., Int. Ed. Engl. 1991, 30, 323.
- 84.
Dixon, D. A.; Grant, D. J.; Christe, K. O.; Peterson, K. A. Inorg. Chem. 2008, 47, 5485.
- 85.
Seppelt, K. Acc. Chem. Res. 2003, 36, 147; Pilmé, J.; Robinson, E. A.; Gillespie, R. J. Inorg. Chem. 2006, 45, 6198; Peterson, K. A.; Dixon, D. A.; Stoll, H. J. Phys. Chem A 2012, 116, 9777.
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Jordan, R.B. (2024). Group 17. In: Principles of Inorganic Chemistry. Springer, Cham. https://doi.org/10.1007/978-3-031-22926-8_17
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