Abstract
A three-dimensional numerical model coupled the fluid-flow simulation and the reaction kinetics was established to study the evolution of the sulfur content in the molten steel. The VOF, k-ε, and DPM models were employed to simulate the fluid flow of three phases in the ladle furnace, including the steel, the slag, and the air. Reactions between the steel and the slag were considered in the simulation using a series of user defined functions. The steel-slag reactions had a significant effect on the sulfur content in the molten steel, resulting the continuous decrease of the sulfur content. The [S] content reduced from 0.077 wt% into 0.01 wt% in 50 min. The distribution of [S] in the molten steel was uneven, with the lowest near the steel-slag interface and the highest in the middle zone between the argon blowing point and the ladle wall.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Maciejewski J (2015) The effects of sulfide inclusions on mechanical properties and failures of steel components. J Fail Anal Prev 15(2):169–178
Weider C, Pichard C (1991) Effects of sulphur and inclusion morphology in friction welding of structural steels. Weld Int 5(5):369–377
Shi C, Huang Y, Zhang J, Li J, Zheng X (2021) Review on desulfurization in electroslag remelting. Int J Miner Metall Mater 28(1):18–29
Visuri VV, Vuolio T, Haas T, Fabritius T (2020) A review of modeling hot metal desulfurization. Steel Res Int 91(4):1900454
Kang JG, Shin JH, Chung Y, Park JH (2017) Effect of slag chemistry on the desulfurization kinetics in secondary refining processes. Metall Mater Trans B 48(4):2123–2135
Takahashi K, Utagawa K, Shibata H, Kitamura S, Kikuchi N, Kishimoto Y (2012) Influence of solid CaO and liquid slag on hot metal desulfurization. ISIJ Int 52(1):10–17
Yang AF, Karasev A, Jönsson PG (2015) Characterization of metal droplets in slag after desulfurization of hot metal. ISIJ Int 55(3):570–577
Cao Q, Pitts A, Nastac L (2018) Numerical modelling of fluid flow and desulphurisation kinetics in an argon-stirred ladle furnace. Ironmaking Steelmaking 45(3):280–287
Fan W, Zhang J, Ao W, Huang J (2015) Effect of Al2O3 and CaF2 on melting temperature of high calcium ladle desulfurization slag. Adv Mater Res 1094:325–328
Wang F, Tan J, Huang X, Wang Q, Liu Z, Baleta J, Li B (2022) Mathematical and numerical predictions of desulfurization behavior in the electromagnetically controlled vibrating-electrode electroslag remelting furnace. Metall Mater Trans B 53(3):1792–1805
Uriostegui Hernandez A, Garnica Gonzalez P, Ramos Banderas JA, Solorio Diaz G, Hernandez Bocanegra CA (2022) Desulphurization kinetic prediction into a steel ladle by coupling thermodynamic correlations, fluidynamics and heat transfer. ISIJ Int 62(6):1189–1198
Jonsson L, Sichen D, Jönsson P (1998) A new approach to model sulphur refining in a gas-stirred Ladle—a coupled CFD and thermodynamic model. ISIJ Int 38(3):260–267
Andersson AMT, Jonsson LTI, Josson PG (2003) A model of reoxidation from the top slag and the effect on sulphur refining during vacuum degassing. Scand J Metall 32(3):123–136
Lou W, Wang X, Liu Z, Luo S, Zhu M (2018) Numerical simulation of desulfurization behavior in ladle with bottom powder injection. ISIJ Int 58(11):2042–2051
Lou W, Zhu M (2015) Numerical simulation of slag-metal reactions and desulfurization efficiency in gas-stirred ladles with different thermodynamics and kinetics. ISIJ Int 55(5):961–969
Lou W, Zhu M (2014) numerical simulation of desulfurization behavior in gas-stirred systems based on computation fluid dynamics—simultaneous reaction model (CFDSRM) coupled model. Metall Mater Trans B 45(5):1706–1722
Zhang Y, Ren Y, Zhang L (2017) Modeling transient evolution of inclusion in Si-Mn-killed steels during the ladle mixing process. Metall Res Technol 114(3):308
Zhang Y, Ren Y, Zhang L (2018) Kinetic study on compositional variations of inclusions, steel and slag during refining process. Metall Res Technol 115(4):1–7
Wang J, Zhang L, Cheng G, Ren Q, Ren Y (2021) Dynamic mass variation and multiphase interaction among steel, slag, lining refractory and nonmetallic inclusions: laboratory experiments and mathematical prediction. Int J Miner Metall Mater 28(8):1298–1308
Luo Y, Liu C, Ren Y, Zhang L (2018) Modeling on the fluid flow and mixing phenomena in a RH steel degasser with oval down-leg snorkel. Steel Res Int 89(12):1800048
Liu C, Li S, Zhang L (2018) Simulation of gas-liquid two-phase flow and mixing phenomena during RH refining process. Acta Metall Sin 54(2):347–356
Duan H (2016) Simulation on multiphase flow and mixing phenomena during ladle metallurgy process. In: The eighth China-Korea joint symposium on advanced steel technology, Chongqing, China, pp 55–62
Duan H, Ren Y, Zhang L (2019) Fluid flow, thermal stratification, and inclusion motion during holding period in steel ladles. Metall Mater Trans B 50(3):1476–1489
Duan H, Zhang L, Thomas B, Conejo A (2018) Fluid flow, dissolution, and mixing phenomena in argon-stirred steel ladles. Metall Mater Trans B 49(5):2722–2743
Acknowledgements
The authors are grateful for support from the National Natural Science Foundation of China (Grant No. U1860206, No. 51725402, 51874031, 51874032), the S&T Program of Hebei (Grant No.20311004D), the High Steel Center (HSC) at North China University of Technology and the High Quality Steel Consortium (HQSC) at University of Science and Technology Beijing, China.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2023 The Minerals, Metals & Materials Society
About this paper
Cite this paper
Wang, J., Zhang, Y., Lyu, B., Zhang, L. (2023). Simulation on the Slag Desulfurization During the LF Refining in a Gas-Blowing Ladle. In: Wagstaff, S., Anderson, A., Sabau, A.S. (eds) Materials Processing Fundamentals 2023. TMS 2023. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-031-22657-1_11
Download citation
DOI: https://doi.org/10.1007/978-3-031-22657-1_11
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-031-22656-4
Online ISBN: 978-3-031-22657-1
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)