Abstract
Tantalum oxide (Ta2O5) thin film is considered as an alternative dielectric layer in both microelectronics and MEMS devices due to its high dielectric constant, high breakdown field and low leakage current density. In this research, radio-frequency magnetron sputtering was used to deposit Ta2O5 thin films on p-type Si (100) substrates. During the film deposition, the RF power and Ar/O2 gas flow ratio were kept constant while the sputtering pressure and substrate temperature were varied. The films were annealed in the air for an hour at 900 ℃ after the deposition. The structural, morphological, and electrical properties of the films were studied with various sputtering parameters. Orthorhombic β—phase structure of Ta2O5 films is observed from XRD investigation. The crystallinity of the films was found to be improved with the increase in the sputtering pressure and substrate temperature. The films, deposited at higher working pressure, became rough, whereas the films deposited at higher temperature became smooth. The Capacitance-voltage and current-voltage techniques were used to study the electrical properties of the thin films. Low oxide charge density of 6.5 × 1011 cm−2 and 3.1 × 1012 cm−2 observed at sputtering pressure of 8.0 × 10–3 mbar and substrate temperature of 300 ℃, respectively.
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References
Iwai, H.: Future semiconductor manufacturing: challenges and opportunities. In IEDM Technical Digest. IEEE International Electron Devices Meeting 2004, pp. 11–16. IEEE (2004)
Iwai, H.: CMOS downsizing toward sub-10 nm. Solid-State Electron. 48(4), 497–503 (2004)
Cheng, C.H., Chin, A.: Low-leakage-current DRAM-like memory using a one-transistor ferroelectric MOSFET with a Hf-based gate dielectric. IEEE electron device letters 35(1), 138–140 (2013)
Atanassova, E., Paskaleva, A.: Challenges of Ta2O5 as high-k dielectric for nanoscale DRAMs. Microelectron. Reliab. 47(6), 913–923 (2007)
Xu, W., et al.: Anomalous bias-stress-induced unstable phenomena of InZnO thin-film transistors using Ta2O5 gate dielectric. J. Phys. D Appl. Phys. 45(20), 205103 (2012)
Vinoy, K.J., Vardan, V.K.: Design of reconfigurable fractal antennas and RF-MEMS for space-based systems. IOP Smart Mater Struct 10(6), 1211–1223 (2001)
Yao, Z.J., Chen, S., Eshelman, S., Denniston, D., Goldsmith, C.: Micromachined low-loss microwave switches. IEEE J Microelectromech. Syst. 8, 129–134 (1999)
Muldavin, J.B., Rebeiz, G.M.: High-Isolation CPW MEMS switches: part 1: modeling. IEEE Trans Micro Tech 48(6), 1045–1052 (2000)
Kingon, A.I., Maria, J.P., Streiffer, S.K.: Alternative dielectrics to silicon dioxide for memory and logic devices. Nature 406, 1032–1038 (2000)
Sayan, S., Garfunkel, E., Suzer, S.: Soft x-ray photoemission studies of the HfO2/SiO2/Si system. Appl. Phys. Lett. 80(12), 2135–2137 (2002)
Intern. Techn. Roadmap for Semiconductor (ITRS) 2004 edition, http://public.itrs.net
Manchanda, L., et al.: Multi-component high-K gate dielectrics for the silicon industry. Microelectron. Eng. 59(1–4), 351–359 (2001)
Das, K.C., et al.: Evolution of microstructural and electrical properties of sputtered HfO2 ceramic thin films with RF power and substrate temperature. Ceram. Int. 42(1), 38–145 (2016)
Kar, J.P., Bose, G., Tuli, S.: Influence of rapid thermal annealing on morphological and electrical properties of RF sputtered AlN films. Mater. Sci. Semicond. Process. 8(6), 646–651 (2005)
Ezhilvalavan, S., Tseng, T.Y.: Preparation and properties of tantalum pentoxide (Ta2O5) thin films for ultra-large-scale integrated circuits (ULSIs) application–a review. J. Mater. Sci.: Mater. Electron. 10(1), 9–31 (1999)
Wibbeler, J., Pfeifer, G., Hietschold, M.: Parasitic charging of dielectric surfaces in capacitive microelectromechanical systems (MEMS). Sens. Actuators, A 71(1–2), 74–80 (1998)
Melle, S., et al.: Reliability modeling of capacitive RF MEMS. IEEE Trans. Microw. Theory Tech. 53(11), 3482–3488 (2005)
Ezhilvalavan, S., Tseng, T.Y.: Conduction mechanisms in amorphous and crystalline Ta2O5 thin films. J. Appl. Phys. 83(9), 4797–4801 (1998)
Tsai, K.C., Wu, W.F., Chao, C.G., Wu, C.C.: Improving Electrical Characteristics of Ta/Ta2O5/Ta Capacitors Using Low-Temperature Inductively Coupled N2O Plasma Annealing. J. Electrochem. Soc. 154(6), 512 (2007)
Lisec, T., Huth, C., Wagner, B.: Dielectric material impact on capacitive RF MEMS reliability. In 34th European Microwave Conference, 2004. Vol. 1, pp. 73–76. IEEE (2004)
Sahoo, A.K., Wu, G.M., Liu, C.Y., Lu, H.C.: Improved amorphous indium gallium zinc oxide thin film transistors by low power RF-sputtering deposition using Ta2O5 dielectric. Nanosci. Nanotechnol. Lett. 7(3), 193–199 (2015)
Sertel, T., Sonmez, N.A., Cetin, S.S., Ozcelik, S.: Influences of annealing temperature on anti-reflective performance of amorphous Ta2O5 thin films. Ceram. Int. 45(1), 11–18 (2019)
Perez, I., et al.: Evidence for structural transition in crystalline tantalum pentoxide films grown by RF magnetron sputtering. J. Alloy. Compd. 712, 303–310 (2017)
Kar, J.P., Bose, G., Tuli, S.: Correlation of electrical and morphological properties of sputtered aluminum nitride films with deposition temperature. Curr. Appl. Phys. 6(5), 873–876 (2006)
Das, K.C., et al.: Surface and interface studies of RF sputtered HfO2 thin films with working pressure and gas flow ratio. J. Mater. Sci.: Mater. Electron. 26(8), 6025–6031 (2015)
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Sahoo, K.K., Pradhan, D., Ghosh, S.P., Gartia, A., Kar, J.P. (2023). Investigation of Structural and Electrical Properties of Ta2O5 Thin Films with Sputtering Parameters for Microelectronic Applications. In: Pandey, A.K., Pal, P., Nagahanumaiah, Zentner, L. (eds) Microactuators, Microsensors and Micromechanisms. MAMM 2022. Mechanisms and Machine Science, vol 126. Springer, Cham. https://doi.org/10.1007/978-3-031-20353-4_30
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