Abstract
New methacrylic monomers and polymers with benzylidene fragment have been synthesized. Benzylidene-containing polymers were obtained by a three step synthetic approach. This includes the condensation, preparation of a methacrylic monomers and their polymerization. Structures of all compounds have been determined by 1H NMR and UV spectroscopy. The results of photochemical and optical activities of the corresponding polymers are presented.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Krupka O, Yu KA, Kushnir K, Blazejowski J (2005) Synthesis and Investigation of a Methacrylic Monomer Based on 4-[4-(Phthalimido)-Phenylsulphamido]-2,6-Dimethoxypyrimidine Mol. Cryst Liq Cryst 427:235–243. https://doi.org/10.1080/15421400590892316
Smokal V, Czaplicki R, Derkowska B, Krupka O, Kolendo A, Sahraoui B (2007) Synthesis and study of nonlinear optical properties of oxazolone containing polymers. Synth Met 157(18–20):708–712. https://doi.org/10.1016/j.synthmet.2007.07.006
Fritz A, Schonhals A, Sapich B, Stumpe J (1999) Dynamic and photochemical behavior of amorphous comb-like copolymers with photochromic azobenzene side groups Macromol. Chem Phys 200:2213. https://doi.org/10.1002/(SICI)1521-3935(19991001)200:10%3c2213::AID-MACP2213%3e3.0.CO;2-G
Mesaik MA, Rahat S, Khan KM, Choudhary MI, Shahnaz M, Ismaeil Z (2004) Synthesis and immunomodulatory properties of selected oxazolone derivatives Bioorg. Med Chem 12:2049–2057. https://doi.org/10.1016/j.bmc.2004.02.034
Cetenko W, Connor D, Sorenson R, Unangst P, Stabler S (1989) Preparation of (arylmethylenyl) thiazolidinones,-imidazolidinones and -oxazolidinones as anti-inflammatory agents and antiallergy agents. Eur Pat. Appl. Warner-Lambert Co., USA
Koczan G, Csik G, Csampai A, Balog E, Bosze S, Sohar P, Hudecz F (2001) Synthesis and characterization of 4-ethoxymethylene-2-naphthyl-5-oxazolone and its fluorescent amino acid derivatives. Tetrahedron 57:4589–4598. https://doi.org/10.1016/S0040-4020(01)00332-5
Icli S, Icli H, Koc H, McKillop A (1994) NMR, absorption and fluorescence parameters of azlactones. Spectrosc Lett 27:1115–1128. https://doi.org/10.1080/00387019408006969
Ullman EF, Baumann N (1970) Unsaturated lactone photochemistry. Effect of wavelength and sensitizer structure on selective population of specific excited states. J Am Chem Soc 192:5892–5899. https://doi.org/10.1021/ja00723a013
Brocklehurst K, Williamson K (1974) Electronic spectra of the isomeric 4-benzylidene-2-phenyl-Δ2-oxazolin-5-ones and the products of their reaction with nucleophiles including α-chymotrypsin: kinetics of the hydrolysis of the isomeric enzyme derivatives. Tetrahedron 30:351. https://doi.org/10.1016/S0040-4020(01)91470-X
Baumann N, Ullman EF (1968) Photosensitization of wavelength-dependent lactones. Influence of orbital symmetries on triplet energy transfer. J Am Chem Soc 90:4158–4160. https://doi.org/10.1021/ja01017a044
Rao YS (1976) Reactions in polyphosphoric acid. I. New stereospecific synthesis of the E isomers of 2-phenyl-4-arylmethylene-2-oxazolin-5-ones. J Org Chem 41:722–725. https://doi.org/10.1021/jo00866a037
Acknowledgements
This work has been supported by Ministry of Education and Science of Ukraine: Grant of the Ministry of Education and Science of Ukraine for perspective development of a scientific direction “Mathematical sciences and natural sciences” at Taras Shevchenko National University of Kyiv.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2023 The Author(s), under exclusive license to Springer Nature Switzerland AG
About this paper
Cite this paper
Smokal, V., Kharchenko, O., Kolendo, O. (2023). Synthesis and Photochemical Properties of Benzylidene-Containing Polymers. In: Fesenko, O., Yatsenko, L. (eds) Nanooptics and Photonics, Nanochemistry and Nanobiotechnology, and Their Applications . Springer Proceedings in Physics, vol 280. Springer, Cham. https://doi.org/10.1007/978-3-031-18104-7_13
Download citation
DOI: https://doi.org/10.1007/978-3-031-18104-7_13
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-031-18103-0
Online ISBN: 978-3-031-18104-7
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)