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Dielectric Behavior of Solid Polymer Electrolyte Films Formed by Double Hydrophilic Block Copolymers

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Nanomaterials and Nanocomposites, Nanostructure Surfaces, and Their Applications

Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 279))

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Abstract

Polymer electrolyte membranes (PEM) based on diblock copolymer poly(ethylene oxide)/polyacrylamide MePEO-b-PAAm (DBC), it’s partially hydrolyzed derivative MePEO-b-P(AAm-co-AAc) (DBChydr) and graft copolymer polyvinyl alcohol/polyacrylamide (PVA-g-PAAm), that form intramolecular polycomplexes, have been prepared by using solution casting technique. The ionic conductivity of PEM systems comprising mentioned copolymers in their pure form and in compositions with LiPF6 were measured at the ambient temperature and humidity. It was noticed that introduction of additional ionic groups -COOH in polyacrylamide block of DBC affected positively the conductive characteristics of the polymer membranes. The ionic conductivity of the membranes filled with LiPF6 increased with the growth of the Li-salt content. The reason for the application of DBCs and PVA-g-PAAm as possible ion-conducting membranes for Li-ion batteries, solar cells, and fuel cells are discussed.

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Authors and Affiliations

  1. Institute of Macromolecular Chemistry of the NAS of Ukraine, 48 Kharkivs’ke Shosse St, Kyiv, 02160, Ukraine

    L. Kunitskaya, T. Zheltonozhskaya, S. Nesin, Valeriy Klepko & N. Minenko

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  1. L. Kunitskaya
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  2. T. Zheltonozhskaya
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  3. S. Nesin
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  4. Valeriy Klepko
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Correspondence to L. Kunitskaya .

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Editors and Affiliations

  1. Institute of Physics, National Academy of Sciences of Ukraine, Kyiv, Ukraine

    Olena Fesenko

  2. Institute of Physics, National Academy of Sciences of Ukraine, Kyiv, Ukraine

    Leonid Yatsenko

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Kunitskaya, L., Zheltonozhskaya, T., Nesin, S., Klepko, V., Minenko, N. (2023). Dielectric Behavior of Solid Polymer Electrolyte Films Formed by Double Hydrophilic Block Copolymers. In: Fesenko, O., Yatsenko, L. (eds) Nanomaterials and Nanocomposites, Nanostructure Surfaces, and Their Applications . Springer Proceedings in Physics, vol 279. Springer, Cham. https://doi.org/10.1007/978-3-031-18096-5_28

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