Abstract
Freeze-casting is a solidification technique for fabricating scaffolds with tunable micro-scale porous structures. In this chapter, the processing principles, theories, and experimental parameters of freeze casting technique are introduced. Two selected natural bio-ceramics, namely silica-based diatomite and fish scale-extracted hydroxyapatite, are utilized as raw materials to fabricated scaffolds and composites. The intrinsic nano-porous features of diatomites are well preserved and integrated with the aligned micro-channels formed by ice dendrites during freezing. The hierarchical porous scaffolds exhibit ultra-lightweight, high porosity, superhydrophilicity and can be applied in the fields of filtration, water absorption and retention, oil–water separation, and thermal insulation. Fish scale-extracted hydroxyapatite scaffolds and composites are eco-friendly and cost-effective and can be heavy metal ion adsorption from wastewater and biomedical fields, such as bone grafting or dental materials. Future perspectives and applications of freeze casting technique are discussed.
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References
Lottermoser, A.: Über das Ausfrieren von Hydrosolen. Ber. Dtsch. Chem. Ges. 41(3), 3976–3979 (1908)
Maxwell, W., Gurnick, R., Francisco, A.: Preliminary Investigation of the ‘Freeze-Casting’ Method for Forming Refractory Powders. NACA Research Memorandum, Lewis Flight Propulsion Laboratory (1954)
Deville, S., Meille, S., Seuba, J.: A meta-analysis of the mechanical properties of ice-templated ceramics and metals. Sci. Technol. Adv. Mater. (2016)
Deville, S.: Freeze-casting of porous ceramics: a review of current achievements and issues. Adv. Eng. Mater. 10(3), 155–169 (2008)
Scotti, K.L., Dunand, D.C.: Freeze casting—a review of processing, microstructure and properties via the open data repository, FreezeCasting.net. Progr. Mater. Sci. 94, 243–305 (2018)
Zhang, H., Hussain, I., Brust, M., Butler, M.F., Rannard, S.P., Cooper, A.I.: Aligned two- and three-dimensional structures by directional freezing of polymers and nanoparticles. Nat. Mater. 4(10), 787–793 (2005)
Wegst, U.G., Schecter, M., Donius, A.E., Hunger, P.M.: Biomaterials by freeze casting. Philos. Trans. A Math. Phys. Eng. Sci. 368(1917), 2099–2121 (2010)
Lo, Y.H., Yang, C.Y., Chang, H.K., Hung, W.C., Chen, P.Y.: Bioinspired diatomite membrane with selective superwettability for oil/water separation. Sci. Rep. 7(1), 1426 (2017)
Liu, W.-K., Liaw, B.-S., Chang, H.-K., Wang, Y.-F., Chen, P.-Y.: From waste to health: synthesis of hydroxyapatite scaffolds from fish scales for lead ion removal. JOM 69(4), 713–718 (2017). https://doi.org/10.1007/s11837-017-2270-5
Liaw, B.S., Chang, T.T., Chang, H.K., Liu, W.K., Chen, P.Y.: Fish scale-extracted hydroxyapatite/chitosan composite scaffolds fabricated by freeze casting—an innovative strategy for water treatment. J. Hazard Mater. 382, 121082 (2020). https://doi.org/10.1016/j.jhazmat.2019.121082
Deville, S., Saiz, E., Tomsia, A.P.: Freeze casting of hydroxyapatite scaffolds for bone tissue engineering. Biomaterials 27(32), 5480–5489 (2006)
Jung, J.-Y., et al.: 3D printed templating of extrinsic freeze-casting for macro-microporous biomaterials. ACS Biomater. Sci. Eng. 5(5), 2122–2133 (2019). https://doi.org/10.1021/acsbiomaterials.8b01308
Mondal, S., Mahata, S., Kundu, S., Mondal, B.: Processing of natural resourced hydroxyapatite ceramics from fish scale. Adv. Appl. Ceram. 109, 234–239 (2010)
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Chen, PY., Chang, HK. (2023). Multifunctional Bio-ceramic Scaffolds and Composites Fabricated by the Freeze Casting Techniques. In: Najman, S., et al. Bioceramics, Biomimetic and Other Compatible Materials Features for Medical Applications. Engineering Materials. Springer, Cham. https://doi.org/10.1007/978-3-031-17269-4_9
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DOI: https://doi.org/10.1007/978-3-031-17269-4_9
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