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Lead Blast Furnace Dust Recycling

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Recycling Technologies for Secondary Zn-Pb Resources

Abstract

The recycling of lead (Pb), which has a limited reserve in the world, has great importance in terms of sustainable and efficient use of resources. Currently, more than half of the lead, which is the softest of base heavy metals, is recovered by recycling. In addition to the insulation of the cables and its use as a radiation shield, lead is mostly used in the manufacture of lead-acid batteries (LABs). Generally, lead smelting flue dust, also known as lead smelting fly ashes, formed during the smelting stage in secondary Pb production is fed back into the smelter. However, the impurities contained in this dust and the other required specifications for feeding into the furnace prevent dust from being fed back into the furnaces. Therefore, it is essential to evaluate these by-products with an effective process and to obtain valuable content from them. In this chapter, firstly the characterization of lead smelting flue dust has been investigated. Afterwards, the processes that can be applied to obtain contents such as Pb, Sb, Zn, and As from these materials were compiled from the literature and a comprehensive review study was presented.

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Abbreviations

EAF:

Electric arc furnace

EDTA:

Ethylenediaminetetraacetic Acid

LAB:

Lead Acid Battery

Pb:

Lead

LAB:

Lead-acid battery

S:

Sulfur

XRD:

X-Ray Diffraction

XPS:

X-Ray Photoelectron Spectroscopy

References

  • Al-dhubaibi A, Vapur H, Top S (2019) Effective processing of specularite ore by wet magnetic separation and reverse flotation techniques. Hittite J Sci Eng 6(3):201–208.https://doi.org/10.17350/HJSE19030000148

  • Altiner M, Top S, Kaymakoğlu B, Seçkin İY, Vapur H (2019) Production of precipitated calcium carbonate particles from gypsum waste using venturi tubes as a carbonation zone. J CO2 Utiliza 29:117–125. https://doi.org/10.1016/j.jcou.2018.12.004

  • Alvarez-Ayuso E, Murciego A (2021) Stabilization methods for the treatment of weathered arsenopyrite mine wastes: arsenic immobilization under selective leaching conditions. J Clean Prod 283:18

    Article  Google Scholar 

  • Battery University (2016) BU-201: How does the Lead Acid Battery Work?, http://batteryuniversity.com/ learn/article/lead_based_batteries. Accessed 05.04.21

  • Brest KK, Henock MM, Guellord N, Kimpiab M, Fabrice Kapiamba K (2021) Statistical investigation of flotation parameters for copper recovery from sulfide flotation tailings, results in engineering, Volume 9. ISSN 100207:2590–1230. https://doi.org/10.1016/j.rineng.2021.100207

    Article  CAS  Google Scholar 

  • Chen CS, Shih YJ, Huang YH (2016) Recovery of lead from smelting fly ash of waste lead-acid battery by leaching and electrowinning, waste management, Volume 52. ISSN 212–220:0956–1053. https://doi.org/10.1016/j.wasman.2016.03.056

    Article  CAS  Google Scholar 

  • CTT technical (2021) The integrated CX system. https://www.ctt-technical.com/Scrap-reprocessing.pdf. Accessed 08.04.21

  • Eatough DJ, Eatough NL, Hill MW, Mangelson NF, Ryder J, Hansen LD, Meisenheimer RG, Fischer JW (1979) The chemical composition of smelter flue dust, atmospheric environment 1967, 13(4). ISSN 489–506:0004–6981. https://doi.org/10.1016/0004-6981(79)90142-2

    Article  Google Scholar 

  • Ellis TW, Mirza AH (2010) The refining of secondary lead for use in advanced lead-acid batteries. J Power Sources 195(14):4525-4529. ISSN 0378-7753https://doi.org/10.1016/j.jpowsour.2009.12.118

  • Ettler V, Vrtišková R, Mihaljevič M, Šebek O, Grygar T, Drahota P (2009) Cadmium, lead and zinc leaching from smelter fly ash in simple organic acids—simulators of rhizospheric soil solutions. J Hazardous Mater 170(2–3):1264–1268. ISSN 0304-3894.https://doi.org/10.1016/j.jhazmat.2009.05.068

  • Ettler V, Mihaljevič M, Šebek O (2010) Antimony and arsenic leaching from secondary lead smelter air-pollution-control residues. Waste Manage Res 28(7):587–595. https://doi.org/10.1177/0734242X09335704

    Article  CAS  Google Scholar 

  • Ettler V, Mihaljevič M, Šebek O, Valigurová R, Klementová M (2012) Differences in antimony and arsenic releases from lead smelter fly ash in soils. Geochemistry 72(4):15–22. ISSN 0009-2819.https://doi.org/10.1016/j.chemer.2012.01.004

  • Gałaś A, Kot-Niewiadomska A, Czerw H, Simić V, Tost M, Wårell L, Gałaś S (2021) Impact of Covid-19 on the mining sector and raw materials security in selected European Countries. Resources 10(5):39. https://doi.org/10.3390/resources10050039

    Article  Google Scholar 

  • Görhan G, Kahraman E, Başpınar MSV, Demir İ (2008) Uçucu Kül Bölüm I: Oluşumu, Sınıflandırılması ve Kullanım Alanları. Yapı Teknolojileri Elektronik Dergisi 2:85–94

    Google Scholar 

  • Gupta C, Mukherjee T (1990) Hydrometallurgy in extraction processes, vol I. CRC Press

    Google Scholar 

  • Ichlas ZT, Rustandi RA, Mubarok MZ (2020) Selective nitric acid leaching for recycling of lead-bearing solder dross. J Clean Produc 264. ISSN 121675:0959–6526. https://doi.org/10.1016/j.jclepro.2020.121675

    Article  CAS  Google Scholar 

  • Kao MY, Petersen RA (1992) The analysis of lead sulphate of battery pastes by the thermogravimetric analysis method. J Mater Sci Lett 11:369–372. https://doi.org/10.1007/BF00729186

    Article  CAS  Google Scholar 

  • Kapp RW (2016) Arsenic: toxicology and health effects. In: Caballero B, Finglas PM, Toldrá F (eds) Encyclopedia of food and health. Academic Press, pp 256–265. ISBN 9780123849533. https://doi.org/10.1016/B978-0-12-384947-2.00043-X.

  • Kim E, Horckmans L, Spooren J, Vrancken KC, Quaghebeur M, Broos K (2017) Selective leaching of Pb, Cu, Ni and Zn from secondary lead smelting residues. Hydrometallurgy 169. ISSN 372–381:0304-386X. https://doi.org/10.1016/j.hydromet.2017.02.027

    Article  CAS  Google Scholar 

  • Klochko K (2021) Lead Information, https://pubs.usgs.gov/periodicals/mcs2021/mcs2021-lead.pdf. Accessed 05 May 2021

  • Kursunoglu S, Top S, kaya M (2020) Recovery of zinc and lead from Yahyali non-sulphide flotation tailing by sequential acidic and sodium hydroxide leaching in the presence of potassium sodium tartrate. Trans Nonferrous Metals Soc China 30(12). ISSN 3367–3378:1003–6326. https://doi.org/10.1016/S1003-6326(20)65468-1

    Article  Google Scholar 

  • Laubertova M, Piroskova J, Dociova S (2017) The technology of lead production from waste. Erzmetall 70:47–54

    Google Scholar 

  • Li W, Han J, Liu W, Jiao F, Wang H, Qin W (2021) Separation of arsenic from lead smelter ash by acid leaching combined with pressure oxidation. Separa Purification Technol 273. ISSN 118988:1383–5866. https://doi.org/10.1016/j.seppur.2021.118988

    Article  CAS  Google Scholar 

  • Lin SW, Vargas-Galarza Z, Felix-Navarro RM (2006) Optimizing the conditions for leaching lead from solid waste produced by pyrometallurgical process of recycling automobile used batteries. J Mex Chem Soc [online]. 50(2):64–70

    Google Scholar 

  • Liu W, Li Z, Han J, Li W, Wang X, Wang N, Qin W (2019) Selective separation of arsenic from lead smelter flue dust by alkaline pressure oxidative leaching. Minerals, 9, 308. https://doi.org/ https://doi.org/10.3390/min9050308.

  • Liu J, Huang S, Chen K, Li J, Wang T, Mei M (2020) Recovering metallic Pb directly from lead smelting dust by NaOH-carbon roasting process. J Mater Res Technol 9(3). ISSN 2744–2753:2238–7854. https://doi.org/10.1016/j.jmrt.2020.01.007

    Article  CAS  Google Scholar 

  • Matsunaga T, Kim JK, Hardcastle S, Rohatgi PK (2001) Crystallinity and selected properties of fly ash particles. Mater Sci Eng 325(1–2):333–343

    Google Scholar 

  • Morachevskii AG, Vaisgant ZI, Rusin AI, Khabachev MN (2001) Removal of sulfur from the active mass of lead battery scrap. Russ J Appl Chem 74:1103–1105

    Article  CAS  Google Scholar 

  • Palden T, Machiels L, Onghena B, Regadio M, Binnemans K (2020) Selective leaching of lead from lead smelter residues using EDTA. RSC Adv 10:42147

    Article  CAS  Google Scholar 

  • Palden T, Regadío M, Binnemans K (2018) Selective solvometallurgical leaching of lead and zinc from jarosite residues from the zinc industry. Proceedings of the 4th international symposium on enhanced landfill mining (ELFM IV), Mechelen (Belgium). Jones PT, Machiels L (eds), pp 133–136

    Google Scholar 

  • Prengaman RD, Mirza AH (2017) - Recycling concepts for lead–acid batteries. In: Garche J, Karden E, Moseley PT, Rand DAJ (eds) Lead-acid batteries for future automobiles. Elsevier, pp 575–598. ISBN 9780444637000, https://doi.org/10.1016/B978-0-444-63700-0.00020-9.

  • Schwitzgebel K (1981) Flue dust agglomeration in the secondary lead industry. JOM 33:38–41. https://doi.org/10.1007/BF03354399

    Article  CAS  Google Scholar 

  • Statista (2018) World refined lead production by type. https://www.statista.com/statistics/797542/refined-lead-production-worldwide-by-type/. Accessed 04 May 2021

  • Türker P, Erdoğan B, Katnaş F, Yeğinobalı A (2009) Türkiye’deki Uçucu Küllerin Sınıflandırılması Ve Özellikleri. Türkiye Çimento Müstahsilleri Birliği, Ankara, 112s

    Google Scholar 

  • Wang F, Li M, Liu Y (2019) Characteristics of lead smelting fume and its potential treatment technology. IOP conference series: earth and environmental science, Volume 384, 2019 International conference on oil & gas engineering and geological sciences, Dalian, China

    Google Scholar 

  • Wills BA, Finch J (2005) Wills’ mineral processing technology: an introduction to the practical aspects of ore treatment and mineral recovery. Butterworth-Heinemann, pp 258–342

    Google Scholar 

  • Vítková M, Ettler V, Šebek O, Mihaljevič M, Grygar T, Rohovec J (2009) The pH-dependent leaching of inorganic contaminants from secondary lead smelter fly ash. J Hazardous Mater 167(1–3). ISSN 427–433:0304–3894. https://doi.org/10.1016/j.jhazmat.2008.12.136

    Article  CAS  Google Scholar 

  • Yang X, Li H, Li C, Wang Y (2014) Recovery of valuable metals from lead flue dust by a integrated process, EPD Congress 2014. Yurko J, Zhang L, Allanore A, Wang C, Spangenberger JS, Kirchain RE, Downey JP, May LD, TMS (The Minerals, Metals & Materials Society)

    Google Scholar 

  • Zhang L, Guo X, Tian Q, Qin H (2021) Selective removal of arsenic from high arsenic dust in the NaOH-S system and leaching behaviour of lead, antimony, zinc and tin. Hydrometallurgy 202. ISSN 105607:0304-386X. https://doi.org/10.1016/j.hydromet.2021.105607

    Article  CAS  Google Scholar 

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Top, S., Altiner, M., Kurşunoğlu, S. (2023). Lead Blast Furnace Dust Recycling. In: Kaya, M. (eds) Recycling Technologies for Secondary Zn-Pb Resources. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-031-14685-5_9

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