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The Quest of Electropromoted Nano-dispersed Catalysts

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Recent Advances in Electrochemical Promotion of Catalysis

Part of the book series: Modern Aspects of Electrochemistry ((MAOE,volume 61))

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Abstract

Electrochemical promotion of catalysis (EPOC) also known as non-Faradaic electrochemical modification of catalytic activity (NEMCA) phenomenon of nano-dispersed catalytic systems has been of paramount interest since the pioneering studies of Vayenas and co-workers in the 1980s. A typical heterogeneous catalyst consists of a nano-sized active phase dispersed on high-surface-area support. This allows decreasing the noble metal catalyst loading while considerably increasing the number of surface-active sites available for the reaction. In EPOC studies the catalyst-working electrode is often fabricated as a continuous, porous film with low dispersion; however, more and more works on the fabrication and study of EPOC with nanostructured, dispersed catalysts have emerged recently. This chapter presents a review of EPOC studies with nano-sized, electropromoted catalytic systems reported in the last decade. The first section discusses the origin of EPOC, the main parameters, and the rules. The second part provides the observation of the EPOC effect for both noble and non-noble nanoparticle catalysts. The third part examines recent advances in density functional theory (DFT) for the understanding of electrified interfaces in catalysis, followed by recent advances in self-sustained EPOC. Finally, the last section highlights the research gaps in understanding and applying electrochemically promoted nanostructured catalysts to technologically important processes.

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Abbreviations

ALD:

Atomic layer deposition

BZY:

BaZr0.85Y0.15O3-α

DFT :

Density functional theory

DLC:

Diamond-like carbon

EDX:

Energy-dispersive X-ray

EMF:

Electromotive force

EPOC :

Electrochemical promotion of catalysis

GO:

Graphene oxide

LSCF/GDC:

La0.6Sr0.4Co0.2Fe0.8O3-δ/Ce0.9Gd0.1O1.95

LSM/GDC:

(La0.8Sr0.2)0.95 MnO3-δ/Ce0.9Gd0.1O1.95

MIEC :

Mixed ionic-electronic conductive

MSI:

Metal-support interaction

NAS-XPS:

Near-ambient pressure X-ray photoelectron spectroscopy

NEMCA:

Non-Faradaic electrochemical modification of catalytic activity

NPs:

Nanoparticles

P-EPOC:

Permanent or persistent electrochemical promotion of catalysis

PM-IRRAS:

Polarization modulation infrared reflection absorption spectroscopy

PVD:

Physical vapor deposition

PVP:

Polyvinylpyrrolidone

RHE:

Reversible hydrogen electrode

RWGS:

Reverse water-gas shift

SHE:

Standard hydrogen electrode

SMSI:

Strong metal-support interaction

SRM:

Steam reforming of methanol

SSEP :

Self-sustained electrochemical promotion

SS-EPOC :

Self-sustained electrochemical promotion of catalysis

TGA:

Thermogravimetric analysis

TMAOH:

Tetramethylammonium hydroxide

TOF :

Turnover frequency

tpb:

Three-phase boundary

TPD:

Temperature program desorption

VOCs :

Volatile organic compounds

WGS:

Water-gas shift

XAS:

X-ray absorption spectroscopy

YSZ :

Yttria-stabilized zirconia

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  1. Department of Chemical and Biological Engineering, Centre for Catalysis Research and Innovation (CCRI), University of Ottawa, Ottawa, ON, Canada

    Arash Fellah Jahromi, Christopher Panaritis & Elena A. Baranova

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  1. Arash Fellah Jahromi
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  2. Christopher Panaritis
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  1. Université de Lyon, Institut de Recherches sur la Catalyse et l’Environnement de Lyon, UMR 5256, CNRS, Université Claude Bernard Lyon 1, Villeurbanne, France

    Philippe Vernoux

  2. Department of Chemical Engineering, University of Patras, Patras, Greece

    Constantinos G. Vayenas

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Fellah Jahromi, A., Panaritis, C., Baranova, E.A. (2023). The Quest of Electropromoted Nano-dispersed Catalysts. In: Vernoux, P., Vayenas, C.G. (eds) Recent Advances in Electrochemical Promotion of Catalysis. Modern Aspects of Electrochemistry, vol 61. Springer, Cham. https://doi.org/10.1007/978-3-031-13893-5_3

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