Abstract
An analytical study of the results of physical and chemical modeling of natural objects of various hydrogeochemical provinces was performed. The HCh software package was used for modeling (Shvarov Yu.V., MSU). V. I. Vernadsky’s position on the diversity of chemical types of natural waters in the Earth’s crust is substantiated. The main components of the “water–rock–gases” system transformation are identified. The high convergence of numerical thermodynamic models based on the fundamental laws of physical chemistry with direct analytical studies is shown. From a detailed analysis of the step-by-step phase changes hydrogeochemical system on the background of the four main factors that determine the chemical composition of natural waters, it was found that the leading parameter of the diversity of waters at the regional scale is the rate of water exchange (the model parameter is the mass ratio of rock/water), canvas serves as the mineral composition of water-bearing rocks.
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Limantseva, O.A., Ryzhenko, B.N., Shvarov, Y.V. (2023). Influence of Water Exchange on the Equilibrium Composition of Aqueous Phase and Mineral Association. In: Kolotov, V.P., Bezaeva, N.S. (eds) Advances in Geochemistry, Analytical Chemistry, and Planetary Sciences. Springer, Cham. https://doi.org/10.1007/978-3-031-09883-3_9
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