Abstract
This chapter deals with how concentrations and compositions are expressed in food systems, including the composition of gaseous mixtures, especially air-water vapor mixtures and the solubility of gases such as carbon dioxide in food and biological systems. It also introduces the principles of mass and thermal energy conservation in food processing and illustrates the application of these principles to individual processing equipment as well as to overall flowsheets with and without recycle streams. The chapter covers stoichiometry of chemical reactions as well as biochemical reactions involving whole cells and cell growth. It also introduces heat or enthalpy of reactions and the nature of exothermic and endothermic reactions.
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References
Niranjan K (1994) Chemical engineering principles and food processing. Trends Food Sci Technol 5:20–23
Bibliography for Further Reading
Yanniotis S (2007) Solving problems in food engineering. Springer, pp 11–32
Doran PM (2012) Bioprocess engineering principles, 2nd edn. Elsevier, pp 87–176
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Appendix 1.1: Properties of Saturated Steam (Data Taken From https://www.ohio.edu/mechanical/thermo/property_tables/H2O/H2O_TempSat1.html; and www.efunda.com); Subscripts f -Liquid Phase, g – Vapour Phase and fg – Phase Change
Appendix 1.1: Properties of Saturated Steam (Data Taken From https://www.ohio.edu/mechanical/thermo/property_tables/H2O/H2O_TempSat1.html; and www.efunda.com); Subscripts f -Liquid Phase, g – Vapour Phase and fg – Phase Change
Temp (°C) | Pressure (MPa) | Specific Volume (m3 kg−1) | Enthalpy (kJ kg−1) | Entropy (kJ kg−1.K−1) | |||||
---|---|---|---|---|---|---|---|---|---|
Tsat | Psat | vf | vg | hf | hfg | hg | Sf | sfg | sg |
0.01 | 0.00061 | 0.00100 | 205.99 | 0.001 | 2500.9 | 2500.9 | 0 | 9.1555 | 9.1555 |
5 | 0.00087 | 0.00100 | 147.01 | 21.0 | 2489.1 | 2510.1 | 0.0763 | 8.9485 | 9.0248 |
10 | 0.00123 | 0.00100 | 106.30 | 42.0 | 2477.2 | 2519.2 | 0.1511 | 8.7487 | 8.8998 |
15 | 0.00171 | 0.00100 | 77.875 | 63.0 | 2465.3 | 2528.3 | 0.2245 | 8.5558 | 8.7803 |
20 | 0.00234 | 0.00100 | 57.757 | 83.9 | 2453.5 | 2537.4 | 0.2965 | 8.3695 | 8.6660 |
25 | 0.00317 | 0.00100 | 43.337 | 104.8 | 2441.7 | 2546.5 | 0.3672 | 8.1894 | 8.5566 |
30 | 0.00425 | 0.00100 | 32.878 | 125.7 | 2429.8 | 2555.5 | 0.4368 | 8.0152 | 8.4520 |
35 | 0.00563 | 0.00101 | 25.205 | 146.6 | 2417.9 | 2564.5 | 0.5051 | 7.8466 | 8.3517 |
40 | 0.00739 | 0.00101 | 19.515 | 167.5 | 2406.0 | 2573.5 | 0.5724 | 7.6831 | 8.2555 |
45 | 0.00960 | 0.00101 | 15.252 | 188.4 | 2394.0 | 2582.4 | 0.6386 | 7.5247 | 8.1633 |
50 | 0.01235 | 0.00101 | 12.027 | 209.3 | 2382.0 | 2591.3 | 0.7038 | 7.3710 | 8.0748 |
55 | 0.01576 | 0.00102 | 9.5643 | 230.3 | 2369.8 | 2600.1 | 0.7680 | 7.2218 | 7.9898 |
60 | 0.01995 | 0.00102 | 7.6672 | 251.2 | 2357.6 | 2608.8 | 0.8313 | 7.0768 | 7.9081 |
65 | 0.02504 | 0.00102 | 6.1935 | 272.1 | 2345.4 | 2617.5 | 0.8937 | 6.9359 | 7.8296 |
70 | 0.03120 | 0.00102 | 5.0395 | 293.2 | 2333.0 | 2626.1 | 0.9551 | 6.7989 | 7.7540 |
75 | 0.03860 | 0.00103 | 4.1289 | 314.0 | 2320.6 | 2634.6 | 1.0158 | 6.6654 | 7.6812 |
80 | 0.04741 | 0.00103 | 3.4052 | 335.0 | 2308.0 | 2643.0 | 1.0756 | 6.5355 | 7.6111 |
85 | 0.05787 | 0.00103 | 2.8258 | 356.0 | 2295.3 | 2651.3 | 1.1346 | 6.4088 | 7.5434 |
90 | 0.07018 | 0.00104 | 2.3591 | 377.0 | 2282.5 | 2659.5 | 1.1929 | 6.2852 | 7.4781 |
95 | 0.08461 | 0.00104 | 1.9806 | 398.1 | 2269.5 | 2667.6 | 1.2504 | 6.1647 | 7.4151 |
100 | 0.10142 | 0.00104 | 1.6718 | 419.2 | 2256.4 | 2675.6 | 1.3072 | 6.0469 | 7.3541 |
110 | 0.14338 | 0.00105 | 1.2093 | 461.4 | 2229.7 | 2691.1 | 1.4188 | 5.8193 | 7.2381 |
120 | 0.19867 | 0.00106 | 0.8912 | 503.8 | 2202.1 | 2705.9 | 1.5279 | 5.6012 | 7.1291 |
130 | 0.27028 | 0.00107 | 0.66800 | 546.4 | 2173.7 | 2720.1 | 1.6346 | 5.3918 | 7.0264 |
140 | 0.36154 | 0.00108 | 0.50845 | 589.2 | 2144.2 | 2733.4 | 1.7392 | 5.1901 | 6.9293 |
150 | 0.47616 | 0.00109 | 0.39245 | 632.2 | 2113.7 | 2745.9 | 1.8418 | 4.9953 | 6.8371 |
160 | 0.61823 | 0.00110 | 0.30678 | 675.47 | 2082.0 | 2757.4 | 1.9426 | 4.8026 | 6.7491 |
170 | 0.79219 | 0.00111 | 0.24259 | 719.08 | 2048.8 | 2767.9 | 2.0417 | 4.6233 | 6.6650 |
180 | 1.0028 | 0.00112 | 0.19384 | 763.05 | 2014.2 | 2777.2 | 2.1392 | 4.4448 | 6.5840 |
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Niranjan, K. (2022). Mass and Energy Balances. In: Engineering Principles for Food Process and Product Realization. Food Engineering Series. Springer, Cham. https://doi.org/10.1007/978-3-031-07570-4_1
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