Abstract
Hazardous contaminating impurities/toxins, such as poisonous metal particles and colors/dyes, are a significant reason for the toxicity of water bodies. These contaminations make an unfriendly impact on sea organisms and immobilize the compounds in plant life. Subsequently, this issue should be moderated as a disturbing natural danger leading to different unsafe sicknesses in humans. Moreover, several waterborne pathogenic microorganisms likewise cause irresistible infections. Numerous techniques are reportedly established to eliminate these toxins and undesirable microorganisms. Adsorptive treatment and/or exclusion of water toxins and microbial sanitization through different nanocellulose (NC)-graphene oxide (GO) nanocomposite (NGON) materials (adsorbents) are introduced in this chapter. As per available literature, these adsorbent materials have shown extraordinary outcomes for the adsorptive exclusion of water contaminants such as poisonous metal ions and colors/dyes along with the removal of aquatic germs, insecticides, etc. Besides, they have numerous other necessities, including ease of preparation, cheap, and eco-friendly, as green composite blends are handily worked, energy-economical, and fit for multifaceted uses. This chapter also focuses on discussing the technologies embraced to fabricate the aforementioned adsorbents, their performance-based response with regards to adsorption capacity (Q). Our article also presents an ephemeral summary of adsorption working principles like isotherms, adsorption affecting parameters, the kinetics, along with the thermodynamics of the adsorption phenomenon. Furthermore, it reconnoiters the current applications, issues of consideration, related to these NGON adsorbents along with future perspectives.
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References
S. Afroze, T.K. Sen, A review on heavy metal ions and dye adsorption from water by agricultural solid waste adsorbents. Water Air Soil Pollut. 229, 1–50 (2018)
T.S. Anirudhan, J.R. Deepa, Nano-zinc oxide incorporated graphene oxide/nanocellulose composite for the adsorption and photo catalytic degradation of ciprofloxacin hydrochloride from aqueous solutions. J. Colloid Interface Sci. 490, 343–356 (2017)
N.I.F. Aris, N.A. Rahman, M.H. Wahid et al., Superhydrophilic graphene oxide/electrospun cellulose nanofibre for efficient adsorption of organophosphorus pesticides from environmental samples. R. Soc. Open Sci. 7, 192050 (2020)
U. Baig, M. Faizan, M. Sajid, Effective removal of hazardous pollutants from water and deactivation of water-borne pathogens using multifunctional synthetic adsorbent materials: a review. J. Clean Prod. 126735 (2021)
A. Bhattacharyya, B. Banerjee, S. Ghorai et al., Development of an auto-phase separable and reusable graphene oxide-potato starch based cross-linked bio-composite adsorbent for removal of methylene blue dye. Int. J. Biol. Macromol. 116, 1037–1048 (2018)
A. Bhattacharyya, S. Ghorai, D. Rana et al., Design of an efficient and selective adsorbent of cationic dye through activated carbon - graphene oxide nanocomposite: study on mechanism and synergy. Mater. Chem. Phys. 260 (2021)
A. Bhattacharyya, D. Mondal, I. Roy et al., Studies of the kinetics and mechanism of the removal process of proflavine dye through adsorption by graphene oxide. J. Mol. Liq. 230, 696–704 (2017)
B.C. Brodie, On the atomic weight of graphite. Philos. Trans. R. Soc. Lond. 149, 249–259 (1859)
J. Chen, H. Li, L. Zhang et al., Direct reduction of graphene oxide/nanofibrillated cellulose composite film and its electrical conductivity research. Sci. Rep. 10, 3124 (2020)
L. Chen, Y. Li, S. Hu et al., Removal of methylene blue from water by cellulose/graphene oxide fibres. J. Exp. Nanosci. 11, 1156–1170 (2016)
X. Chen, S. Zhou, L. Zhang et al., Adsorption of heavy metals by graphene oxide/cellulose hydrogel prepared from NaOH/urea aqueous solution. Materials (Basel) 9 (2016)
Y. Chen, Synthesis and characterization of novel functional materials based on cellulose and graphene oxide (2020)
E. Chibowski, A. Szczes, Magnetic water treatment-a review of the latest approaches. Chemosphere 203, 54–67 (2018)
A. Chiori, Urban water planning in Lagos, Nigeria: an analysis of current infrastructure developments and future water management solutions (2018)
P. Dhar, B. Pratto, A.J. Gonçalves Cruz et al. Valorization of sugarcane straw to produce highly conductive bacterial cellulose/graphene nanocomposite films through in situ fermentation: kinetic analysis and property evaluation. J. Clean Prod. 238 (2019)
A.M. Dimiev, L.B. Alemany, J.M. Tour, Graphene oxide. Origin of acidity, its instability in water, and a new dynamic structural model. ACS Nano 7, 576–588 (2012)
K. Dutta, B. Das, J.T. Orasugh et al., Bio-derived cellulose nanofibril reinforced poly(N-isopropylacrylamide)-g-guar gum nanocomposite: an avant-garde biomaterial as a transdermal membrane. Polymer 135, 85–102 (2018)
W. Gao, L.B. Alemany, L. Ci, P.M. Ajayan, New insights into the structure and reduction of graphite oxide. Nat. Chem. 1, 403–408 (2009)
H. Gu, C. Gao, X. Zhou et al., Nanocellulose nanocomposite aerogel towards efficient oil and organic solvent adsorption. Adv. Compos. Hybrid Mater. 1–10 (2021)
Y. Hui, W. Xie, H. Gu, Reduced Graphene oxide/nanocellulose/amino-multiwalled carbon nanotubes nanocomposite aerogel for excellent oil adsorption. ES Food Agrofor. (2021)
W.S. Hummers, R.E. Offeman, Preparation of graphitic oxide. J. Am. Chem. Soc. 80, 1339 (1958)
A. Hussain, J. Li, J. Wang et al., Hybrid monolith of graphene/TEMPO-oxidized cellulose nanofiber as mechanically robust, highly functional, and recyclable adsorbent of methylene blue dye. J. Nanomater. (2018)
W.B. Jensen, Vignettes in the history of chemistry. 1. What is the origin of the Gibbs–Helmholtz equation? ChemTexts 2 1 (2016)
W. Jei, S.-H. Gui, J.-H. Wu, D.-D. Xu, Y. Sun, X.-Y. Dong, Y.-Y. Dai, Y.-F. Li, Nanocellulose-graphene oxide hybrid aerogel towards water purification. Appl. Environ. Biotechnol. 4 (2019)
N.A.V Jitendra, Synthesis, characterization and preparation of nanocellulose and different cellulose/nanocellulose/graphene composites from cassava root and its potential application for pesticide adsorption from water. Int. J. Res. Anal. Rev. (IJRAR) 5 (2018)
R. Kant, Textile dyeing industry an environmental hazard. J. Nat. Sci. 4(1), 22–26 (2012)
P. Kotcharat, P. Chuysinuan, T. Thanyacharoen et al., Development of bacterial cellulose and polycaprolactone (PCL) based composite for medical material. Sustain. Chem. Pharm. 20 (2021)
A.H. Lerf, H. He, M. Forster, J. Klinowski, Structure of graphite oxide revisited. J. Phys. Chem. B 102, 4477–4482 (1998)
P. Li, X. Yang, H. Miao et al., Simultaneous determination of 19 triazine pesticides and degradation products in processed cereal samples from Chinese total diet study by isotope dilution–high performance liquid chromatography–linear ion trap mass spectrometry. Anal. Chim. Acta 781, 63–71 (2013)
W. Li, L. Zhang, D. Hu et al., A mesoporous nanocellulose/sodium alginate/carboxymethyl-chitosan gel beads for efficient adsorption of Cu(2+) and Pb(2). Int. J. Biol. Macromol. 187, 922–930 (2021)
D. Liao, Y. Guan, Y. He et al., Pickering emulsion strategy for high compressive carbon aerogel as lightweight electromagnetic interference shielding material and flexible pressure sensor. Ceram. Int. 47, 23433–23443 (2021)
J. Liu, S. Wang, L. Jiang et al., Production and characterization of antimicrobial bacterial cellulose membranes with non-leaching activity. J. Ind. Eng. Chem. 103, 232–238 (2021)
P. Liu, C. Zhu, A.P. Mathew, Mechanically robust high flux graphene oxide - nanocellulose membranes for dye removal from water. J. Hazard. Mater. 371, 484–493 (2019)
W. Logrono, M. Perez, G. Urquizo et al., Single chamber microbial fuel cell (SCMFC) with a cathodic microalgal biofilm: A preliminary assessment of the generation of bioelectricity and biodegradation of real dye textile wastewater. Chemosphere 176, 378–388 (2017)
H. Luo, J. Xie, J. Wang et al., Step-by-step self-assembly of 2D few-layer reduced graphene oxide into 3D architecture of bacterial cellulose for a robust, ultralight, and recyclable all-carbon absorbent. Carbon 139, 824–832 (2018)
X. Luo, L. Liu, L. Wang et al., Facile synthesis and low concentration tylosin adsorption performance of chitosan/cellulose nanocomposite microspheres. Carbohyd. Polym. 206, 633–640 (2019)
X. Luo, L. Liu, L. Wang et al., Facile synthesis and low concentration tylosin adsorption performance of chitosan/cellulose nanocomposite microspheres. Carbohydr. Polym. 206, 633–640 (2019)
C.R. Minitha, K. Rajavel, R.T. Rajendra Kumar, Magnetite decorated reduced graphene oxide: a study of multifunctional antibacterial and removal of lead ion properties for water disinfection applications. Adv. Eng. Mater. 22 (2020)
Y. Nakajima TaM, Formation process and structure of graphite oxide. Carbon 32, 469–475 (1994)
J.T. Orasugh, S. Dutta, D. Das et al., Sustained release of ketorolac tromethamine from poloxamer 407/cellulose nanofibrils graft nanocollagen based ophthalmic formulations. Int. J. Biol. Macromol. 140, 441–453 (2019)
J.T. Orasugh, S.K. Ghosh, D. Chattopadhyay, Nanofiber-reinforced biocomposites, in Fiber-Reinforced Nanocomposites: Fundamentals and Applications (2020), pp. 199–233
J.T. Orasugh, N.R. Saha, D. Rana et al., Jute cellulose nano-fibrils/hydroxypropylmethylcellulose nanocomposite: A novel material with potential for application in packaging and transdermal drug delivery system. Ind. Crops Prod. 112, 633–643 (2018)
J.T. Orasugh, N.R. Saha, G. Sarkar et al., Synthesis of methylcellulose/cellulose nano-crystals nanocomposites: material properties and study of sustained release of ketorolac tromethamine. Carbohydr. Polym. 188, 168–180 (2018)
J.T. Orasugh, N.R. Saha, G. Sarkar et al., A facile comparative approach towards utilization of waste cotton lint for the synthesis of nano-crystalline cellulose crystals along with acid recovery. Int. J. Biol. Macromol. 109, 1246–1252 (2018)
J.T. Orasugh, G. Sarkar, N.R. Saha et al., Effect of cellulose nanocrystals on the performance of drug loaded in situ gelling thermo-responsive ophthalmic formulations. Int. J. Biol. Macromol. 124, 235–245 (2019)
K. Ozge, C. Hande, Chitosan/graphene oxide/nanocellulose composites for removal of Cu(II) and Pb(II) Ions in aqueous solution. Polym. Sci. Ser. A (2021)
P. Pandey, P. Kass, M. Soupir et al., Analysis and application of Bacillus subtilis sortases to anchor recombinant proteins on the cell wall. AMB Expr. 4, 1–16 (2014)
A. Payen, Mémoire sur les Applications Théoriques et Pratiques des Propriétés du Tissu Élémentaire des Végétaux. Compt. Rendus 8, 59–61 (1839)
S.C. Pinto, G. Goncalves, S. Sandoval et al., Bacterial cellulose/graphene oxide aerogels with enhanced dimensional and thermal stability. Carbohydr. Polym. 230 115598 (2020)
Y. Qin, S. Li, Y. Li et al., Mechanically robust polybenzoxazine/reduced graphene oxide wrapped-cellulose sponge towards highly efficient oil/water separation, and solar-driven for cleaning up crude oil. Compos. Sci. Technol. 197 (2020)
A. Radhakrishnan, J. Nahi, B. Beena, Synthesis and characterization of multi-carboxyl functionalized nanocellulose/graphene oxide-zinc oxide composite for the adsorption of uranium (VI) from aqueous solutions: Kinetic and equilibrium profiles. Mater. Today: Proc. 41, 557–563 (2021)
S.S. Ray, A.O.C. Iroegbu, Nanocellulosics: benign, sustainable, and ubiquitous biomaterials for water remediation. ACS Omega 6, 4511–4526 (2021)
E. Rosenberg, Heavy metals in water: presence, removal and safety. Johns. Matthey Technol. Rev. 59, 293–297 (2015)
G. Ruess, Über das graphitoxyhydroxyd (graphitoxyd). Monatshefte für Chemie 76, 381–417 (1746)
S. Sadhukhan, A. Bhattacharyya, D. Rana et al., Synthesis of RGO/NiO nanocomposites adopting a green approach and its photocatalytic and antibacterial properties. Mater. Chem. Phys. 247, 122906 (2020)
G. Sarkar, J.T. Orasugh, N.R. Saha et al., Cellulose nanofibrils/chitosan based transdermal drug delivery vehicle for controlled release of ketorolac tromethamine. New J. Chem. 41, 15312–15319 (2017)
L. Saya, D. Gautam, V. Malik et al., Natural polysaccharide based graphene oxide nanocomposites for removal of dyes from wastewater: a review. J. Chem. Eng. Data 66, 11–37 (2020)
W. Scholz, H.P. Boehm, Untersuchungen am graphitoxid. VI. Betrachtungen zur struktur des graphitoxids. Z. Anorg. Allg. Chem. 369, 327–340 (1969)
P.R. Sharma, S.K. Sharma, T. Lindström et al., Nanocellulose‐enabled membranes for water purification: perspectives. Adv. Sustain. Syst. 4 (2020)
R. Sreenivasan, S. Suma Mahesh, V.S. Sumi, Synthesis and application of polymer-grafted nanocellulose/graphene oxide nano composite for the selective recovery of radionuclides from aqueous media. Sep. Sci. Technol. 54, 1453–1468 (2018)
L. Staudenmaier, Verfahren zur darstellung der graphitsaure. Berichte Der Deutschen Chemischen Gesellschaft (A and B Series) 31, 1481–1487 (1898)
F. Suo, G. Xie, J. Zhang et al., A carbonised sieve-like corn straw cellulose–graphene oxide composite for organophosphorus pesticide removal. RSC Adv. 8, 7735–7743 (2018)
T. Szabó, O. Berkesi, P. Forgó, K. Josepovits, Y. Sanakis, D. Petridis, I. Dékány, Evolution of surface functional groups in a series of progressively oxidized graphite oxides. Chem. Mater. 18, 2740–2749 (2006)
J. Tao, J. Yang, C. Ma et al., Cellulose nanocrystals/graphene oxide composite for the adsorption and removal of levofloxacin hydrochloride antibiotic from aqueous solution. R. Soc. Open Sci. 7, 200857 (2020)
P. Tchounwou, C. Yedjou, A. Patlolla et al., Heavy metal toxicity and the environment in Molecular, clinical and environmental toxicology, ed. by A. Luch, vol. 101 (Springer, Berlin, 2012), pp. 133–164
J. Tersur Orasugh, S. Dutta, D. Das et al., Utilization of cellulose nanocrystals (CNC) biopolymer nanocomposites in ophthalmic drug delivery system (ODDS). J. Nanotechnol. Res. 01 (2019)
D. Trache, V.K. Thakur, R. Boukherroub, Cellulose nanocrystals/graphene hybrids-a promising new class of materials for advanced applications. Nanomaterials (Basel) 10 (2020)
A. Tshikovhi, S.B. Mishra, A.K. Mishra, Nanocellulose-based composites for the removal of contaminants from wastewater. Int. J. Biol. Macromol. 152, 616–632 (2020)
Ulrich Hofmann uRH Uber die Saurenatur und die Methylierung von Graphitoxyd. Berichte Der Deutschen Chemischen Gesellschaft (A and B Series) 72, 754–771
L. Valencia, S. Monti, S. Kumar et al., Nanocellulose/graphene oxide layered membranes: elucidating their behaviour during filtration of water and metal ions in real time. Nanoscale 11, 22413–22422 (2019)
Y.-J. Wan, P.-L. Zhu, S.-H. Yu et al., Ultralight, super-elastic and volume-preserving cellulose fiber/graphene aerogel for high-performance electromagnetic interference shielding. Carbon 115, 629–639 (2017)
J. Wang, X. Li, L. Tang et al., Synthesis approaches to magnetic graphene oxide and its application in water treatment: a review. Water Air Soil Pollut. 232 (2021)
Y. Wang, S. Yadav, T. Heinlein et al., Ultra-light nanocomposite aerogels of bacterial cellulose and reduced graphene oxide for specific absorption and separation of organic liquids. RSC Adv. 4 (2014)
Z. Wang, L. Song, Y. Wang et al., Construction of a hybrid graphene oxide/nanofibrillated cellulose aerogel used for the efficient removal of methylene blue and tetracycline. J. Phys. Chem. Solids 150 (2021)
P. Wexler, Encyclopedia of Toxicology (Elsevier/Academic Press, 2014)
Y. Wu, T.Y. Huang, Z.X. Li et al., In-situ fermentation with gellan gum adding to produce bacterial cellulose from traditional Chinese medicinal herb residues hydrolysate. Carbohydr. Polym. 270, 118350 (2021)
C. Xiang, C. Wang, R. Guo et al., Synthesis of carboxymethyl cellulose-reduced graphene oxide aerogel for efficient removal of organic liquids and dyes. J. Mater. Sci. 54, 1872–1883 (2018)
A. Yang, J. Wu, C.P. Huang, Graphene oxide-cellulose composite for the adsorption of uranium(VI) from dilute aqueous solutions. J. Hazard. Toxic Radioact. Waste 22 (2018)
J. Yang , C. Ma, J. Tao et al., Optimization of polyvinylamine-modified nanocellulose for chlorpyrifos adsorption by central composite design. Carbohydr. Polym. 245, 116542 (2020)
M. Yao, Z. Wang, Y. Liu et al., Preparation of dialdehyde cellulose graftead graphene oxide composite and its adsorption behavior for heavy metals from aqueous solution. Carbohydr. Polym. 212, 345–351 (2019)
Q. Yao, B. Fan, Y. Xiong et al., 3D assembly based on 2D structure of cellulose nanofibril/graphene oxide hybrid aerogel for adsorptive removal of antibiotics in water. Sci. Rep. 7, 45914 (2017)
H. Yu, S. Zhang, Y. Wang et al., Covalent modification of Nanocellulose (NCC) by functionalized Graphene oxide (GO) and the study of adsorption mechanism. Compos. Interfaces 28, 145–158 (2020)
S. Yu, D. Wei, L. Shi et al., Three-dimensional graphene/titanium dioxide composite for enhanced U (VI) capture: insights from batch experiments, XPS spectroscopy and DFT calculation. Environ. Pollut. 251, 975–983 (2019)
A. Zaman, J.T. Orasugh, P. Banerjee et al., Facile one-pot in-situ synthesis of novel graphene oxide-cellulose nanocomposite for enhanced azo dye adsorption at optimized conditions. Carbohydr. Polym. 246, 116661 (2020)
C. Zhang, R.Z. Zhang, Y.Q. Ma et al., Preparation of cellulose/graphene composite and its applications for triazine pesticides adsorption from water. ACS Sustain. Chem. Eng. 3, 396–405 (2015)
M. Zhao, S. Zhang, G. Fang et al., Directionally-grown carboxymethyl cellulose/reduced graphene oxide aerogel with excellent structure stability and adsorption capacity. Polymers (Basel) 12 (2020)
A.L.T. Zheng, S. Sabidi, T. Ohno et al., Cu2O/TiO2 decorated on cellulose nanofiber/reduced graphene hydrogel for enhanced photocatalytic activity and its antibacterial applications. Chemosphere 286, 131731 (2021)
X. Zhou, Q. Fu, H. Liu et al., Solvent-free nanoalumina loaded nanocellulose aerogel for efficient oil and organic solvent adsorption. J. Colloid Interface Sci. 581, 299–306 (2021)
C. Zhu, P. Liu, A.P. Mathew, Self-assembled TEMPO cellulose nanofibers: graphene oxide-based biohybrids for water purification. ACS Appl. Mater. Interfaces 9, 21048–21058 (2017)
C. Zhu, S. Monti, A.P. Mathew, Cellulose nanofiber-graphene oxide biohybrids: disclosing the self-assembly and copper-ion adsorption using advanced microscopy and reaxff simulations. ACS Nano 12, 7028–7038 (2018)
A. Ishikawa, T. Okano, J. Sugiyama, Fine structure and tensile properties of ramie fibres in the crystalline form of cellulose I, II, IIII and IVI. Polymer 38(2), 463–468 (1997). https://doi.org/10.1016/S0032-3861(96)00516-2
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The authors wish to acknowledge the Department of Chemical Sciences, University of Johannesburg, Doorfontein, Johannesburg 2028, South Africa, and DST-CSIR National Centre for Nanostructured Materials, Council for Scientific and Industrial Research, Pretoria 0001, South Africa.
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Orasugh, J.T., Ray, S.S. (2022). Nanocellulose-Graphene Oxide-Based Nanocomposite for Adsorptive Water Treatment. In: Hato, M.J., Sinha Ray, S. (eds) Functional Polymer Nanocomposites for Wastewater Treatment. Springer Series in Materials Science, vol 323. Springer, Cham. https://doi.org/10.1007/978-3-030-94995-2_1
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