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Fundamental Spectroscopic Studies

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Luminescent Materials

Part of the book series: Springer Series in Materials Science ((SSMATERIALS,volume 322))

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Abstract

The excited manifolds of luminescent materials activated with lanthanide ions and their associated spectroscopies range in complexity from the simplest case of Ce\(^{3+}\)-doped materials, where only one unpaired electron plays the relevant roles, to the much more complex case of Eu\(^{2+}\)-doped materials, where many electrons are active in the open-shells and create a variety of problems and opportunities. In this Chapter, a multiconfigurational ab initio approach to fundamental spectroscopic studies of materials with different levels of complexity is discussed.

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Notes

  1. 1.

    For the sake of simplicity, the notation that corresponds to the cubic \(O_h\) site of Eu\(^{2+}\) in the difluorides will be used in this discussion. For the octahedral \(O_h\) site of Eu\(^{2+}\) in the sulfides, everything holds, except that 5\(de_{g}\) and 5\(dt_{2g}\) must be interchanged.

References

  1. P.A. Tanner, C.S.K. Mak, N.M. Edelstein, K.M. Murdoch, G. Liu, J. Huang, L. Seijo, Z. Barandiarán, J. Am. Chem. Soc. 125, 13225 (2003)

    Article  CAS  Google Scholar 

  2. R.W. Schwartz, Mol. Phys. 30, 81 (1975)

    Article  CAS  Google Scholar 

  3. A. Bessière, P. Dorenbos, C. van Eijk, L. Pidol, K. Krämer, H. Güdel, J. Phys.: Condens. Matter 16, 1887 (2004)

    Google Scholar 

  4. J. Wen, L. Ning, C.K. Duan, Y. Chen, Y. Zhang, M. Yin, J. Phys. Chem. C 116, 20513 (2012)

    Article  CAS  Google Scholar 

  5. L. Ning, F. Yang, C. Duan, Y. Zhang, J. Liang, Z. Cui, J. Phys.: Condens. Matter 24, 05502 (2012)

    Google Scholar 

  6. J. Gracia, L. Seijo, Z. Barandiarán, D. Curulla, H. Niemansverdriet, W. van Gennip, J. Lumin. 128, 1248 (2008)

    Article  CAS  Google Scholar 

  7. L. Ning, C. Wu, L. Li, L. Lin, C. Duan, Y. Zhang, L. Seijo, J. Phys. Chem. C 116, 18419 (2012)

    Article  CAS  Google Scholar 

  8. L. Seijo, Z. Barandiarán, J. Chem. Phys. 141, 214706/1 (2014)

    Google Scholar 

  9. L. van Pieterson, M.F. Reid, R.T. Wegh, S. Soverna, A. Meijerink, Phys. Rev. B 65, 045113 (2002)

    Google Scholar 

  10. E. Loh, Phys. Rev. 158, 273 (1967)

    Article  CAS  Google Scholar 

  11. T. Szczurek, M. Schlesinger, in Rare Earth Spectroscopy. ed. by J. Legendziewicz, W. Strek (World Scientific, Singapore, 1985), p. 309

    Google Scholar 

  12. K.D. Oskam, A.J. Houtepen, A. Meijerink, J. Lumin. 97, 107 (2002)

    Article  CAS  Google Scholar 

  13. B.M. Tissue, J.C. Wright, Phys. Rev. B 36, 9781 (1987)

    Article  CAS  Google Scholar 

  14. L. van Pieterson, R.P.A. Dullens, P.S. Peijzel, A. Meijerink, J. Chem. Phys. 115, 9393 (2001)

    Article  CAS  Google Scholar 

  15. E. Radzhabov, J. Lumin. 129, 1581 (2009)

    Article  CAS  Google Scholar 

  16. M. Krośnicki, A. Kedziorski, L. Seijo, Z. Barandiarán, J. Phys. Chem. A 118, 358 (2014)

    Article  CAS  Google Scholar 

  17. E. Loh, Phys. Rev. 175, 533 (1968)

    Article  CAS  Google Scholar 

  18. E.J. Heller, J. Chem. Phys. 62, 1544 (1975)

    Article  CAS  Google Scholar 

  19. E.J. Heller, Acc. Chem. Res. 14, 368 (1981)

    Article  CAS  Google Scholar 

  20. G.H. Dieke, H.M. Crosswhite, B. Dunn, J. Opt. Soc. Am. 51(8), 820 (1961)

    Article  CAS  Google Scholar 

  21. G.H. Dieke, H.M. Crosswhite, Appl. Opt. 2(7), 675 (1963)

    Article  CAS  Google Scholar 

  22. J.J. Joos, P.F. Smet, L. Seijo, Z. Barandiarán, Inorg. Chem. Front. 7, 871 (2020)

    Article  CAS  Google Scholar 

  23. M.C. Downer, C.D. Corderomontalvo, H. Crosswhite, Phys. Rev. B 28(9), 4931 (1983)

    Article  CAS  Google Scholar 

  24. C. Dujardin, B. Moine, C. Pedrini, J. Lumin. 54(5), 259 (1993)

    Article  CAS  Google Scholar 

  25. N. Yamashita, S. Fukumoto, S. Ibuki, H. Ohnishi, Jpn. J. Appl. Phys. 32, 3135 (1993)

    Article  CAS  Google Scholar 

  26. N. Yamashita, O. Harada, K. Nakamura, Jpn. J. Appl. Phys. 34(10), 5539 (1995)

    Article  CAS  Google Scholar 

  27. P.F. Smet, J.E. Van Haecke, F. Loncke, H. Vrielinck, F. Callens, D. Poelman, Phys. Rev. B 74(3) (2006)

    Google Scholar 

  28. C. Pedrini, M.F. Joubert, D.S. McClure, J. Lumin. 125(1–2), 230 (2007)

    Article  CAS  Google Scholar 

  29. S.V. Gastev, J.K. Choi, R.J. Reeves, Phys. Solid State 51(1), 44 (2009)

    Article  CAS  Google Scholar 

  30. G. Blasse, B. Grabmaier, in Luminescent materials (Springer, 1994), pp. 1–9

    Google Scholar 

  31. P.A. Tanner, Chem. Soc. Rev. 42, 5090 (2013)

    Article  CAS  Google Scholar 

  32. C. Cascales, J. Fernández, R. Balda, Opt. Express 13, 2141 (2005)

    Article  CAS  Google Scholar 

  33. V.A. Morozov, A. Bertha, K.W. Meert, S. Van Rompaey, D. Batuk, G.T. Martinez, S. Van Aert, P.F. Smet, M.V. Raskina, D. Poelman, A.M. Abakumov, J. Hadermann, Chem. Mater. 25, 4387 (2013)

    Article  CAS  Google Scholar 

  34. E. Friedman, W. Low, J. Chem. Phys. 33, 1275 (1960)

    Article  CAS  Google Scholar 

  35. R. Pandey, S. Sivaraman, J. Phys. Chem. Solids 52, 211 (1991)

    Article  CAS  Google Scholar 

  36. G. Blasse, Phys. Status Solidi B 55, K131 (1973)

    Article  CAS  Google Scholar 

  37. A. Meijerink, G. Blasse, J. Lumin. 43, 283 (1989)

    Article  CAS  Google Scholar 

  38. J.D. Axe, Phys. Rev. A 136, A42 (1964)

    Article  Google Scholar 

  39. N. Bloembergen, J. Lumin. 31, 23 (1984)

    Article  Google Scholar 

  40. B. Moine, C. Pédrini, B. Courtois, J. Lumin. 50(1), 31 (1991)

    Article  CAS  Google Scholar 

  41. P.A. Rodnyĭ, A.K. Khadro, A.S. Voloshinovskĭ, G.B. Stryganyuk, Opt. Spectrosc. 103(4), 568 (2007)

    Article  CAS  Google Scholar 

  42. J.E. Van Haecke, P.F. Smet, D. Poelman, J. Lumin. 126(2), 508 (2007)

    Article  CAS  Google Scholar 

  43. N. Yamashita, Jpn. J. Appl. Phys. 30(12a), 3335 (1991)

    Article  CAS  Google Scholar 

  44. G. Sánchez-Sanz, L. Seijo, Z. Barandiarán, J. Chem. Phys. 131, 024505 (2009)

    Google Scholar 

  45. M. Karbowiak, C. Rudowicz, J. Lumin. 199, 116 (2018)

    Article  CAS  Google Scholar 

  46. M. Suta, C. Wickleder, J. Lumin. 210, 210 (2019)

    Article  CAS  Google Scholar 

  47. M.J. Freiser, S. Methfess, F. Holtzber, J. Appl. Phys. 39, 900 (1968)

    Article  CAS  Google Scholar 

  48. S.J. Camardello, P.J. Toscano, M.G. Brik, A.M. Srivastava, J. Lumin. 151, 256 (2014)

    Article  CAS  Google Scholar 

  49. P. Dorenbos, ECS J. Solid State Sci. Technol. 2(2), R3001 (2013)

    Article  CAS  Google Scholar 

  50. J. Grimm, H.U. Güdel, Chem. Phys. Lett. 404, 40 (2005)

    Article  CAS  Google Scholar 

  51. J. Grimm, E. Beurer, H.U. Güdel, Inorg. Chem. 45, 10905 (2006)

    Article  CAS  Google Scholar 

  52. J. Grimm, J.F. Suyver, E. Beurer, G. Carver, H.U. Güdel, J. Phys. Chem. B 110, 2093 (2006)

    Article  CAS  Google Scholar 

  53. R.T. Wegh, A. Meijerink, Phys. Rev. B 60, 10820 (1999)

    Article  CAS  Google Scholar 

  54. H. Witzke, D.S. McClure, B. Mitchell, in Luminescence of Crystals, Molecules, and Solutions. ed. by F.E. Williams (Plenum, New York, 1973), p. 598

    Chapter  Google Scholar 

  55. Z. Pan, C. Duan, P.A. Tanner, Phys. Rev. B 77, 085114 (2008)

    Google Scholar 

  56. M. Suta, W. Urland, C. Daul, C. Wickleder, Phys. Chem. Chem. Phys. 18, 13196 (2016)

    Article  CAS  Google Scholar 

  57. M. de Jong, A. Meijerink, L. Seijo, Z. Barandiarán, J. Phys. Chem. C 121, 10095 (2017)

    Article  CAS  Google Scholar 

  58. M. de Jong, D. Biner, K. Krämer, Z. Barandiarán, L. Seijo, A. Meijerink, J. Phys. Chem. Lett. 7, 2730 (2016)

    Article  CAS  Google Scholar 

  59. C.W. Struck, W.H. Fonger, J. Lumin. 10, 1 (1975)

    Article  CAS  Google Scholar 

  60. G. Sánchez-Sanz, L. Seijo, Z. Barandiarán, J. Phys. Chem. A 113, 12591 (2009)

    Article  CAS  Google Scholar 

  61. Z. Barandiarán, L. Seijo, J. Chem. Phys. 138, 074102 (2013)

    Google Scholar 

  62. NIST Atomic Spectra Database, NIST Standard Reference Database #78

    Google Scholar 

  63. G.H. Dieke, Spectra and Energy Levels of Rare Earth Ions in Crystals (Interscience Publishers, New York, 1968)

    Google Scholar 

  64. B. Henderson, G.F. Imbusch, Optical Spectroscopy of Inorganic Solids (Clarendon, Oxford, 1989)

    Google Scholar 

  65. U. Oetliker, M.J. Riley, H.U. Güdel, J. Lumin. 63, 63 (1995)

    Article  CAS  Google Scholar 

  66. K.W. Krämer, H.U. Güdel, R.N. Schwartz, J. Alloys Compd. 275–277, 191 (1998)

    Article  Google Scholar 

  67. P.S. Peijzel, P. Vermeulen, W.J.M. Schrama, A. Meijerink, M.F. Reid, G.W. Burdick, Phys. Rev. B 71, 125126 (2005)

    Google Scholar 

  68. M.F. Reid, P.S. Senanayake, J.P.R. Wells, G. Berden, A. Meijerink, A.J. Salkeld, C.K. Duan, R.J. Reeves, Phys. Rev. B 84, 113110 (2011)

    Google Scholar 

  69. G. Sánchez-Sanz, L. Seijo, Z. Barandiarán, J. Chem. Phys. 133, 114509 (2010)

    Google Scholar 

  70. Z. Barandiarán, L. Seijo, J. Chem. Phys. 141, 234704 (2014)

    Google Scholar 

  71. T.S. Piper, J.P. Brown, D.S. McClure, J. Chem. Phys. 46, 1353 (1967)

    Article  CAS  Google Scholar 

  72. E. Loh, Phys. Rev. B 7, 1846 (1973)

    Article  CAS  Google Scholar 

  73. A.A. Kaplyanskii, P.L. Smolyanskii, Opt. Spectrosc. 40, 301 (1976)

    Google Scholar 

  74. E. Beurer, J. Grimm, P. Gerner, H.U. Güdel, J. Am. Chem. Soc. 128, 3110 (2006)

    Article  CAS  Google Scholar 

  75. W.T. Carnall, H.M. Crosswhite, Optical Spectra and Electronic Structure of Actinide Ions in Compounds and in Solution. (Springer, Dordrecht, 1986), pp. 1235–1277. The Chemistry of the Actinide Elements

    Google Scholar 

  76. T. Gouder, R. Eloirdi, Photoelectron Spectroscopy of Actinide Materials (John Wiley & Sons, 2019), p. 193. The Heaviest Metals: Science and Technology of the Actinides and Beyond

    Google Scholar 

  77. Z.R. Jones, M.Y. Livshits, F.D. White, E. Dalodière, M.G. Ferrier, L.M. Lilley, K.E. Knope, S.A. Kozimor, V. Mocko, B.L. Scott, B.W. Stein, J.N. Wacker, D.H. Woena, Chem. Sci. 44, (2021). 10.1039/D1SC00233C. http://dx.doi.org/10.1039/D1SC00233C

  78. L. Seijo, Z. Barandiarán, E. Harguindey, J. Chem. Phys. 114, 118 (2001)

    Article  CAS  Google Scholar 

  79. D. Piehler, W.K. Kot, N. Edelstein, J. Chem. Phys. 94, 942 (1991)

    Article  CAS  Google Scholar 

  80. N. Edelstein, W.K. Kot, J.C. Krupa, J. Chem. Phys. 96, 1 (1992)

    Article  CAS  Google Scholar 

  81. L. Seijo, Z. Barandiarán, J. Chem. Phys. 115, 5554 (2001)

    Article  CAS  Google Scholar 

  82. L. Seijo, Z. Barandiarán, in Computational Chemistry: Reviews of Current Trends, vol. 4, ed. by J. Leszczyński (World Scientific, Singapore, 1999), pp. 55–152

    Chapter  Google Scholar 

  83. R.W. Schwartz, P.N. Schatz, Phys. Rev. B 8, 3229 (1973)

    Article  CAS  Google Scholar 

  84. Z. Barandiarán, L. Seijo, J. Chem. Phys. 118, 7439 (2003)

    Article  CAS  Google Scholar 

  85. B. Ordejón, L. Seijo, Z. Barandiarán, J. Chem. Phys. 123, 204502 (2005)

    Google Scholar 

  86. B. Ordejón, M. Karbowiak, L. Seijo, Z. Barandiarán, J. Chem. Phys. 125, 074511 (2006)

    Google Scholar 

  87. B. Ordejón, L. Seijo, Z. Barandiarán, J. Chem. Phys. 126, 194712 (2007)

    Google Scholar 

  88. J.F. Wyart, V. Kaufman, J. Sugar, Phys. Scr. 22, 389 (1980)

    Article  CAS  Google Scholar 

  89. C.H.H. Van Deurzen, K. Rajnak, J.G. Conway, J. Opt. Soc. Am. B 1, 45 (1984)

    Article  Google Scholar 

  90. E. Eliav, U. Kaldor, Y. Ishikawa, Phys. Rev. A 51, 225 (1995)

    Article  CAS  Google Scholar 

  91. R.A. Satten, C.L. Schreiber, E.Y. Wong, J. Chem. Phys. 42, 162 (1965)

    Article  CAS  Google Scholar 

  92. C.D. Flint, P.A. Tanner, Mol. Phys. 61, 389 (1987)

    Article  CAS  Google Scholar 

  93. W. Xu, S. Dai, L.M. Toth, J.R. Peterson, Chem. Phys. 193, 339 (1995)

    Article  CAS  Google Scholar 

  94. P.A. Tanner, J. Dexpert-Ghys, Z.W. Pei, J. Lin, Chem. Phys. 215, 125 (1997)

    Article  CAS  Google Scholar 

  95. M. Kirm, J.C. Krupa, V.N. Makhov, E. Neodin, G. Zimmerer, J.Y. Gesland, J. Lumin. 104, 85 (2003)

    Article  CAS  Google Scholar 

  96. L. Seijo, Z. Barandiarán, J. Chem. Phys. 118, 5335 (2003)

    Article  CAS  Google Scholar 

  97. M. Karbowiak, J. Drożdżyński, S. Hubert, E. Simoni, W. Strek, J. Chem. Phys. 108, 10181 (1998)

    Article  CAS  Google Scholar 

  98. M. Karbowiak, J. Drozdzynski, J. Phys. Chem. A 108, 6397 (2004)

    Article  CAS  Google Scholar 

  99. M. Karbowiak, Chem. Phys. 314, 189 (2005)

    Article  CAS  Google Scholar 

  100. F. Ruipérez, Z. Barandiarán, L. Seijo, J. Chem. Phys. 127, 144712 (2007)

    Google Scholar 

  101. F. Ruipérez, B.O. Roos, Z. Barandiarán, L. Seijo, Chem. Phys. Lett. 434, 1 (2007)

    Article  CAS  Google Scholar 

  102. S.K. Roy, R. Prasad, Chem. Phys. 535, 110781 (2020)

    Google Scholar 

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Authors and Affiliations

  1. Departamento de Química, Universidad Autónoma de Madrid, Madrid, Spain

    Zoila Barandiarán

  2. Department of Solid State Sciences, Ghent University, Gent, Belgium

    Jonas Joos

  3. Departamento de Química, Universidad Autónoma de Madrid, Madrid, Spain

    Luis Seijo

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  1. Zoila Barandiarán
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  2. Jonas Joos
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  3. Luis Seijo
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Correspondence to Zoila Barandiarán .

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Barandiarán, Z., Joos, J., Seijo, L. (2022). Fundamental Spectroscopic Studies. In: Luminescent Materials. Springer Series in Materials Science, vol 322. Springer, Cham. https://doi.org/10.1007/978-3-030-94984-6_9

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