Skip to main content

Organic Shape-Memory Polymers and their Foams and Composites in Space

  • Chapter
  • First Online:
Shape Memory Composites Based on Polymers and Metals for 4D Printing

Abstract

Organic shape-memory foams (OSMFs) are innovative and smart materials. They can respond to an external stimulus (heat-induced, electricity-induced, light exposure, magnetic field, water, and solvent) by changing their shape and recovering an equilibrium one. They have the advantages of lightweight, low cost, high shape deformability, high shape recoverability, tailorable switch temperature, and are easy to manufacture. Shape-memory provides additional functionalities to already known performances of organic forms such as the partial recovery of damages from impacts or volume reduction for long-time storage. For this reason, OSMFs have big potential to be used in the aerospace and biomedical field mainly as light actuators, expandable and self-deployable structures, and environmental-sensitive structures. In this chapter, some works on OSMFs are reviewed, highlighting synthesis and characterization of different materials, challenges, and applications mainly for Space, biomedicine, and 4D printing. Space applications are particularly deepened. Two experiments in Space, one (I-FOAM) performed on the ISS, and the second (RIBES/FOAM2) by using an unmanned flight are described and compared. SMP foams and composites have been recovered in microgravity thanks to an autonomous device where three different samples were placed before the flight. Obtained results show OSMF applicability under microgravity conditions as a premise for future applications in space. Moreover, the possibility to manufacture OSMFs by 4D could open new scenarios for in-space manufacturing and colonization missions.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 149.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 199.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 199.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Santo L (2016) Shape-memory polymer foams. Prog Aerosp Sci 81:60–65

    Google Scholar 

  2. Quadrini F, Santo L Squeo EA (2012) Shape-memory epoxy foams for space applications. Mat Lett (69):20–23

    Google Scholar 

  3. Santo L, Quadrini F, Mascetti G, Dolce F, Zolesi V (2013) Mission STS-134: results of shape-memory foam experiment. Acta Astron 91:333–340

    Article  Google Scholar 

  4. Santo L, Quadrini F, Squeo EA, Dolce F, Mascetti G, Bertolotto D, Villadei W, Ganga PL, Zolesi V (2012) Behavior of shape-memory epoxy foams in microgravity: experimental results of STS-134 mission. Microgravity Sci Technol 24:287–296

    Article  Google Scholar 

  5. Santo L, Quadrini F, Ganga PL, Zolesi V (2015) Mission BION-M1: results of RIBES/FOAM2 experiment on shape-memory polymer foams and composites. Aerosp Sci Technol 40:109–114

    Article  Google Scholar 

  6. Quadrini F (2014) Polymer matrix composites with shape-memory properties. Mat Sci For 783–786:2509–2516

    Google Scholar 

  7. Babaevskii PG, Kozlov NA, Devicheva OV (2015) The influence of the component composition on the glass transition temperature and open porosity of shape-memory polyester urethane foam. Plast Mas 5–6:43–47

    Google Scholar 

  8. L. Santo GM, Quadrini TF (2015) Manufacturing of a shape-memory polymer actuator. In: Proceedings of the ASME 2015 international manufacturing science and engineering conference MSEC2015. Charlotte, North Carolina, USA

    Google Scholar 

  9. Santo L, Quadrini F, Bellisario D (2016) Shape-memory composite antennas for space applications. Mat Sci Eng (161)

    Google Scholar 

  10. Santo L, Quadrini F, Accettura A, Villadei W (2014) Shape-memory composites for self-deployable structures in aerospace applications. Proc Eng 88:42–47

    Article  Google Scholar 

  11. Sokolowski W, Tan S, Willis P, Pryor M, Shape-memory self-deployable structures for solar sails. In: Proceedings of SPIE—the international society for optical engineering, p 7267

    Google Scholar 

  12. Tobushi H, Okumura K, Endo M, Hayashi S (2014) Thermomechanical properties of polyurethane-shape-memory polymer foam. J Intell Mater Syst Struct 12:283–287

    Article  Google Scholar 

  13. Di Prima MA, Lesniewski M, Gall K, McDowell DL, Sanderson T, Campbell D (2007) Thermo-mechanical behavior of epoxy shape-memory polymer foams. Smart Mater Struct 16:2330–2340

    Article  Google Scholar 

  14. Meents EP, Barnell TJ, Cable KM, Margraf TW, Havens E (2009) Self-healing reflexive composite structures for marine environments. In: Proceedings of 2009 international sampe symposium and exhibition, vol 54. Baltimore, MD, United States. Code 79037, p 16

    Google Scholar 

  15. Santo L, Quadrini F (2015) Shape-memory composite sandwich with self-healing properties for marine applications. In: 20th international conference on composite materials. Copenhagen

    Google Scholar 

  16. John M, Li G (2010) Self-healing of sandwich structures with a grid stiffened shape-memory polymer syntactic foam core. Smart Mat Struct (19):7

    Google Scholar 

  17. Zhang P, Ogunmekan B, Ibekwe S, Jerro D, Pang SS, Li G (2015) Healing of shape-memory polyurethane fiber-reinforced syntactic foam subjected to tensile stress. J Intell Mat Syst Struct 17:1–10

    Google Scholar 

  18. Kashyap D, Gaur S, Kanagaraj S (2020) Development of hybrid shape-memory polyurethane composites for endovascular applications. Mat Today Commun (22):100751

    Google Scholar 

  19. Landsman TL, Bush RL, Glowczwski A, Horn J, Jessen SL, Ungchusri E, Diguette K, Smith HR, Sayyeda MH, Nash D, Jr. Clubb FJ, Maitland DJ (2016) Design and verification of a shape-memory polymer peripheral occlusion device. J Mech Behav Biomed Mat (63):195–206

    Google Scholar 

  20. Boyle AJ, Landsman TL, Wierzbicki MA, Nash LD, Hwan W, Miller MW, Tuzun E, Hasan SM, Maitland DJ (2016) In vitro and in vivo evaluation of a shape-memory polymer foam-overwire embolization device delivered in saccular aneurysm models. J Biomed Mat Res Part B App Biomat (7):104

    Google Scholar 

  21. Wang J, Luo J, Kunkel R, Liu Y, Bohnstedt B, Lee CH (2018) Biomedical devices using shape-memory polymer foams for treatment of intracranial aneurysms. In: Proceedings of ASME 2018, international mechanical engineering congress and exposition. IMECE2048–86120

    Google Scholar 

  22. Wang J, Luo J, Kunkel R, Saha M, Bohnstedt N, Lee C-H, Liu Y (2019) Development of shape-memory polymer nanocomposites foam for treatment of intracranial aneurysms. Mat Lett 250:38–41

    Article  Google Scholar 

  23. Harrison RH, St-Pierre J-P, Stevens MM (2014) Tissue engineering and regenerative medicine: a year in review. Tiss Eng Part B: Rev 20:1–16

    Article  Google Scholar 

  24. Langer R, Vacanti J (2016) Advances in tissue engineering. J Ped Surg (51):1

    Google Scholar 

  25. Webber MJ, Khan OF, Sydlik SA, Tang BC, Langer RA (2015) A perspective on the clinical translation of scaffolds for tissue engineering. Biomed Eng (43):3

    Google Scholar 

  26. Del Bakhshayesh AR, Annabi N, Khalilov R, Akbarzadeh A, Samiei M, Alizadeh E, Alizadeh-Ghodsi M, Davaran S, Montaseri A (2018) Recent advances on biomedical applications of scaffolds in wound healing and dermal tissue engineering. Artif Cells Nanomed Biotechnol (46):691–705

    Google Scholar 

  27. Amani H, Mostafavi E, Arzaghi H, Davaran S, Akbarzadeh A, Akhavan O, Pazoki-Toroudi H, Webster TJ (2019) Three-dimensional graphene foams: synthesis, properties, biocompatibility, biodegradability, and applications in tissue engineering. ACS Biomater Sci Eng 5(1):193–214

    Article  Google Scholar 

  28. Hsu SH, Huang GS (2013) Substrate-dependent Wnt signaling in MSC differentiation within biomaterial-derived 3D spheroids. Biomat 34(20):4725–4738

    Article  Google Scholar 

  29. Chen G, Qi Y, Niu L, Di T, Zhong J, Fang T, Yan W (2015) Application of the cell sheet technique in tissue engineering. Biomed Repo 3(6):749–757

    Article  Google Scholar 

  30. Xie R, Hu J, Hoffmann O, Zhang Y, Ng O, Qin T, Guo X (2018) Self-fitting shape-memory polymer foam inducing bone regeneration: a rabbit femoral defect study. Biochem Biophys Acta (BBA)—Gen Subj (1862)4:936–945

    Google Scholar 

  31. Song JJ, Chang HH, Naguib HE (2015) Design and characterization of biocompatible shape-memory polymer (SMP) blend foams with a dynamic porous structure. Polymer 56:82–92

    Article  Google Scholar 

  32. Quadrini F, Bellisario D, Santo L, Del Gaudio C, Bianco A (2013) Shape-memory foams of microbial polyester for biomedical applications. Pol-Pl Tech Eng 52:599–602

    Article  Google Scholar 

  33. Jang LK, Fletcher GK, Monroe MB, Maitland DJ (2020) Biodegradable shape-memory polymer foams with appropriate thermal properties for hemostatic applications. J Biomed Mater Res A 108(6):1281–1294

    Article  Google Scholar 

  34. Muschalek R, Nash L, Jones R, Hasan SM, Keller BK, Monroe MBB, Maitland DJ (2017) Effects of sterilization on shape-memory polyurethane embolic foam devices. J Med Device 11(3):0310111–0310119

    Article  Google Scholar 

  35. Ratna D, Karger-Kocsis J (2008) Recent advances in shape-memory polymers and composites: a review. J Mater Sci 43:254–269

    Article  Google Scholar 

  36. Quadrini F, Squeo EA (2008) Solid-state foaming of epoxy resin. J Cell Plast 44:161–173

    Article  Google Scholar 

  37. Lucignano C, Squeo EA, Guglielmotti A, Quadrini F (2011) Recycling of waste epoxy-polyester powders for foam production. Int J Manuf Mat Mech Eng 1:10–20

    Google Scholar 

  38. Squeo EA, Quadrini F (2010) Shape-memory epoxy foams by solid-state foaming. Smart Mat Struct 19:105002

    Google Scholar 

  39. Quadrini F, Santo L, Squeo EA (2012) Solid-state foaming of nano-clay-filled thermoset foams with shape-memory properties. Pol-Pl Tech Eng 51:560–567

    Article  Google Scholar 

  40. Santo L, Tedde GM, Quadrini F, Mutlay I (2015) CNT and graphene filled shape-memory foams by solid state foaming. Key Eng Mat 651–653:719–725

    Article  Google Scholar 

  41. Santo L, Quadrini F, De Chiffre L (2013) Forming of shape-memory composite structures. Key Eng Mat 554–557:1930–1937

    Article  Google Scholar 

  42. Santo L, Quadrini F, Bellisario D, Ciampoli L (2015) Self-repairing behavior of shape-memory composites. App Mech Mat 809–810:453–547

    Google Scholar 

  43. Santo L, Quadrini F, Bellisario D (2016) Multilayered composite plates with shape-memory properties. Key Eng Mat 699:1–7

    Article  Google Scholar 

  44. Gibson I, Rosen DW, Stucker B (2010) Additive manufacturing technologies. Springer, New York

    Book  Google Scholar 

  45. Ligon SC, Liska R, Stampfl J, Gurr M, Mulhaupt R (2017) Polymers for 3D printing and customized additive manufacturing. Chem Rev 117(15):10212–10290

    Article  Google Scholar 

  46. Ge Q, Qi JH, Dunn ML (2013) Active materials by four-dimension printing. App Phys Lett 103:131901

    Google Scholar 

  47. Tao R, Ji L, Li Y, Wan Z, Hu W, Wu W, Liao B, Ma L, Fang D (2020) 4D printed origami metamaterials with tunable compression twist behavior and stress-strain curves. Comp Part B: Eng 201:108344

    Google Scholar 

  48. Ji L, Hu WB, Tao R, Liao B, Wan Z, Wu W, Xi L, Fang D (2020) Compression behavior of the 4D printed reentrant honeycomb: Experiment and finite element analysis. Smart Mat Struct 29(11)

    Google Scholar 

  49. Invernizzi M, Turri S, Levi M, Suriano R (2018) 4D printed thermally activated self-healing and shape-memory polycaprolactone-based polymers. Eur Pol J 101:169–176

    Article  Google Scholar 

  50. Invernizzi M, Natale G, Levi M, Turri S, Griffini G (2016) UV-assisted 3D printing of glass and carbon fiber-reinforced dual-cure polymer composites. Materials 9(7):583

    Article  Google Scholar 

  51. Senatov FS, Niaza KV, Yu M, Zadorozhnyy MY, Maksimkin AV, Kaloshkin SD, Estrin YZ (2016) Mechanical properties and shape-memory effect of 3D-printed PLA-based porous scaffolds. J Mech Behav Biomed Mater 57:139–148

    Article  Google Scholar 

  52. Mu X, Bertron T, Dunn C, Qiao H, Wu J, Zhao Z, Saldana C, Qi HJ (2017) Porous polymeric materials by 3D printing of photocurable resin. Mater Horiz 4(3)

    Google Scholar 

  53. Amato DN, Amato DV, Sandoz M, Weigand J, Patton DL, Visser CW (2020) Programmable porous polymers via direct bubble writing with surfactant-free inks. ACS Appl Mater Interfaces 12(37):42048–42055

    Article  Google Scholar 

  54. Visser CW, Amato DN, Mueller J, Lewis JA (2019) Architected polymer foams via direct bubble writing. Adv Mater 31(46):1904668

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Loredana Santo .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2022 The Author(s), under exclusive license to Springer Nature Switzerland AG

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Santo, L., Santoro, D., Quadrini, F. (2022). Organic Shape-Memory Polymers and their Foams and Composites in Space. In: Maurya, M.R., Sadasivuni, K.K., Cabibihan, JJ., Ahmad, S., Kazim, S. (eds) Shape Memory Composites Based on Polymers and Metals for 4D Printing. Springer, Cham. https://doi.org/10.1007/978-3-030-94114-7_13

Download citation

  • DOI: https://doi.org/10.1007/978-3-030-94114-7_13

  • Published:

  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-030-94113-0

  • Online ISBN: 978-3-030-94114-7

  • eBook Packages: EngineeringEngineering (R0)

Publish with us

Policies and ethics