Abstract
Magnesium oxide (MgO) construction boards are currently being used to replace fibre cement boards in various construction applications. This include usage in external claddings where reports of hygroscopic degradation were linked to presence of residual chlorides originating from the manufacturing process. The industry has responded with new products that are being marketed as Magnesium Oxysulphate (MOS) boards that are still essentially MgO based but are manufactured from non-chloride precursor. In this paper the hygroscopic performance of the new MOS based MgO is compared with some other commercially Chloride containing samples. It is shown that MOS based samples exhibited lower water absorption comparable to fibre cement boards. No evidence of chloride in the new MOS based MgO boards was found by Energy Dispersive Spectroscopy (EDS). Small angle neutron scattering (SANS), of dry samples and hydrated samples using deuterated water and normal water showed that the better hygroscopic properties of MOS based MgO board was not related to structural morphological modification and are more likely due to the absence of residual chloride in the new generation MgO boards.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Martins, J.A., Gomes, C.M., Fontanini, P., Dornelles, K.: Comparative analysis on thermal performance of MgO and fiber cement boards applied to light steel frame building systems. J. Build. Eng. 21, 312–316 (2019)
Li, P.X., Froese, T.M., Cavka, B.T.: Life cycle assessment of magnesium oxide structural insulated panels for a smart home in Vancouver. Energy Build. 175, 78–86 (2018)
Walling, S.A., Provis, J.L.: Magnesia-based cements: a journey of 150 years, and cements for the future? Chem. Rev. 116(7), 4170–4204 (2016)
Wang, D.X., Di, S.J., Gao, X.Y., Wang, R.H., Chen, Z.G.: Strength properties and associated mechanisms of magnesium oxychloride cement-solidified urban river sludge. Constr. Build. Mater. 250, 118933 (2020)
Jays, N., Olofinjana, A., Young, D.J.: Assessing variability in the hygrothermal performance of magnesium oxide (MgO) cladding products of the Australian market. Constr. Build. Mater. 203, 491–500 (2019)
Luo, X.R., et al.: Effect of hydroxyacetic acid on the water resistance of magnesium oxychloride cement. Constr. Build. Mater. 246, 118428 (2020)
Jiříčková, A., et al.: Synthesis, structure, and thermal stability of magnesium oxychloride 5Mg(OH)2∙MgCl2∙8H2O. Appl. Sci. 10(5), 1683 (2020)
He, P.P., Poon, C.S., Richardson, I.G., Tsang, D.C.W.: The mechanism of supplementary cementitious materials enhancing the water resistance of magnesium oxychloride cement (MOC): a comparison between pulverized fuel ash and incinerated sewage sludge ash. Cem. Concr. Compos. 109, 103562 (2020)
Li, X., Qiu, R.F., Xue, F.B., Fang, L., Cheng, F.Q.: Effects of unreactive MgO and impurities in light burned MgO on the hydration process and performance of base magnesium sulfate cement. Constr. Build. Mater. 240, 117854 (2020)
Guo, T., Wang, H.F., Yang, H.J., Cai, X.S., Ma, Q., Yang, S.M.: The mechanical properties of magnesium oxysulfate cement enhanced with 517 phase magnesium oxysulfate whiskers. Constr. Build. Mater. 150, 844–850 (2017)
Tang, S.W., Wei, C.R., Cai, R.J., Huang, J.S., Chen, E., Yuan, J.H.: In situ monitoring of pore structure of magnesium oxysulfate cement paste: effect of MgSO4/H2O ratio. J. Ind. Eng. Chem. 83, 387–400 (2020)
Zeng, X., Yu, H., Wu, C.: An overview of study on basic magnesium sulfate cement and concrete in China (2012–2019). KSCE J. Civ. Eng. 23(10), 4445–4453 (2019). https://doi.org/10.1007/s12205-019-0199-7
Qin, L., Gao, X.J., Li, W.G., Ye, H.: Modification of magnesium oxysulfate cement by incorporating weak acids. J. Mater. Civ. Eng. 30(9), 04018209 (2018)
Acknowledgements
The authors acknowledge AINSE for awarding grant No. 8285 to carry out neutron diffraction studies at ANSTO.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2022 The Author(s), under exclusive license to Springer Nature Switzerland AG
About this paper
Cite this paper
Olofinjana, A., Jays, N., Young, D., Mata, J., Haque, R. (2022). Hygroscopic Performance of Sulphate-Based MgO Construction Boards. In: Batako, A., Burduk, A., Karyono, K., Chen, X., Wyczółkowski, R. (eds) Advances in Manufacturing Processes, Intelligent Methods and Systems in Production Engineering. GCMM 2021. Lecture Notes in Networks and Systems, vol 335. Springer, Cham. https://doi.org/10.1007/978-3-030-90532-3_30
Download citation
DOI: https://doi.org/10.1007/978-3-030-90532-3_30
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-90531-6
Online ISBN: 978-3-030-90532-3
eBook Packages: Intelligent Technologies and RoboticsIntelligent Technologies and Robotics (R0)