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Evaporation Induced Self-assembly

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Mesoporous Ordered Silica Films

Part of the book series: Advances in Sol-Gel Derived Materials and Technologies ((Adv.Sol-Gel Deriv. Materials Technol.))

Abstract

This chapter is dedicated to describing self-assembly during the deposition of a thin silica film. It is a very complex process that can be well controlled through an accurate design of the process parameters. The solvent’s evaporation in the precursor sol induces self-organization through the changes of the chemical-physical variables of the system. In reality, the whole self-assembly process is governed by the weak forces that regulate the micelle formation and the interactions between the surfactant and the silica building blocks. Evaporation, in this sense, is the phenomenon that favours the interactions at the supramolecular level. Self-assembly has been extensively studied and thoroughly described as a function of the process conditions.

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References

  1. M. Ogawa, Formation of novel oriented transparent films of layered silica-surfactant nanocomposites. J. Am. Chem. Soc. 116, 7941–7942 (1994)

    CAS  Google Scholar 

  2. M. Ogawa, A simple set-gel route for the preparation of silica-surfactant mesostructured materials. Chem. Commun. 32, 1149–1150 (1996)

    Google Scholar 

  3. M. Ogawa, Preparation of transparent thin films of silica-surfactant mesostructured materials. Supramol. Sci. 5, 247–251 (1998)

    CAS  Google Scholar 

  4. J.S. Beck, J.C. Vartuli, W.J. Roth, M.E. Leonovicz, C.T. Kresge, K.D. Schmidt, C.T.-W. Chu, D.H. Olson, E.W. Sheppard, S.B. McCullen, J.B. Higgins, J.L.J. Schlenker, A new family of mesoporous molecular sieves prepared with liquid crystal templates. J. Am. Chem. Soc. 114, 10834–10843 (1992)

    CAS  Google Scholar 

  5. C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartuli, J.S. Beck, Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism. Nature 359, 710–712 (1992)

    CAS  Google Scholar 

  6. P. Innocenzi, L. Malfatti, Mesoporous thin films: properties and applications. Chem. Soc. Rev. 42, 4198–4216 (2013)

    CAS  Google Scholar 

  7. Y. Lu, R. Ganguli, C.A. Drewien, M.T. Anderson, C.J. Brinker, W. Gong, Y. Guo, H. Soyez, B. Dunn, M.H. Huang, J.I. Zink, Continuous formation of supported cubic and hexagonal mesoporous films by sol–gel dip-coating. Nature 389, 364–368 (1997)

    CAS  Google Scholar 

  8. C.J. Brinker, Y. Lu, A. Sellinger, H. Fan, Evaporation-induced self-assembly: nanostructures made easy. Adv. Mater. 11, 579–585 (1999)

    CAS  Google Scholar 

  9. G.J.A.A. Soler-Illia, P. Innocenzi, Mesoporous hybrid thin films: the physics and chemistry beneath. Chem. Eur. J. 12, 4478–4494 (2006)

    CAS  Google Scholar 

  10. D. Grosso, F. Cagnol, G.J.A.A. Soler-Illia, E.L. Crepaldi, H. Amenitsch, A. Brunet-Bruneau, A. Bourgeois, C. Sanchez, Fundamentals of mesostructuring through evaporation-induced self-assembly. Adv. Funct. Mater. 14, 309–322 (2004)

    CAS  Google Scholar 

  11. R. Ranganathan, M. Peric, R. Medina, U. Garcia, B.L. Bales, M. Almgren, Size, hydration, and shape of SDS/heptane micelles investigated by time-resolved fluorescence quenching and electron spin resonance. Langmuir 17, 6765–6770 (2001)

    CAS  Google Scholar 

  12. A. Gibaud, S. Dourdain, O. Gang, B.M. Ocko, In situ grazing incidence small-angle x-ray scattering real-time monitoring of the role of humidity during the structural formation of templated silica thin films. Phys. Rev. B 70, 161403(R) (2004)

    Google Scholar 

  13. F. Cagnol, D. Grosso, G.J.A.A. Soler-Illia, E.L. Crepaldi, F. Babonneau, H. Amenitsch, C. Sanchez, Humidity-controlled mesostructuration in CTAB-templated silica thin film processing. The existence of a modulable steady state. J. Mater. Chem. 13, 61–66 (2003)

    CAS  Google Scholar 

  14. S. Dourdaina, A. Rezairea, A. Mehdib, B.M. Ockoc, A. Gibaud, Real time GISAXS study of micelle hydration in CTAB templated silica thin films. Phys. B 357, 180–184 (2005)

    Google Scholar 

  15. P. Innocenzi, L. Malfatti, T. Kidchob, P. Falcaro, Order-disorder in self-assembled mesostructured silica films: a concepts review. Chem. Mater. 21, 2555–2564 (2009)

    CAS  Google Scholar 

  16. M. Klotz, P.-A. Albouy, A. Ayral, C. Ménager, D. Grosso, A. Van der Lee, V. Cabuil, F. Babonneau, C. Guizard, The true structure of hexagonal mesophase-templated silica films as revealed by X-ray scattering: effects of thermal treatments and of nanoparticle seeding. Chem. Mater. 17, 1721–1728 (2000)

    Google Scholar 

  17. S.H. Tolbert, T.E. Schaffer, J. Feng, P.K. Hansma, G.D. Stucky, A new phase of oriented mesoporous silicate thin films. Chem. Mater. 9, 1962–1967 (1997)

    CAS  Google Scholar 

  18. D. Zhao, P. Yang, D.I. Margolese, F. Chmelka Bradley, G.D. Stucky, Synthesis of continuous mesoporous silica thin films with three-dimensional accessible pore structures. Chem. Commun. 2499–2500 (1998)

    Google Scholar 

  19. S. Besson, C. Ricolleau, T. Gacoin, C. Jacquiod, J.-P. Boilot, A new 3D organization of mesopores in oriented CTAB silica films. J. Phys. Chem. B 104, 12095–12097 (2000)

    Google Scholar 

  20. X. Auvray, C. Petipas, R. Anthore, I. Rico, A. Lattes, X-ray diffraction study of mesophases of cetyltrimethylammonium bromide in water, formamide, and glycerol. J. Phys. Chem. 93, 7458–7464 (1989)

    CAS  Google Scholar 

  21. D. Zhao, P. Yang, N. Melosh, J. Feng, B.F. Chmelka, G.D. Stucky, Continuous mesoporous silica films with highly ordered large pore structures. Adv. Mater. 10, 1380–1385 (1998)

    CAS  Google Scholar 

  22. S. Besson, T. Gacoin, C. Ricolleau, T. Gacoin, C. Jacquiod, J.-P. Boilot, Phase diagram for mesoporous CTAB–silica films prepared under dynamic conditions. J. Mater. Chem. 13, 404–409 (2003)

    CAS  Google Scholar 

  23. M.P. Tate, B.W. Eggiman, J.D. Kowalski, H.W. Hillhouse, Order and orientation control of mesoporous silica films on conducting gold substrates formed by dip-coating and self-assembly: a grazing angle of incidence small-angle X-ray scattering and field emission scanning electron microscopy study. Langmuir 21, 10112–10118 (2005)

    CAS  Google Scholar 

  24. B.W. Eggiman, M.P. Tate, H.W. Hillhouse, Rhombohedral structure of highly ordered and oriented self-assembled nanoporous silica thin films. Chem. Mater. 18, 723–730 (2006)

    CAS  Google Scholar 

  25. A.H. Schoen, Infinite periodic minimal surfaces without self-intersections (Technical report). NASA Technical Note. NASA. NASA TN D-5541. Available online at: 19700020472.pdf (nasa.gov) (1970)

    Google Scholar 

  26. K. Schumacher, P.I. Ravikovitch, A. Du Chesne, A.V. Neimark, K.K. Unger, Characterization of MCM-48 materials. Langmuir 16, 4648–4654 (2000)

    CAS  Google Scholar 

  27. V.K. Urade, T.-C. Wei, M.P. Tate, J.D. Kowalski, H.D. Hillhouse, Nanofabrication of double-gyroid thin films. Chem. Mater. 19, 768–777 (2007)

    CAS  Google Scholar 

  28. M.P. Tate, V.N. Urade, S.J. Gaik, C.M. Muzzillo, H.W. Hillhouse, How to dip-coat and spin-coat nanoporous double-gyroid silica films with EO19-PO43-EO19 surfactant (Pluronic P84) and know it using a powder X-ray diffractometer. Langmuir 26, 4357–4367 (2010)

    CAS  Google Scholar 

  29. A.C. Finnefrock, R. Ulrich, G.E.S. Toombes, S.M. Gruner, U. Wiesner, The plumber’s nightmare:1 a new morphology in block copolymer−ceramic nanocomposites and mesoporous aluminosilicates. J. Am. Chem. Soc. 125, 13084–13093 (2003)

    CAS  Google Scholar 

  30. A.C. Finnefrock, U. Ralph, C.A. Du, C.C. Honeker, K. Schumacher, K.K. Unger, S.M. Gruner, U. Wiesner, Metal oxide containing mesoporous silica with bicontinuous “plumber’s nightmare” morphology from a block copolymer-hybrid mesophase. Angew. Chem. 113, 1247–1251 (2001)

    Google Scholar 

  31. D.R. Dunphy, F.L. Garcia, B. Kaehr, C.Y. Khripin, A.D. Collord, H.K. Baca, M.P. Tate, H.W. Hillhouse, J.W. Strzalka, Z. Jiang, J. Wang, C.J. Brinker, Tricontinuous cubic nanostructure and pore size patterning in mesostructured silica films templated with glycerol monooleate. Chem. Mater. 23, 2107–2112 (2001)

    Google Scholar 

  32. S. Shunai Che, S. Kamiya, O. Terasaki, T. Tatsumi, The formation of cubic Pm3n mesostructure by an epitaxial phase transformation from hexagonal p6mm mesophase. J. Am. Chem. Soc. 123, 12089–12090 (2001)

    Google Scholar 

  33. P. Innocenzi, L. Malfatti, T. Kidchob, P. Falcaro, S. Costacurta, M. Guglielmi, G. Mattei, H. Amenitsch, Thermal induced phase transitions in self-assembled mesostructured films studied by small angle X-ray scattering. J. Synchr. Rad. 12, 734–738 (2005)

    CAS  Google Scholar 

  34. P. Falcaro, S. Costacurta, G. Mattei, H. Amenitsch, A. Marcelli, M. Cestelli Guidi, M. Piccinini, A. Nucara, L. Malfatti, T. Kidchob, P. Innocenzi, Highly ordered “defect-free” self-assembled hybrid films with a tetragonal mesostructure. J. Am. Chem. Soc. 127, 3838–3846 (2005)

    CAS  Google Scholar 

  35. A. Grunenwald, A. Ayral, P.-A. Albouy, C. Licitra, P. Gergaud, D. Quemener, A. Deratani, V. Rouessac, A. Zenasni, V. Jousseaume, Hydrophobic mesostructured organosilica-based thin films with tunable mesopore ordering. Microp. Mesop. Mater. 150, 64–75 (2012)

    CAS  Google Scholar 

  36. P. Falcaro, D. Grosso, H. Amenistch, P. Innocenzi, Silica mesostructured films with low refractive index and high thermal stability. J. Phys. Chem. B 108, 10942–10948 (2004)

    CAS  Google Scholar 

  37. G.A. McConnell, A.P. Gast, Predicting disorder-order phase transitions in polymeric micelles. Phys. Rev. E 54, 5447 (1996)

    CAS  Google Scholar 

  38. E.L. Crepaldi, G.J.A.A. Soler-Illia, D. Grosso, F. Cagnol, F. Ribot, C. Sanchez, Controlled formation of highly organized mesoporous titania thin films: from mesostructured hybrids to mesoporous nanoanatase TiO2. J. Am. Chem. Soc. 125, 9770–9786 (2003)

    CAS  Google Scholar 

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Correspondence to Plinio Innocenzi .

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Innocenzi, P. (2022). Evaporation Induced Self-assembly. In: Mesoporous Ordered Silica Films. Advances in Sol-Gel Derived Materials and Technologies. Springer, Cham. https://doi.org/10.1007/978-3-030-89536-5_4

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