Abstracts
Kinetic features of oxidation and cis-trans isomerization of methyl linoleate in the presence of lipophilic thiol in hydrocarbon solution are considered taking 2-mercaptoethanol (RSH), the simplest thiol, as an example. The effects of hydrophilic endogenous thiol glutathione (GSH) on hydrogen peroxide decomposition, thiol-ene reaction of GSH with unsaturated phenol resveratrol (RVT) and the oxidation of sunflower oil and methyl linoleate in the micellar solution in the presence of GSH are discussed as well. Both RSH and GSH were found to reduce hydroperoxides and H2O2, and these reactions are accompanied by free radical formation.
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This work was supported by the Russian Foundation for Basic Research (project no. 20-03-00753) and performed under a state task (project no. 0082-2018-0006, registration no. АААА-А18-118020890097-1).
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Kasaikina, O.T., Zinatullina, K.M., Kancheva, V.D., Slavova-Kasakova, A.K., Loshadkin, D.V. (2022). Effect of Lipophilic and Hydrophilic Thiols on the Lipid Oxidation. In: Bravo-Diaz, C. (eds) Lipid Oxidation in Food and Biological Systems. Springer, Cham. https://doi.org/10.1007/978-3-030-87222-9_8
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