Abstract
From the very beginning of combustion research, it was understood that the chemical reactions of the combustion process consist of the oxidation of fuel. For example, it was clear that when hydrogen–oxygen is burned, water is formed, and when methane–oxygen is burned, water and carbon dioxide are formed.
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Notes
- 1.
Temperature dependence of the rate coefficient (3.1.8) had been suggested by Jacobus Van’t Hoff (the first winner of Nobel Prize in Chemistry, 1901). Svante Arrhenius (received Nobel Prize in Chemistry, 1903) has given theoretical explanation and formulated the concept of activation energy.
References
L.D. Landau, E.M. Lifshitz, Course of Theoretical Physics, vol. 5 (Pergamon Press, Oxford, Statistical Physics, 1989)
J.O. Hirschfelder, C.F. Gurtiss, R.B. Bird, Molecular Theory of Gases and Liquids (Wiley, NewYork, 1964)
S.A. Arrhenius, Über die Reaktionsgeschwindigkeit bei der Inversion von Rohrzucker durch Säuren. Z. Phys. Chem. 4, 226–248 (1989)
A.N. Hayhurst, I.M. Vince, Nitric oxide formation from N2 in flames: The importance of “prompt” NO. Prog. Energy Combust. Sci. 6, 35–51 (1980)
J.A. Miller, C.T. Bowman, Mechanism and modeling of nitrogen chemistry in combustion. Prog. Energy Combust. Sci. 15, 287–338 (1989)
J.C. Kramlich, W.P. Linak, Nitrous oxide behavior in the atmosphere, and in combustion and industrial systems. Prog. Energy Combust. Sci. 20, 149–202 (1994)
S.C. Hill, L.D. Smoot, Modeling of nitrogen oxides formation and destruction in combustion systems. Prog. Energy Combust. Sci. 26, 417–458 (2000). https://doi.org/10.1016/S0360-1285(00)00011-3
P. Glarborga, J.A. Miller, B. Ruscic, S.J. Klippenstein, Modeling nitrogen chemistry in combustion. Prog. Energy Combust. Sci. 67, 31–68 (2018)
Ya. B. Zel'dovich, The oxidation of nitrogen in combustion explosions. Acta Physicochimica U.S.S.R. 21, 577–628 (1946)
Ya.B. Zeldovich, D.A. Frank-Kamenetskii, P. Sadovnikov, oxidation of nitrogen in combustion. Published. Acad. Sci. USSR (1947)
Y.B. Zeldovich, G.I. Barenblatt, V.B. Librovich, G.M. Makhviladze, The Mathematical theory of combustion and explosions. Science Publ. Moscow, 1980 (in Russian). English translation: Consultants Bureau, New York (1985).
C.P. Fenimore, Formation of nitric oxide in premixed hydrocarbon flames, in Symposium (International) on Combustion, vol 13, pp. 373–380 (1971).
D.W. Pershing, O.L. Wendt, Relative contributions of volatile nitrogen and char nitrogen to NOx emissions from pulverized coal flames. Ind. Eng. Chem. Process. Des. Dev. 18, 60–67 (1979)
C.T. Bowman, Kinetics of nitric oxide formation in combustion processes, in Proceedings of Fourteenth Symposium (International) on Combustion, The Combustion Institute, Pittsburgh, PA (1973). pp. 729–738.
C.T. Bowman, Kinetics of pollutant formation and destruction in combustion. Prog. Energy Combust. Sci. 1, 33–45 (1975)
G.A. Lavoie, J.B. Heywood, J.C. Keck, Experimental and theoretical study of nitric oxide formation in internal combustion engines. Combust. Sci. Technol. 1, 313–326 (1970)
J.F. Driscoll, R.H. Chen, Y. Yoon, Nitric oxide levels of turbulent jet diffusion flames: effects of varying residence time and Damköhler number Combust. Flame 88, 37–49 (1992)
C. Morely, The formation and destruction of hydrogen cyanide from atmospheric and fuel nitrogen in rich atmospheric-pressure flames Combust. Flame 27, 189–204 (1976)
L.V. Moskaleva, M.C. Lin, The spin-conserved reaction CH: a major pathway to prompt NO studied by quantum/statistical theory calculations and kinetic modeling of rate constant. Proc. Combust. Inst. 28, 2393–2401 (2000)
A.A. Konnov, On the relative importance of different routes forming in hydrogen flames. Combust Flame 134, 421–424 (2003)
Q. Cui, K. Morokuma, J.M. Bowman, S.J. Klippenstein, The spin-forbidden reaction CH(2Π)+N2→HCN+N(4S) revisited. II. Nonadiabatic transition state theory and application. J. Chem. Phys. 110 (1999) pp. 9469–9482
B.A. Williams, J.W. Fleming, Experimental and modeling study of formation in 10 torr methane and propane flames: evidence for additional prompt- precursors. Proc. Combust. Inst. 31, 1109–1117 (2007)
F.H.V. Coppens, J. De Ruyck, A.A. Konnov, The effects of composition on burning velocity and nitric oxide formation in laminar premixed flames of + + +. Combust. Flame 149, 409–417 (2007)
A.A. Konnov, On the role of radicals in the prompt- mechanism. Combust. Expl. Shock Waves 44, 497–501 (2008)
A.A. Konnov, Implementation of the NCN pathway of prompt-NO formation in the detailed reaction mechanism. Combust. Flame 156, 2093–2105 (2009)
D.L. Baulch, D.D. Drysdale, D.G. Home, A.C. Lloyd, Evaluated kinetic data for high temperature reactions. Butterworths, London 1, 2 (1973)
D.L. Baulch, C.G. Cobos, R.A. Cox, P. Frank, G. Hayman, T.H. Just, J.A. Kerr, T. Murrells, M.J. Pilling, J. Troe, R.W. Walker, J. Warnatz, Summary table of evaluated kinetic data for combustion modeling. Combust. Flame 98, 59–79 (1994)
D.L. Baulch, C.T. Bowman, C.G. Cobos, R.A. Cox, T.H. Just, J.A. Kerr, M.J. Pilling, D. Stocker, J. Troe, W. Tsang, R.W. Walker, J. Warnatz, Evaluated kinetic data for combustion modeling: supplement II. J. Phys. Chem. Ref. Data 34, 757–1397 (2005)
R.K. Hanson, S. Salimian, Survey of rate constants in the N-H-O system, in Combustion Chemistry, ed. by W.C. Gardiner, Jr (Springer-Verlag, NY, 1984).
W. Tsang, J.T. Herron, Chemical Kinetic Data Base for Propellant Combustion. I. Reactions involving NO, NO2, HNO, HNO2, HCN and N2O. J. Phys. Chem. Ref. Data 20, 609–663 (1991)
J. Warnatz, Rate coefficients in the C-H-O system, in Combustion Chemistry, ed. by W.C. Gardiner Jr (Springer, NY, 1984)
R.J. Kee, E.M. Rupley, J.A. Miller, Chemkin-II: a fortan chemical kinetics package for the analysis of gas-phase chemical kinetics. Sandia National Laboratories Report. SAND898009 (1990)
D. De Soete, Overall reaction rate of and formation from fuel nitrogen, in Fifteenth Symposium (International) on Combustion. The Combustion Institute, Pittsburgh, PA (1975). pp. 1093–1102
P. Glarborg, P.G. Kristensen, K. Dam-Johansen, J.A. Miller, Branching fraction of the reaction between 1210 and 1370 K. J. Phys. Chem. A 101, 3741–3745 (1997)
P. Glarborg, K. Dam-Johansen, and J.A. Miller. The reaction of ammonia with nitrogen dioxide in a flow reactor: implications for the reaction. Int. J. Chem. Kinet. 27, 1207–1220 (1995)
J.A. Miller, P. Glarborg, Modeling the formation of and in the Thermal De-NOx process. Springer Ser. Chem. Phys. 61, 318–333 (1996)
J. A. Miller and P. Glarborg. Modeling the Thermal DeNOx process: Closing in on a final solution. Int. J. Chem. Kinet. 31, 757765 (1999)
N.N. Semenov, Chain Reactions, Goskhimtekhizdat, Leningrad, 1934 (Chemical Kinetics and Chain Reactions, Oxford University Press, Oxford, English Translation, 1935)
C.N. Hinshelwood, The Kinetics of Chemical Change (Oxford University Press, Oxford, 1940)
U. Maas, J. Warnatz, Ignition processes in hydrogen-oxygen mixtures. Combust. Flame 74, 53–69 (1988)
G.J. Minkoff, C.F.H. Tipper, Chemistry of Combustion Reactions (Butterworth, London, 1962)
F.W. Williams, R.S. Sheinson, Manipulation of cool and blue flames in the winged vertical tube reactor. Combust. Sci. Technol. 7, 85–92 (1973)
J. Warnatz, in Combustion Chemistry, ed. by W. C. Gardiner , Jr (Springer, New York, 1984).
M. Frenklach, H. Wang, M.J. Rabinowit, Optimization and analysis of large chemical kinetic mechanisms using the solution mapping method—combustion of methane. Prog. Energy Combust. Sci. 18, 47–73 (1992)
T.B. Hunter, H. Wang, T.A. Litzinger, M. Frenklach, The oxidation of methane at elevated pressures: experiments and modeling. Combust. Flame 97, 201–224 (1994)
P. Dagaut, J.C. Boettner, M. Cathonnet, Methane oxidation: experimental and kinetic modeling study. Combust. Sci. Technol. 77, 127–148 (1991)
P. Dagaut, M. Cathonnet, J.C. Boettner, F. Guillard, Kinetic modeling of propane oxidation. Combust. Sci. Technol. 56, 23–63 (1987)
M. Cathonnet, Chemical kinetic modeling of combustion from 1969 to 2019, Combust. Sci. Technol. 98, 265–279 (1994)
M. Nehse, J.Warnatz, C. Chevalier, Kinetic modeling of the oxidation of large aliphatic hydrocarbons, in Symposium (International) on Combustion, vol 26 (1996). pp. 773–780
J.A. Sutton, B.A. Williams, J.W. Fleming, Investigation of NCN and prompt-NO formation in low-pressure C1–C4 alkane flames. Combust. Flame 159, 562–576 (2012)
J.A. Miller, M.J. Pilling, J. Troe, Unravelling combustion mechanisms through a quantitative understanding of elementary reactions. Proc. Combust. Inst. 30, 43–88 (2005)
C. K. Westbrook, W. J. Pitz, O.r Herbinet, H. J. Curran, E. J. Silke. A comprehensive detailed chemical kinetic reaction mechanism for combustion of n-alkane hydrocarbons from n-octane to n-hexadecane. Combust. Flame, Elsevier 156, 181–199 (2008)
I. Glassman, R.A. Yetter, Combustion, 4th edn (Elsevier, 2008)
H.J. Curran, Developing detailed chemical kinetic mechanisms for fuel combustion. Proceed. Combust. Institute 37, 57–81 (2019)
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Liberman, M.A. (2021). Combustion Chemistry. In: Combustion Physics. Springer, Cham. https://doi.org/10.1007/978-3-030-85139-2_1
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DOI: https://doi.org/10.1007/978-3-030-85139-2_1
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