Skip to main content

Post-Treatment

  • Chapter
  • First Online:
Reverse Osmosis Seawater Desalination Volume 2
  • 394 Accesses

Abstract

Chapter 3 sets out the criteria to be met with regard to the composition of the product water of an SWRO plant, the treatment steps to be applied to meet these requests, and how these are to be dimensioned and calculated. While the main focus of post-treatment when using SWRO product water as industrial process water is on the reduction of its salinity, a number of additional quality criteria must be taken into account when using it as drinking water and/or in agriculture. These are national or international drinking water regulations, regulations for the composition of water for agricultural irrigation and livestock farming, and guidelines to mitigate the corrosive effect of the product water on the materials used in the water distribution network as well as the make-up of existing water resources. SWRO post-treatment includes post-desalination, alkalisation/remineralisation, conditioning, and primary and secondary disinfection of the product water. Alkalinisation/remineralisation involves increasing the alkalinity and calcium content of the product water. Conditioning may optionally include dosing of fluoride, magnesium, and corrosion inhibitors, and the disinfection steps the use of chlorine, chlorine dioxide, and/or chloramine. The process components of post-treatment are described in terms of their structure and mode of operation, and their design is outlined. For alkalisation/remineralisation, the dimensioning of the hydrated lime/carbon dioxide process and that of the limestone filter/carbon dioxide variant are presented. Chapter 3 concludes with descriptions of how to calculate the power take-up of the whole post-treatment stage and of its constituent process steps.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 249.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Notes

  1. 1.

    Australian and New Zealand Guidelines for Fresh and Marine Water Quality-Volume 3.

    Primary Industries-Rationale and Background Information (Irrigation and general water uses, stock drinking water, aquaculture and human consumers of aquatic foods), 2000.

  2. 2.

    American Public Health Association, American Waters Works Association, Waters Environment Federation Standard Methods for the Examination of Water and Wastewater-APHA 2330 Calcium Carbonate Saturation.

  3. 3.

    DIN 38404-10-2012—German standard methods for the examination of water, waste water and sludge—Physical and physico-chemical parameters (group C)—Part 10—Calculation of the calcite saturation of water (C 10).

  4. 4.

    DIN EN 12502—Guidance on the assessment of corrosion likelihood in water distribution and storage systems Part 1: General; Part 2: Influencing factors for copper and copper alloys; Part 3: Influencing factors for hot-dip galvanised ferrous materials; Part 4: Influencing factors for stainless steels; Part 5: Influencing factors for cast iron, unalloyed and low-alloy steels.

  5. 5.

    DOW Water & Process Solutions, Amberlite PWA 10 & Amberlite IRA 743; Lanxess, Lewatit, MK 51; Mitsubishi Chemical, DIAION CRBO3 & CRBO5; Purolite, S 108.

  6. 6.

    Guidelines for Drinking Waters Quality-4th Edition, 2011, World Health Organisation (WHO).

  7. 7.

    2018 Edition of the Drinking Water Standards and Health Advisories Tables-United States Environmental Protection Agency.

References

  1. Ludwig, H., Reverse Osmosis Seawater Desalination, Volume 1, Springer, 2022.

    Google Scholar 

  2. Ayers R.S., Westcot D.W., Water quality for agriculture - FAO Irrigation and drainage paper 29 Rev. 1, Rome: Food and Agriculture Organization of the United Nations FAO, 1985.

    Google Scholar 

  3. Plummer N.L., Busenberg E., “The solubilities of calcite, aragonite and vaterite in CO2-H2O solutions between 0 and 90°C, and an evaluation of the aqueous model for the system CaCO3-CO2-H2O,” Geochimics et Cosmochimica Acta, vol. 46, pp. 1011–1040, 1982.

    Google Scholar 

  4. Harned H.S., Owen B.B., The Physical Chemistry of Electrolytic Solutions, 3rd edition, New York: Reinhold Publishing Corp., 1958.

    Google Scholar 

  5. Joint Task Group on Calcium Carbonate Saturation, “Suggested Methods for Calculating and Interpreting Calcium Carbonate Saturation Indexes,” Journal AWWA (American Water Works Association), vol. 82, no. 7, pp. 71–77, 1990.

    Google Scholar 

  6. de Moel P.J., van der Helm A.W.C., van Rijn M., van Dijk J.C., van der Meer W.G.J., “Assessment of calculation methods for calcium carbonate saturation in drinking for DIN 38404-10 compliance,” Drinking Water Engineering and Science, vol. 6, no. 2, pp. 115–124, 2013.

    Google Scholar 

  7. Ryznar J.W., “A New Index for Determining Amount of Calcium Carbonate Scale Formed by a Water,” Journal American Water Works Association, vol. 36, no. 4, pp. 472–486, 1944.

    Google Scholar 

  8. Puckorius P.R., Brooke J.M., “A New Practical Index for Calcium Carbonate Scale Prediction in Cooling Tower Systems,” CORROSION, vol. 47, no. 4, pp. 280–284, 1991.

    Google Scholar 

  9. Larson J.E., Skold R.V., “Laboratory Studies Relating Mineral Quality of Water to Corrosion of Steel and Cast Iron,” CORROSION, vol. 14, no. 6, pp. 285–288, 1958.

    Google Scholar 

  10. Gorenflo A., Brusilovsky M., Faigon M., Liberman B., “High pH operation in seawater reverse osmosis permeate: First results from the world’s largest SWRO plant in Ashkelon,” Desalination, vol. 203, pp. 82–90, 2007.

    Google Scholar 

  11. Molina V.G., Taub M., Yohay L., Busch M., “Long term membrane process and performance in Ashkelon Seawater Reverse Osmosis Desalination plant,” Desalination and Water Treatmernt, vol. 31, pp. 115–120, 2011.

    Google Scholar 

  12. I.D.E Technologies Ltd, Liberman B., Liberman I., “US Patent 7,097,769 B2 - METHOD OF BORON REMOVAL IN PRESENCE OF MAGNESIUM IONS,” 2006.

    Google Scholar 

  13. I.D.E Technologies Ltd, Liberman B., Liberman I., “European Patent EP 1 363 856 B1 - METHOD OF BORON REMOVAL IN PRESENCE OF MAGNESIUM IONS,” 2006.

    Google Scholar 

  14. MEDRC Series of R & D Reports - MEDRC Project: 12-CoE-007- Ouda A.S., “Investigate the Boron Content Reduction from Seawater Reverse Osmosis Permeate by Ion Exchange method (Case Study: SWRO Desalination Plant of Gaza Power Station),” The Middle East Desalination Research Center, Muscat, Sultanate of Oman, 2014.

    Google Scholar 

  15. Nadav N., “Boron removal from seawater reverse osmosis permeate utilizing selective ion exchange resin,” Desalination, vol. 124, pp. 131–135, 1999.

    Google Scholar 

  16. Ludwig H., Hetschel M., “Treatment of Distillates and Permeates from Seawater Desalination Plants,” Desalination, vol. 58, pp. 135–154, 1986.

    Google Scholar 

  17. Glade H., Meyer J.,Will S., “The release of CO2 in MSF and ME distillers and its use for the recarbonation if the distillate: a comparison,” Desalination, vol. 182, pp. 99–110, 2005.

    Google Scholar 

  18. Hasson D., Bendrihem O., “ Modeling demineralization of desalinated water by limestone dissolution,” Desalination, vol. 190, pp. 189–200, 2006.

    Google Scholar 

  19. Baldauf G., Henkel M., “Möglichkeiten und Grenzen der Marmorentsäuerung vor dem Hintergrund der neuen Trinkwasserverordnung,” GWF Wasser - Abwasser, vol. 132, no. 3, pp. 132–140, 1991.

    Google Scholar 

  20. Yamauchi Y., Tanaka K., Hattori K., Kondo M., Ukawa N., “REMINERALIZATION OF DESALINATION WATER BY LIMESTONE DISSOLUTION FILTER,” Desalination, vol. 66, pp. 365–383, 1987.

    Google Scholar 

  21. Shemer H., Hasson D., Semiat R., Priel M., Nadav N., Shulman A., Gelman E., “Remineralization of desalinated water by limestone dissolution with carbon dioxide,” Desalination and Water Treatment , vol. 51, pp. 877–881, 2013.

    Google Scholar 

  22. Ludwig H., “Post-treatment and Potabilisation - A Quality Determining Factor in the Generation of Drinking Water by Means of Sea Water Desalination,” in International Desalination Assoziation - Congress on Desalination and Water Reuse , Madrid, Spain, 1997.

    Google Scholar 

  23. Lehmann O., Birnhack L., Lahav O., “Design aspects of calcite-dissolution reactors applied for post treatment of desalinated water,” Desalination, vol. 314, pp. 1–9, 2013.

    Google Scholar 

  24. Wiegleb K., “Planungskriterien zur Enteisenung und Entsäuerung durch Filtration über halbgebrannte Dolomite,” gwf Wasser - Abwasser, vol. 142, no. 6, pp. 417–422, 2001.

    Google Scholar 

  25. Cotruvo J., Bartram J., eds., “Calcium and Magnesium in Drinking-water : Public health significance,” World Health Organization WHO, Geneva, 2009.

    Google Scholar 

  26. “Safe Drinking-water from Desalination - WHO/HSE/WSH/11.03,” World Health Organisation WHO, Geneva, 2011.

    Google Scholar 

  27. Hasson D., Semiat R., Shemer H., Priel M., Nadav N., “Simple process for hardening desalinated water with Mg2+ ions,” Desalination and Water Treatment, vol. 51, pp. 924–929, 2013.

    Google Scholar 

  28. Birnhack L., Lahav O., “A new post-treatment process for attaining Ca2+, Mg2+, SO42- and alkalinity criteria in desalinated water,” Water Research, vol. 41, pp. 3989–3997, 2007.

    Google Scholar 

  29. Birnhack L., Oren S., Lehmann O., Lahav O., “Development of an additional step to current CO2-based CaCO3 dissolution post-treatment processes for cost-effective Mg2+ supply to desalinated water,” Chemical Engineering Journal, vol. 160, pp. 48–56, 2010.

    Google Scholar 

  30. Birnhack L., Penn R., Oren S., Lehmann O., Lahav O., “Pilot scale evaluation of a novel post-treatment process for desalinated water,” Desalination and Water Treatment, vol. 13, pp. 128–136, 2010.

    Google Scholar 

  31. Fawell J., Bailey K., Chilton J., Dahi E., Fewtrell L., Magara Y., “Fluoride in Drinking-water,” World Health Organization WHO / IWA Publishing, 2006.

    Google Scholar 

  32. American Water Works Association AWWA, Water Fluoridation - Principles & Practices - Manual of Water Supply Practices - M4, Denver, 2016.

    Google Scholar 

  33. Kim D., Amy G.L., Karanfil T., “Disinfection by-product formation during seawater desalination: A review,” Water Research, vol. 81, pp. 343–355, 2015.

    Google Scholar 

  34. U.S. Environmental Protection Agency, Guidance Manual for Compliance with the Filtration and Disinfection Requirements for Public Water Systems using Surface Water Sources, Washington, USA: U.S. Environmental Protection Agency, 1991.

    Google Scholar 

  35. U.S. Environmental Protection Agency, „LT1ESWTR Disinfection Profiling and Benchmarking - Technical Guidance Manual,“ U.S. Environmental Protection Agency - Office of Water, Washington USA, 2003.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Annexes

Annexes

3.1.1 3.A1 Post-Treatment: Remineralization/Alkalinization—Lime/CO2 Process Design

figure a

3.1.2 3.A2 Post-Treatment: Remineralization/Alkalinization—Limestone/CO2 Process Design

figure b
figure c

3.1.3 3.A3 Post-Treatment: Disinfection Process Design—Primary and Secondary Disinfection

figure d
figure e

= Input parameter

Rights and permissions

Reprints and permissions

Copyright information

© 2022 The Author(s), under exclusive license to Springer Nature Switzerland AG

About this chapter

Check for updates. Verify currency and authenticity via CrossMark

Cite this chapter

Ludwig, H. (2022). Post-Treatment. In: Reverse Osmosis Seawater Desalination Volume 2. Springer, Cham. https://doi.org/10.1007/978-3-030-81927-9_3

Download citation

  • DOI: https://doi.org/10.1007/978-3-030-81927-9_3

  • Published:

  • Publisher Name: Springer, Cham

  • Print ISBN: 978-3-030-81926-2

  • Online ISBN: 978-3-030-81927-9

  • eBook Packages: EngineeringEngineering (R0)

Publish with us

Policies and ethics