Abstract
Novel monomers based on (2Z)-2-(benzylidene)-6-hydroxy-1-benzofuran-3 (2H)-one with different substituents were synthesized by reaction of acylation with methacryloyl chloride. Kinetic of homopolymerization was investigated by dylatometric method. The synthesis of copolymers based on novel aurone containing monomers and methylmethacrylate was conducted in 10% dimethylformamide solution with 2,2ˊ-azobisisobutyronitrile as radical initiator at 80 °C (argon atmosphere). All structures of novel monomers were identified by 1H NMR and MS. The photochemical properties of synthesized aurone containing polymers have been investigated by UV VIS spectroscopy. It was found that aurone moiety in the side chain of polymer has been shown ability to Z-E-isomerization under irradiation with wavelength 365 nm. The half-reaction periods for Z-isomers of aurone containing polymers were calculated.
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Kharchenko, O. et al. (2021). Photochemical Properties of Side Chain Aurone Polymers. In: Fesenko, O., Yatsenko, L. (eds) Nanooptics and Photonics, Nanochemistry and Nanobiotechnology, and Their Applications . NANO 2020. Springer Proceedings in Physics, vol 264. Springer, Cham. https://doi.org/10.1007/978-3-030-74800-5_21
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